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    Heat-hardenable cationic water-dilutable binders
    165.
    发明授权
    Heat-hardenable cationic water-dilutable binders 失效
    热可硬化阳离子水可稀释粘合剂

    公开(公告)号：US4458054A

    公开(公告)日：1984-07-03

    申请号：US443456

    申请日：1982-11-22

    Applicant: Gerhard Schmozer ,  Heiner Verdino ,  Wolfgang Daimer

    Inventor： Gerhard Schmozer ,  Heiner Verdino ,  Wolfgang Daimer

    IPC: C08K5/00 ,  C08G59/14 ,  C08G59/40 ,  C08G59/62 ,  C08G85/00 ,  C08K5/10 ,  C08K5/11 ,  C08K5/1515 ,  C08K5/17 ,  C08K5/29 ,  C08L63/00 ,  C09D5/00 ,  C09D5/44 ,  C09D163/00 ,  C09D201/02 ,  C08L63/02

    CPC classification number: C08K5/11 ,  C09D5/4496

    Abstract: Cationic heat-hardenable binders comprising polymers containing amine groups and a crosslinking component which is film-forming with the amine group containing polymer through transesterification at elevated temperatures are described. The binders which are water-dilutable upon protonization of the amine groups comprise(a) 60 to 95% by weight of a polymer having a hydroxyl value of from 40 to 450 mg KOH/g and an amine value of from 20 to 150 mg KOH/g, water-soluble or water-dilutable upon protonation of the basic groups, and(b) 5 to 40% by weight of a cross-linking component of the general formula ##STR1## n having a value of from 1 through 5, R.sub.1 being the moiety of a monoalcohol having from 1 to 8 C-atoms or of a polyol or of a polyamine or of a polyepoxy compound or of a polyisocyanate remaining after reaction with one or more carboxylic acid groups, andR.sub.2 being a straight chain or branched alkyl radical with from 1 to 8 C-atoms.The binders have excellent characteristics particularly when deposited from an electrodeposition system.

    Abstract translation: 描述了阳离子热硬化性粘合剂，其包含含有胺基团的聚合物和通过在高温下通过酯交换而与含胺基聚合物成膜的交联组分。 在胺基质子化时可水稀释的粘合剂包含（a）60至95重量％的羟基值为40至450mg KOH / g和胺值为20至150mg KOH的聚合物 / g，在碱性基团的质子化时可溶于水或可稀释水溶液，和（b）5至40重量％的具有1至5个数值的通式“IMAGE”n的交联组分， R1是具有1至8个C原子的一元醇或多元醇或多胺或聚环氧化合物或多异氰酸酯与一个或多个羧酸基反应后残留的一元醇的部分，并且R 2是直链或 具有1至8个C原子的支链烷基。 粘合剂具有优异的特性，特别是当从电沉积系统沉积时。

    Process for metallic coat finishing
    168.
    发明授权
    Process for metallic coat finishing 失效
    金属涂层整理工艺

    公开(公告)号：US4323600A

    公开(公告)日：1982-04-06

    申请号：US176155

    申请日：1980-08-07

    Applicant: Kenji Sakata ,  Toshiaki Yamada ,  Kenji Uchiyama ,  Yugo Hasegawa

    Inventor： Kenji Sakata ,  Toshiaki Yamada ,  Kenji Uchiyama ,  Yugo Hasegawa

    IPC: B05D7/14 ,  B05D1/36 ,  B05D5/06 ,  B05D7/00 ,  C09D5/38 ,  C09D201/02

    CPC classification number: B05D7/532 ,  B05D5/068 ,  Y10T428/31692 ,  Y10T428/31931

    Abstract: Metallic coat finishing with good gloss vividness is provided by undercoating a liquid coating containing a specified thermosetting vinyl copolymer and a metallic appearance imparting pigment, overcoating a thermosetting, clear powder paint and then baking the two coated film together. The specified thermosetting vinyl copolymer is obtained by copolymerizing N-alkoxymethyl(metha)-acrylic amide, a hydroxyl group containing vinyl monomer, a carboxyl group containing vinyl monomer and copolymerizable other vinyl monomers in specified amounts.

    Abstract translation: 通过底漆涂布含有特定热固性乙烯基共聚物和金属外观赋予颜料的液体涂料，再涂覆热固性，透明粉末涂料，然后将两个涂布膜一起烘烤，提供具有良好光泽鲜艳度的金属涂层。 指定的热固性乙烯基共聚物通过N-烷氧基甲基（甲基） - 丙烯酰胺，含羟基的乙烯基单体，含羧基的乙烯基单体和可共聚的其它乙烯基单体以规定的量共聚而获得。

    Air-cross-linkable polyacrylate lacquer binders containing chemically fixed wood preservatives
    170.
    发明授权
    Air-cross-linkable polyacrylate lacquer binders containing chemically fixed wood preservatives 失效
    含有化学固定木材防腐剂的可交联聚丙烯酸酯漆粘合剂

    公开(公告)号：US4267082A

    公开(公告)日：1981-05-12

    申请号：US34551

    申请日：1979-04-30

    Applicant: Rolf Dhein ,  Gerswid Poetter ,  Hans Rudolph

    Inventor： Rolf Dhein ,  Gerswid Poetter ,  Hans Rudolph

    IPC: C08F8/00 ,  B27K3/12 ,  B27K3/15 ,  C08F8/14 ,  C08F8/46 ,  C09D133/14 ,  C09D201/02 ,  C09D3/28 ,  C09D3/80 ,  C09D5/14

    CPC classification number: C09D133/14 ,  C08L97/02 ,  B27K3/12 ,  B27K3/15 ,  C08K5/136 ,  C08L33/06

    Abstract: An air-cross-linkable lacquer binder comprising a copolymer of copolymerized units of from 10 to 40% by weight of glycidyl acrylate, glycidyl methacrylate or a mixture thereof, and 70 to 10% by weight of at least one other vinyl monomer which has been reacted with (based in each case on the quantity of lacquer binder) of from 0.01 to 30% by weight of at least one wood preservative having at least one glycidyl-reactive hydrogen atom and from 20 to 60% by weight of at least one air-drying natural or isomerized fatty acid and from 0 to 10% by weight of a dicarboxylic acid anhydride, said lacquer binder having an average molecular weight M.sub.n of from 1500 to 15,000 and an acid number of from 3 to 15. One special advantage of the lacquer binder according to the invention is that the wood preservatives are chemically fixed to the polymer molecule so that their release is retarded and the protective action is prolonged. Another advantage is the possibility to prepare well-drying wood preservative systems with lacquers which have not been treated with drying agents.

    Abstract translation: 一种可空气交联的漆粘合剂，其包含共聚单元的共聚物，其共聚单元为10至40重量％的丙烯酸缩水甘油酯，甲基丙烯酸缩水甘油酯或其混合物，以及70至10重量％的至少一种其它乙烯基单体 与至少一种具有至少一个缩水甘油基反应性氢原子的至少一种木材防腐剂和20至60重量％的至少一种空气反应（基于每种情况下的漆粘合剂的量）为0.01至30重量％ 干燥天然或异构化脂肪酸和0至10重量％的二羧酸酐，所述漆粘合剂的平均分子量Mn为1500至15,000，酸值为3至15。 根据本发明的漆粘合剂是木材防腐剂化学固定在聚合物分子上，使得它们的释放被延迟并且保护作用被延长。 另一个优点是可以用干燥剂处理过的漆来制备干燥良好的木材防腐剂体系。

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