Abstract:
The present invention discloses a clay/amine complex which is an excellent surfactant and a good reinforcing agent of polymers. The complex of the present invention can be produced by modifying layered inorganic silicate clay such as montomorillonite, with an intercalating agent, AMO (amine terminal-mannich oligomer). The AMO can be obtained by polymerizing polyoxyalkylene amine having molecular weight over 1000, p-cresol and formaldehyde. The present invention further discloses a nanosilica plate, which can be obtained by extracting the above complex with a hydroxide or a chloride of alkali metal or alkaline-earth metal, and consequently, the AMO intercalating agent can be recycled for reusing.
Abstract:
A new class of useful gasoline additives is prepared via two consecutive reactions including: (1) amidation of water-soluble hydrophilic, low molecular weight triamine with alkyl acetate at an elevated temperature under N2 pressure to prepare a symmetrical triamide; and (2) alkoxylation of the triamides with 1,2-epoxyalkane to prepare poly(oxyalkylene)triamide alkoxylate of three telechelic hydroxy groups, having the general formula: wherein x, y and z are from 1 to 20, R is poly(oxyalkylene) of a molecular weight from 72 to 1000, and R′ is an alkyl having a carbon number from 2 to 18.
Abstract:
The present invention is directed to the use of phenyl substituted, five member aromatic amine alkoxylate compounds as additives in fuel compositions. The invention is also directed to the use of these compounds for decreasing intake valve deposits.
Abstract:
The present invention is directed to the use of aromatic amide-containing phenol alkoxylate compounds having a weight average molecular weight is greater than about 600 as additives in fuel compositions. The invention is also directed to the use of these compounds for decreasing intake valve deposits, controlling octane requirement and reducing octane requirement. The invention is still further directed to the aromatic amide-containing phenol alkoxylate compounds.
Abstract:
High molecular weight active polyoxyalkylene reaction product formed in two steps and containing urea or urethane and urea linkages are disclosed which contain as the principle reaction component, a diamine having the formula: ##STR1## or a diol having the formula: ##STR2## wherein R' independently represents hydrogen or methyl and x is a number having an average value of at least 1 to about 70 and a diisocyanate of the formula: ##STR3## an active amine selected from the group consisting of amine terminated triethylene glycol, amine terminated tetraethylene glycol, isophorone diamine, dipropylene triamine, or diethylene triamine.
Abstract:
Block polyamido polyamine condensation products of an aromatic polycarboxylic acid component with a polyoxyalkylene polyamine component prepared by reacting the polycarboxylic acid component with an amount of the polyoxyalkylene polyamine component sufficient to react each carboxyl group with 1 mole of the polyoxyalkylene polyamine component.The polyoxyalkylene polyamine being selected from the group consisting of polyoxypropylene diamines, polyoxyethylene diamines, polyoxyethylene/oxypropylene diamines and polyoxypropylene triamines, and the aromatic polycarboxylic acid component being selected from the group consisting of C.sub.8 to C.sub.28 benzene dicarboxylic acids, benzene tricarboxylic acids, naphthalene carboxylates, hemimellitic acid, 1,1,3-trimethyl-3-phenylindan-4',5-dicarboxylic acid, trimellitic acid, and anhydrides and C.sub.1 to C.sub.4 alkyl esters thereof.
Abstract:
This present invention relates to a disproportionation catalyst and a process for preparing a disproportionation catalyst comprising forming a calcined composite comprising at least one of molybdenum and rhenium supported on an inorganic oxide support and contacting the calcined composite with an organosilane compound selected from the group consisting of silanes containing at least one silicon-hydrogen bond per molecule, silanes containing at least one silicon-silicon bond per molecule and mixtures thereof, and to a process for the disproportionation of olefinic hydrocarbons comprising contacting at least one olefinic hydrocarbon with a catalyst comprising at least one of molybdenum and rhenium supported on an inorganic oxide support promoted with an organosilane compound selected from the group consisting of silanes containing at least one silicon-hydrogen bond per molecule, silanes containing at least one silicon-silicon bond per molecule and mixtures thereof.
Abstract:
This invention is a two step process for converting linear paraffins to linear alpha olefins. In the first step the paraffins are cracked to a mixture of alpha and internal olefins by use of a cracking catalyst of a zeolite in combination with an alkali(ne earth) metal compound wherein the sum of the amount of the alkali(ne earth) metal in the compound plus any metal cation exchanged into the zeolite is in excess of that required to provide a fully metal cation-exchanged zeolite. The resulting olefin-containing cracked product is then converted to a substantially alpha olefin-containing product by contact with ethylene and a disproportionation catalyst at disproportionation conditions. The resulting products contains only small amounts of aromatics.
Abstract:
Normally liquid polyfunctional final Mannich condensates that are useful as curing agents for epoxy resins are prepared by reacting a para C.sub.1 -C.sub.15 alkyl phenol with formaldehyde and a first polyoxyalkylene diamine to form an intermediate Mannich condensate that is reacted, in turn, with formaldehyde and a second polyoxyalkylene diamine to form the final Mannich condensate, the first polyoxyalkylene diamine having the formula: ##STR1## wherein: n represents a positive number having a value of 1 to about 6, andR' independently represents hydrogen or a methyl group, the second polyoxyalkylene diamine having the formula: ##STR2## wherein n and n' represent positive numbers having a value of 1 to about 6,R' independently represents hydrogen or a methyl group, andR"' represents an alkyl group containing 1 to 4 carbon atoms or a cyanoethyl group.
Abstract:
Tetrafunctional amine derivatives of digyclidyl ethers of Bisphenol A that are liquid at ambient temperatures and that are useful as curing agents for epoxy resins are disclosed together with the method by which they are prepared which comprises the steps of:dissolving the diglycidyl ether in a solvent (acetone or methyl ethyl ketone) and adding a polyoxyalkylene diamine in the mole ratio of about 4 to about 5 moles of the diglycidyl ether per mole of said polyoxyalkylene diamine to provide an initial reaction mixture,heating the initial reaction mixture with agitation at a temperature of about 80.degree. to about 160.degree. C. for about 1 to about 4 hours sufficient to permit the diglycidyl ether to quantitatively react with the polyoxyalkylene diamine and to substantially completely volatilize the solvent to thereby form an intermediate reaction product,adding to the intermediate reaction product about 4 moles or more of a polyoxyethylene diamine per mol of initially used polyoxyalkylene diamine and heating the thus-formed second reaction mixture at a temperature of about 100.degree. to about 150.degree. C. for about 0.5 to about 5 hours, to form the tetrafunctional amine derivative.