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公开(公告)号:US20190093036A1
公开(公告)日:2019-03-28
申请号:US16136702
申请日:2018-09-20
Applicant: ExxonMobil Research and Engineering Company
Inventor: Scott K. Berkhous , Sheryl B. Rubin-Pitel , Kenneth C. H. Kar , Erin R. Fruchey
CPC classification number: C10L1/1691 , C10L1/02 , C10L1/04 , C10L1/08 , C10L1/1291 , C10L3/06 , C10L3/10 , C10L10/14 , C10L2200/0272 , C10L2200/0415 , C10L2200/043 , C10L2200/0438 , C10L2200/0446 , C10L2200/0461 , C10L2270/026 , C10L2290/543 , C10L2290/544
Abstract: Compositions corresponding to marine diesel fuels, fuel oils, jet fuels, and/or blending components thereof are provided that include at least a portion of a natural gas condensate fraction. Natural gas condensate fractions derived from a natural gas condensate with sufficiently low API gravity can provide a source of low sulfur, low pour point blend stock for formation of marine diesel and/or fuel oil fractions. Natural gas condensate fractions can provide these advantages and/or other advantages without requiring prior hydroprocessing and/or cracking.
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公开(公告)号:US20210246391A1
公开(公告)日:2021-08-12
申请号:US17244222
申请日:2021-04-29
Applicant: ExxonMobil Research and Engineering Company
Inventor: Timothy J. Anderson , Erin R. Fruchey , Suzanne R. Golisz , Kenneth C. H. Kar , Sheryl B. Rubin-Pitel
IPC: C10L1/08
Abstract: Provided are marine fuel compositions having acceptable wax behavior. In one form, the marine fuel composition has the following enumerated properties: a kinematic viscosity at 50° C. of about 5 cSt to about 700 cSt; a wax endpoint temperature of less than about 100° C.; and a ratio of kinematic viscosity at 100° C. to operating viscosity greater than 1, wherein the operating viscosity is at least about 2 cSt. The marine fuel composition exists in a liquid phase with essentially all the wax in the composition melted (essentially free of solid wax) prior to fuel injection into a marine engine.
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公开(公告)号:US10781386B2
公开(公告)日:2020-09-22
申请号:US16162859
申请日:2018-10-17
Applicant: ExxonMobil Research and Engineering Company
Inventor: Kenneth C. H. Kar , Sheryl B. Rubin-Pitel , David T. Ferrughelli , Anthony S. Mennito , Teng Xu
Abstract: Marine fuel oil compositions are provided that exhibit unexpectedly high cetane numbers after addition of a cetane improver. Methods of making such compositions are also provided. The unexpected nature of the marine fuel oil compositions is based in part on the ability to achieve a substantial improvement in estimated cetane number by addition of a cetane improver to a hydrocarbonaceous composition with a natural estimated cetane number of less than 35. These unexpectedly high increases in estimated cetane number for fuels or fuel blending components with low natural estimated cetane numbers can allow for production of fuel compositions with desirable combustion characteristics while also maintaining a higher level of aromatic compounds and/or reducing or minimizing the amount of distillate boiling range components in the fuel or fuel blending component.
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公开(公告)号:US20200291317A1
公开(公告)日:2020-09-17
申请号:US16716875
申请日:2019-12-17
Applicant: ExxonMobil Research and Engineering Company
Inventor: Timothy J. Anderson , Erin R. Fruchey , Suzanne R. Golisz , Kenneth C. H. Kar , Sheryl B. Rubin-Pitel
Abstract: Marine fuel compositions that are low sulfur and have improved wax flow viscosity are disclosed. An example marine fuel composition may have the following enumerated properties: a sulfur content of about 0.50% or less by weight of the marine fuel composition; a density at 15° C. of about 0.86 g/cm3 to about 1.01 g/cm3; a kinematic viscosity at 50° C. of about 1 centistoke to about 700 centistokes; and a ratio of kinematic viscosity to wax flow viscosity of greater than 1, wherein the wax flow viscosity is determined using a minimum operating viscosity of about 8 centistokes at 50° C.
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公开(公告)号:US10597596B2
公开(公告)日:2020-03-24
申请号:US16136702
申请日:2018-09-20
Applicant: ExxonMobil Research and Engineering Company
Inventor: Scott K. Berkhous , Sheryl B. Rubin-Pitel , Kenneth C. H. Kar , Erin R. Fruchey
Abstract: Compositions corresponding to marine diesel fuels, fuel oils, jet fuels, and/or blending components thereof are provided that include at least a portion of a natural gas condensate fraction. Natural gas condensate fractions derived from a natural gas condensate with sufficiently low API gravity can provide a source of low sulfur, low pour point blend stock for formation of marine diesel and/or fuel oil fractions. Natural gas condensate fractions can provide these advantages and/or other advantages without requiring prior hydroprocessing and/or cracking.
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公开(公告)号:US10597594B1
公开(公告)日:2020-03-24
申请号:US16200884
申请日:2018-11-27
Applicant: ExxonMobil Research and Engineering Company
Inventor: Erin R. Fruchey , Scott K. Berkhous , Kenneth C. H. Kar , Sheryl B. Rubin-Pitel , Aditya S. Shetkar
IPC: C10L1/04
Abstract: Heavy hydrotreated gas oil compositions are provided, along with marine fuel oil compositions and marine gas oil compositions that include a substantial portion of a hydrotreated heavy atmospheric gas oil. The hydrotreated heavy atmospheric gas oil can correspond to a gas oil with a relatively low viscosity and an elevated paraffin content in a narrow boiling range which results in a relatively high cloud point and/or pour point.
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公开(公告)号:US20190093032A1
公开(公告)日:2019-03-28
申请号:US16136682
申请日:2018-09-20
Applicant: ExxonMobil Research And Engineering Company
Inventor: Scott K. Berkhous , Sheryl B. Rubin-Pitel , Kenneth C. H. Kar , Erin R. Fruchey
IPC: C10L1/04
CPC classification number: C10L1/1691 , C10L1/02 , C10L1/04 , C10L1/08 , C10L1/1291 , C10L3/06 , C10L3/10 , C10L10/14 , C10L2200/0272 , C10L2200/0415 , C10L2200/043 , C10L2200/0438 , C10L2200/0446 , C10L2200/0461 , C10L2270/026 , C10L2290/543 , C10L2290/544
Abstract: Compositions corresponding to marine diesel fuels, fuel oils, jet fuels, and/or blending components thereof are provided that include at least a portion of a natural gas condensate fraction. Natural gas condensate fractions derived from a natural gas condensate with sufficiently low API gravity can provide a source of low sulfur, low pour point blend stock for formation of marine diesel and/or fuel oil fractions. Natural gas condensate fractions can provide these advantages and/or other advantages without requiring prior hydroprocessing and/or cracking.
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公开(公告)号:US11299684B2
公开(公告)日:2022-04-12
申请号:US17126204
申请日:2020-12-18
Applicant: ExxonMobil Research and Engineering Company
Inventor: Kenneth C. H. Kar , Sheryl B. Rubin-Pitel , Lisa M. Guay , Timothy J. Anderson , Shifang Luo , Marcia E. Dierolf
Abstract: Marine diesel fuel/fuel blending component compositions and fuel oil/fuel blending component compositions are provided that are derived from crude oils having high naphthenes to aromatics volume and/or weight ratios and a low sulfur content. In addition to having a high naphthenes to aromatics ratio, a low sulfur content, and a low but substantial content of aromatics, such fuels and/or fuel blending components can have a reduced or minimized carbon intensity relative to fuels derived from conventional sources. The unexpected ratio of naphthenes to aromatics contributes to the fuels and/or fuel blending components further having additional unexpected properties, including low density, low kinematic viscosity, and/or high energy density.
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公开(公告)号:US11099144B2
公开(公告)日:2021-08-24
申请号:US16716941
申请日:2019-12-17
Applicant: ExxonMobil Research and Engineering Company
Inventor: Erin R. Fruchey , Suzanne R. Golisz , Kenneth C. H. Kar , Sheryl B. Rubin-Pitel
Abstract: Fuel compositions that are low sulfur and have adequate combustion quality are disclosed. An example fuel composition that is low sulfur may have the following enumerated properties: a sulfur content of about 0.50% or less by weight of the fuel composition; a calculated carbon aromaticity index of about 870 or less; a density at 15° C. of about 900 kg/m3 to about 1,010 kg/m3; a kinematic viscosity at 50° C. of about 100 centistokes to about 700 centistokes; and an estimated cetane number of about 7 or greater.
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公开(公告)号:US20210054298A1
公开(公告)日:2021-02-25
申请号:US16993850
申请日:2020-08-14
Applicant: ExxonMobil Research and Engineering Company
Inventor: Logan P. Renninger , Scott K. Berkhous , Donald J. Mattran , Geert W. Steenbeke , Dongil Kang , Kenneth C. H. Kar
Abstract: This disclosure relates to compositions and methods of making an additized fuel composition comprising a base fuel composition and a randomly branched nitrate composition. The randomly branched nitrate composition includes a plurality of primary nitrate molecules, each molecule therein having an empirical chemical formula of CnNO3, wherein Cn is a branched aliphatic moiety which may be the same or different for each molecule, n is an integer selected from the group consisting of 8, 9, 10, 11 and 12, at least one carbon atom in the branched aliphatic moiety being bound to three or more carbon atoms, a branching index ranging from 1.8 to 2.2, and greater than 80% of the branches in the aliphatic moiety being in other than the alpha position. The additized fuel composition may be diesel fuel composition or a gasoline fuel composition. Such randomly branched nitrate composition may be more stable, and thus safer to handle than 2-ethylhexylnitrate and may have a lower overall nitrogen content, leading to lower NOx emissions upon combustion in diesel and gasoline fuel compositions.
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