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公开(公告)号：US10704001B2
公开(公告)日：2020-07-07
申请号：US16025276
申请日：2018-07-02
Applicant: ExxonMobil Research and Engineering Company
Inventor： Kenneth Chi Hang Kar , Sheryl B. Rubin-Pitel , David T. Ferrughelli , Anthony S. Mennito , Teng Xu
Abstract: A first hydroprocessed product and a second hydroprocessed product produced from a multi-stage process for upgrading pyrolysis tar, such as steam cracker tar, are provided herein. Fuel blends including the first hydroprocessed product and/or the second hydroprocessed product are also provided herein as well as methods of lowering pour point of a gas oil using the first hydroprocessed product and the second hydroprocessed product.
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公开(公告)号：US20170269042A1
公开(公告)日：2017-09-21
申请号：US15450612
申请日：2017-03-06
Applicant: ExxonMobil Research and Engineering Company
Inventor： Changyub Paek , Anthony S. Mennito
CPC classification number: B01D15/361 , B01J41/04 , B01J47/00 , C07C51/47 , C07C2601/08 , C07C2601/14 , C10G29/20 , C10G2300/203 , C07C61/005
Abstract: A process for selective isolation of high molecular weight (˜1230 Daltons) naphthenic acids (Arn acids). The process includes providing a polymeric resin with a bound a quaternary amino group and applying a crude oil sample containing Arn acids to the polymeric resin. A first wash of an organic solvent is applied to the sample followed by a second wash of a polar organic solvent mixture. The first two washes remove unwanted crude oil compositions while the Arn acids are bound to the quaternary amino groups. A third wash of acidified organic solvent removes the Arn acids from the polymeric resin, thereby forming an elute comprising the Arn acids and the acidified organic solvent. The acidified organic solve is then evaporated isolating the Arn acids from the crude oil sample.
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公开(公告)号：US10781386B2
公开(公告)日：2020-09-22
申请号：US16162859
申请日：2018-10-17
Applicant: ExxonMobil Research and Engineering Company
Inventor： Kenneth C. H. Kar , Sheryl B. Rubin-Pitel , David T. Ferrughelli , Anthony S. Mennito , Teng Xu
Abstract: Marine fuel oil compositions are provided that exhibit unexpectedly high cetane numbers after addition of a cetane improver. Methods of making such compositions are also provided. The unexpected nature of the marine fuel oil compositions is based in part on the ability to achieve a substantial improvement in estimated cetane number by addition of a cetane improver to a hydrocarbonaceous composition with a natural estimated cetane number of less than 35. These unexpectedly high increases in estimated cetane number for fuels or fuel blending components with low natural estimated cetane numbers can allow for production of fuel compositions with desirable combustion characteristics while also maintaining a higher level of aromatic compounds and/or reducing or minimizing the amount of distillate boiling range components in the fuel or fuel blending component.
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Patent Agency Ranking
公开(公告)号：US10883055B2
公开(公告)日：2021-01-05
申请号：US15935471
申请日：2018-03-26
Applicant: ExxonMobil Research and Engineering Company
Inventor： Aruna Mohan , Mohsen S. Yeganeh , Daniel P. Cherney , Anthony S. Mennito , Shane P. Deighton , Jessica L. Vreeland
Abstract: A method for selective extraction of naphthenic acids from an acidic crude oil, including: providing an acidic crude oil including naphthenic acids and having a total acid number (TAN) greater than 0.4; mixing the acidic crude oil with a first aqueous solution including water and a weak base to extract a portion of naphthenic acids from the acidic crude oil thereby creating a second aqueous solution containing a mixture of the portion of naphthenic acids, the water and the weak base in an emulsion; separating the second aqueous solution from the emulsion; wherein the second aqueous solution contains an additional portion of the acidic crude oil; adding a salt to the second aqueous solution, thereby causing the additional portion of the acidic crude oil to separate from the second aqueous solution; removing the additional portion of the acidic crude oil from the second aqueous solution; and extracting the portion of the naphthenic acids from the second aqueous solution.
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公开(公告)号：US20190127651A1
公开(公告)日：2019-05-02
申请号：US16162859
申请日：2018-10-17
Applicant: ExxonMobil Research and Engineering Company
Inventor： Kenneth C.H. Kar , Sheryl B. Rubin-Pitel , David T. Ferrughelli , Anthony S. Mennito , Teng Xu
Abstract: Marine fuel oil compositions are provided that exhibit unexpectedly high cetane numbers after addition of a cetane improver. Methods of making such compositions are also provided. The unexpected nature of the marine fuel oil compositions is based in part on the ability to achieve a substantial improvement in estimated cetane number by addition of a cetane improver to a hydrocarbonaceous composition with a natural estimated cetane number of less than 35. These unexpectedly high increases in estimated cetane number for fuels or fuel blending components with low natural estimated cetane numbers can allow for production of fuel compositions with desirable combustion characteristics while also maintaining a higher level of aromatic compounds and/or reducing or minimizing the amount of distillate boiling range components in the fuel or fuel blending component.
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公开(公告)号：US20190016980A1
公开(公告)日：2019-01-17
申请号：US16025276
申请日：2018-07-02
Applicant: ExxonMobil Research and Engineering Company
Inventor： Kenneth Chi Hang Kar , Sheryl B. Rubin-Pitel , David T. Ferrughelli , Anthony S. Mennito , Teng Xu
Abstract: A first hydroprocessed product and a second hydroprocessed product produced from a multi-stage process for upgrading pyrolysis tar, such as steam cracker tar, are provided herein. Fuel blends including the first hydroprocessed product and/or the second hydroprocessed product are also provided herein as well as methods of lowering pour point of a gas oil using the first hydroprocessed product and the second hydroprocessed product.
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7.发明授权公开(公告)号：US09490109B2
公开(公告)日：2016-11-08
申请号：US14178627
申请日：2014-02-12
Applicant: ExxonMobil Research and Engineering Company
Inventor： Kuangnan Qian , Kathleen E Edwards , Anthony S. Mennito , Roland B. Saeger
CPC classification number: H01J49/0027 , G01N33/2835
Abstract: A method to determine the model-of-composition of a vacuum resid in which the resid is separated into fractions including the DAO fraction which is then separated into chemical classes including saturates, aromatics, sulfides and polars by a combination of soft ionization methods. The results of the ionization analysis are reconciled with other analysis such as bulk analysis, then consolidated to generate the modeol-of composition.
Abstract translation: 确定真空渣油的组成模型的方法，其中残渣分离成包含DAO馏分的级分，然后通过软电离方法的组合将其分离成化学类别，包括饱和物，芳族化合物，硫化物和极性。 电离分析的结果与其他分析如批量分析相协调，然后合并以产生组合的模式。
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公开(公告)号：US09418828B2
公开(公告)日：2016-08-16
申请号：US13832564
申请日：2013-03-15
Applicant: ExxonMobil Research and Engineering Company
Inventor： Anthony S. Mennito , Kuangnan Qian
CPC classification number: H01J49/26 , G01N33/2835 , H01J49/164
Abstract: A method for characterizing the saturates portion of a petroleum or hydrocarbon sample that includes compounds with boiling points of 1000° F. (538° C.) or higher includes use of laser desorption ionization (LDI) to desorb and vaporize petroleum saturates into the gas phase. After ionization, the saturate compounds cations can be detected using mass spectrometry. The mass spectrum generated from the ionized saturated compounds is then characterized by assigning molecular formulas to any “detected” masses that exhibit a peak with an intensity greater than a defined signal to noise threshold. After making the molecular assignments, the abundance of each assigned molecule can be determined based on the signal magnitude of the peaks in the mass spectrum. The assigned molecules and the corresponding abundances can then be grouped based on a variety of factors.
Abstract translation: 用于表征包括沸点为1000°F（538℃）或更高的化合物的石油或烃样品的饱和部分的方法包括使用激光解吸电离（LDI）将石油饱和物解吸和蒸发到气体中 相。 电离后，可以使用质谱法检测饱和化合物阳离子。 从电离的饱和化合物产生的质谱图的特征在于将分子式分配给任何“检测到的”质量，其表现出具有大于定义的信噪比阈值的强度的峰。 在进行分子分配之后，可以基于质谱中峰的信号幅度来确定每个分配的分子的丰度。 分配的分子和相应的丰度可以根据多种因素分组。
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