公开(公告)号：US20200017368A1

公开(公告)日：2020-01-16

申请号：US16491485

申请日：2018-03-06

Applicant: Oxford University Innovation Limited ,  SCG CHEMICALS CO., LTD.

Inventor： Dermot O'Hare ,  Shik Chi Tsang ,  Meng-Jung Li

IPC: C01G15/00 ,  B01J23/825 ,  C07C29/154

Abstract: New layered double hydroxide materials useful as intermediates in the formation of catalysts are described, as well as methods of preparing the layered double hydroxides. Also described are catalysts suitable for catalysing the hydrogenation of CO2 to methanol, as well as methods for preparing the catalysts. The LDH-derived catalysts of the invention are active in the hydrogenation of CO2 to methanol, and show improved activity with respect to Cu/ZnO catalysts derived from copper-zinc hydroxycarbonate precursors.

公开(公告)号：US10131548B2

公开(公告)日：2018-11-20

申请号：US15168783

申请日：2016-05-31

Applicant: SCG Chemicals Co., Ltd.

Inventor： Dermot O'Hare ,  Qiang Wang

IPC: C01F7/76 ,  C08K3/26 ,  C08K3/28 ,  C01F7/00 ,  C09C1/40 ,  C01B35/12 ,  C01F11/00 ,  C08K3/22 ,  C08K3/30

Abstract: The present invention relates to a process for modifying a layered double hydroxide (LDH), the process comprising, a. providing a material comprising a layered double hydroxide of formula: [Mz+1-xM′y+x(OH)2]q+(Xn−)q/n.bH2O wherein M and M′ are metal cations, z is 1 or 2, x is 0.1 to 1, b is 0 to 5, y is 3 or 4, X is an anion, n is 1 to 3 and q is determined by x, y and z, b. optionally washing the material at least once with a mixture of water and a mixing solvent miscible with water, and c. washing the material obtained in step a or b at least once with at least one first solvent, the first solvent being miscible with water and having a solvent polarity P′.

公开(公告)号：US09382123B2

公开(公告)日：2016-07-05

申请号：US14367437

申请日：2012-12-18

Applicant: SCG Chemicals Co., Ltd.

Inventor： Dermot O'Hare ,  Qiang Wang

IPC: C08K3/22 ,  C01F11/00 ,  C01B35/12 ,  C01F7/00 ,  C09C1/40

CPC classification number: C01F7/767 ,  C01B35/128 ,  C01F7/002 ,  C01F7/004 ,  C01F7/005 ,  C01F11/00 ,  C01P2002/01 ,  C01P2002/22 ,  C01P2002/50 ,  C01P2002/84 ,  C01P2002/88 ,  C01P2004/04 ,  C01P2004/54 ,  C01P2004/61 ,  C08K3/22 ,  C08K3/26 ,  C08K3/28 ,  C08K3/30 ,  C08K2003/2206 ,  C08K2003/2224 ,  C08K2003/2227 ,  C08K2003/3045 ,  C09C1/40 ,  C08K3/10 ,  C08L23/12

Abstract: Disclosed herein is a process for modifying a layered double hydroxide (LDH), the process comprising a. providing a material comprising a layered double hydroxide of formula: [Mz+1-xM′y+x(OH)2]q+(Xn−)q/n.bH2O wherein M and M′ are metal cations, z is 1 or 2, x is 0.1 to 1, b is 0 to 5, y is 3 or 4, X is an anion, n is 1 to 3 and q is determined by x, y and z; b. optionally washing the material at least once with a mixture of water and a mixing solvent miscible with water; and c. washing the material obtained in a. or b. at least once with at least one first solvent, the first-solvent being miscible with water and having a solvent polarity P′ in the range of 3.8 to 9 to obtain a modified layered double hydroxide.

Abstract translation: 本文公开了一种修饰层状双氢氧化物（LDH）的方法，该方法包括a。 提供包含式[Mz + 1-xM'y + x（OH）2] q +（Xn-）q / n.bH2O的层状双氢氧化物的材料，其中M和M'是金属阳离子，z是1或2 x为0.1〜1，b为0〜5，y为3或4，X为阴离子，n为1〜3，q由x，y，z决定。 b。 任选地用水和与水混溶的混合溶剂的混合物洗涤材料至少一次; 和c。 洗涤a中得到的材料。 或b。 与至少一种第一溶剂至少一次，第一溶剂与水混溶并且溶剂极性P'在3.8至9的范围内，以获得改性的层状双氢氧化物。

公开(公告)号：US11111154B2

公开(公告)日：2021-09-07

申请号：US16054324

申请日：2018-08-03

Applicant: SCG Chemicals Co., Ltd.

Inventor： Dermot O'Hare ,  Qiang Wang

IPC: C01F7/00 ,  C01G9/00 ,  C01G49/00 ,  C01B35/12

Abstract: The present invention relates to a process for modifying a layered double hydroxide (LDH), the process comprising, a. providing a water-wet layered double hydroxide of formula: [Mz+1-xM′y+x]a+(Xn−)a/r.bH2O   (1) wherein M and M′ are metal cations, z=1 or 2; y=3 or 4, x is 0.1 to 1, preferably x

公开(公告)号：US20210171788A1

公开(公告)日：2021-06-10

申请号：US16763292

申请日：2018-11-13

Applicant: SCG CHEMICALS CO., LTD. ,  SCG PACKAGING PUBLIC COMPANY LIMITED

Inventor： Dermot O'Hare ,  Jingfang Yu ,  Dana-Georgiana Crivoi ,  Kanittika Ruengkajorn

IPC: C09D7/62 ,  C09D129/04 ,  C08K9/04 ,  C08K3/32 ,  C08K3/26 ,  C08K3/22 ,  B05D7/04 ,  C08J7/048 ,  C08J7/04

Abstract: A process for the preparation of a coated substrate is described, in which a substrate is coated with a coating mixture containing a polymer and an amino acid-modified layered double hydroxide. The process of the invention is markedly simpler than conventional techniques for affording coated substrates having reduced permeability to degradative gases. The coated substrates obtainable by the process are particularly useful in packaging applications, notably in the food industry.

公开(公告)号：US20190270891A1

公开(公告)日：2019-09-05

申请号：US16461246

申请日：2017-11-15

Applicant: SCG Chemicals Co., Ltd.

Inventor： Dermot O'Hare ,  Jean-Charles Buffet ,  Chunping Chen ,  Kanittika Ruengkajorn ,  Anchelee Wongariyakawee

IPC: C09C1/40 ,  C08K3/26 ,  C08K9/04 ,  C08K9/06

Abstract: Surface-modified layered double hydroxides (LDHs) are disclosed, as well as processes by which they are made, and uses of the LDHs in composite materials. The surface-modified LDHs of the invention are more organophilic than their unmodified analogues, which allows the LDHs to be incorporated in a wide variety of materials, wherein the interesting functionality of LDHs may be exploited.

公开(公告)号：US20190152794A1

公开(公告)日：2019-05-23

申请号：US16308592

申请日：2017-05-25

Applicant: SCG Chemicals Co., Ltd. ,  SCG Packaging Public Company Limited

Inventor： Dermot O'Hare ,  Jean-Charles Buffet ,  Kanittika Ruengkajorn

IPC: C01F7/00

Abstract: Layered double hydroxides (LDHs) are disclosed, as well as methods by which they may be manufactured. The LDHs are subjected to a solvent treatment step during manufacture, which confers high surface area and pore volume properties to the LDHs. The particular solvents used in the preparation of the LDHs renders allows for an overall more efficient and environmentally-friendly manufacturing process.

公开(公告)号：US10221259B2

公开(公告)日：2019-03-05

申请号：US15541663

申请日：2016-01-06

Applicant: SCG CHEMICALS CO., LTD.

Inventor： Dermot O'Hare ,  Jean-Charles Buffet ,  Chunping Chen

IPC: C08F4/02 ,  C08F4/6592 ,  C08F10/02 ,  C08F4/659 ,  B01J37/03 ,  B01J37/06 ,  B01J37/34 ,  B01J21/08 ,  B01J27/236 ,  B01J35/00 ,  B01J35/02 ,  B01J35/08 ,  B01J35/10 ,  B01J31/16 ,  B01J31/22

Abstract: A catalyst system is provided which comprises a solid support material having, on its surface, one or more catalytic transition metal complex wherein the solid support material comprises SiO2@AMO-LDH microspheres having the formula I: (i) wherein, Mz+ and M′y+ are two different charged metal cations; z=1 or 2; y=3 or 4; 0 0.01 and 0 q>0; Xn− is an anion with n>0, preferably 1−5a=z(1−x)+xy−2; and the AMO-solvent is an 100% aqueous miscible organic solvent. Preferably, M′ in the formula I is Al. Preferably, M in the formula I is Li, Mg or Ca. The catalyst system has use in the polymerization and/or copolymerization of at least one olefin to produce a homopolymer and/or copolymer.

公开(公告)号：US10040695B2

公开(公告)日：2018-08-07

申请号：US15129137

申请日：2015-03-25

Applicant: SCG Chemicals Co., Ltd.

Inventor： Dermot O'Hare ,  Chunping Chen ,  Aunchana Wangriya ,  Anchalee Wangariyakawee ,  Qiang Wang

IPC: B01J20/08 ,  B01J21/10 ,  B01J23/06 ,  B01J37/08 ,  B01J27/138 ,  B01J27/053 ,  B01J27/232 ,  B01J37/04 ,  B01J20/30 ,  B01J27/25 ,  C01F11/18 ,  B01J27/236 ,  B01J31/26 ,  B01J31/28 ,  B01J31/02 ,  B01J35/10 ,  B01J35/02 ,  B01J37/03 ,  B01J37/02 ,  B01J20/22 ,  B01J20/04 ,  B01J20/28 ,  C09D1/00 ,  C01F11/46 ,  C01F11/36 ,  C01G53/00 ,  C01G51/00 ,  C01G3/00

Abstract: Layered double hydroxides having a high surface area (at least 125 m2/g) and the formula (I) [Mz+1−xM′y+x(OH)2]a+(Xn−)a/n+bH2O.c(AMO-solvent)  (I) wherein M and M′ are different and each is a charged metal cation (and must be present), z=1 or 2; y=3 or 4, 0

公开(公告)号：US20170088644A1

公开(公告)日：2017-03-30

申请号：US15310814

申请日：2015-05-13

Applicant: SCG Chemicals Co., Ltd.

Inventor： Dermot O'Hare ,  Jean-Charles Buffet ,  Zoe Turner

IPC: C08F110/02

CPC classification number: C08F110/02 ,  B01J2231/12 ,  C08F4/025 ,  C08F4/646 ,  C08F4/65912 ,  C08F4/65925 ,  C08F4/65927 ,  C08F4/69 ,  C08F210/02 ,  C08F2420/04 ,  C08F210/16 ,  C08F4/7042 ,  C08F4/63904 ,  C08F210/14

Abstract: The present invention relates to a synergistic dual olefin copolymerization catalyst system comprising a solid support material having, on its surface, two or more catalytic metal complexes wherein the two or more catalytic metal complexes comprise at least one first transition metal complex and a second transition metal complex different from the first transition metal complex; use of such a system as a catalyst; a process for producing a polymer of an olefin utilizing the catalyst system.