公开(公告)号：US20160250625A1

公开(公告)日：2016-09-01

申请号：US14777649

申请日：2014-06-03

Applicant: DEXERIALS CORPORATION

Inventor： Hiroki KANAYA ,  Mamiko NOMURA

IPC: B01J31/06 ,  C07C201/12 ,  B01J8/02

CPC classification number: B01J31/062 ,  B01J8/02 ,  B01J31/06 ,  B01J37/00 ,  B01J2208/02 ,  C07B53/00 ,  C07B2200/07 ,  C07C201/12 ,  C07C201/16 ,  C07C205/48 ,  C07C2601/10 ,  C07C2601/14 ,  C07C205/19

Abstract: An optically active compound production method using a column reactor, a column for column reactor is charged with asymmetric catalyst particles to produce the column reactor, and reaction compound is introduced into column reactor to bring reaction compound into contact with asymmetric catalyst particles, whereby reaction compound is converted to optically active compound. Asymmetric catalyst particles are preferably resin particles that are prepared from a monomer composition containing a proline derivative monomer having unsaturated bond and radical polymerization initiator and serve as catalyst for enamine mechanism reaction. Asymmetric catalyst particles are preferably resin particles prepared by micro-channel method including injecting monomer composition into continuous phase to thereby form droplets of monomer composition in continuous phase and then heating droplets to cause proline derivative monomer having an unsaturated bond to undergo radical polymerization.

Abstract translation: 使用柱式反应器，塔式反应器塔的旋光化合物制备方法装有不对称催化剂颗粒以制备塔式反应器，并将反应化合物引入塔式反应器以使反应化合物与不对称催化剂颗粒接触，由此反应化合物 转化为光学活性化合物。 不对称催化剂颗粒优选由含有具有不饱和键的脯氨酸衍生物单体和自由基聚合引发剂的单体组合物制备并用作烯胺机理反应的催化剂的树脂颗粒。 不对称催化剂颗粒优选通过微通道法制备的树脂颗粒，包括将单体组合物注入连续相中，从而在连续相中形成单体组合物的液滴，然后加热液滴以使具有不饱和键的脯氨酸衍生物单体进行自由基聚合。

公开(公告)号：US20160001271A1

公开(公告)日：2016-01-07

申请号：US14769021

申请日：2013-12-02

Applicant: OBSHCHESTVO S OGRANICHENNOY OTVETSTVENNOST'YU "GAZOKHIM TEKHNO"

Inventor： Sergey Erikovich DOLINSKIY ,  Nikolay Yakovlevich USACHEV ,  Andrey Mikhaylovich PLESHAKOV

IPC: B01J23/89 ,  B01J37/08 ,  B01J37/02 ,  B01J23/86

CPC classification number: B01J23/8993 ,  B01J21/04 ,  B01J21/06 ,  B01J23/83 ,  B01J23/866 ,  B01J23/882 ,  B01J23/883 ,  B01J23/89 ,  B01J23/8913 ,  B01J23/894 ,  B01J27/20 ,  B01J37/00 ,  B01J37/0217 ,  B01J37/0225 ,  B01J37/04 ,  B01J37/08 ,  B01J37/084 ,  B01J37/10 ,  B82B3/00 ,  C01B3/40 ,  C01B2203/0233 ,  C01B2203/0244 ,  C01B2203/0261 ,  C01B2203/1064 ,  C01B2203/107 ,  C01B2203/1094 ,  Y02P20/52

Abstract: The invention relates to a method for preparation of oxide-polymetallic catalysts containing platinum-group metals for steam-oxidative conversion to obtain carbon monoxide and hydrogen. The method comprises treatment of NiO and CO3O4 by solutions of Al, Ce, Zr nitrates and palladium (Pd(NH3)4Cl2), platinum (H2[PtCl6]·6H2O) and rhodium (H3[RhCl6]) compounds followed by drying, carbonization of the obtained material in a methane flow at 550° C., preparation of slurry from this material, pseudo-boehmite and tetraisopropoxysilane, filling foam nichrome pores with obtained material suspension, elimination of water at 80° C., calcinating during 3 hours in an atmosphere of argon at 1300° C., elimination of carbon by water vapors at 600° C. during 3 hours. The technical result is development of a highly efficient heterogeneous catalyst. 3 material claims, 7 tables, 4 examples.

Abstract translation: 本发明涉及一种制备含有铂族金属的氧化物 - 多金属催化剂用于蒸汽氧化转化以获得一氧化碳和氢气的方法。 该方法包括通过Al，Ce，Zr硝酸盐和钯（Pd（NH 3）4 Cl 2），铂（H 2 [PtCl 6]·6H 2 O）和铑（H 3 [RhCl 6]）化合物的溶液处理NiO和CO 3 O 4，然后干燥，碳化 的所得材料在550℃的甲烷流中，从该材料制备浆料，假勃姆石和四异丙氧基硅烷，用获得的材料悬浮液填充泡沫镍铬合金孔，在80℃下除去水，在3小时内煅烧 在1300℃的氩气气氛中，在600℃下在3小时内用水蒸气消除碳。 技术成果是开发高效的多相催化剂。 3件物料索赔，7份表，4份实例。

公开(公告)号：US20150314279A1

公开(公告)日：2015-11-05

申请号：US14649593

申请日：2013-12-05

Applicant: INVISTA NORTH AMERICA S.A.R.L.

Inventor： Thomas E. VOS

IPC: B01J31/18 ,  C07C253/10 ,  B01J37/00 ,  C07C253/30

CPC classification number: C07C253/10 ,  B01J31/185 ,  B01J37/00 ,  B01J2231/322 ,  B01J2531/847 ,  B01J2531/90 ,  C07C253/30 ,  C07C253/34 ,  C07C255/04

Abstract: The invention provides methods useful in the industrial scale process for hydrocyanation of butadiene to adiponitrile for recycle of unwanted byproduct 2-methyl-3-butenenitrile (2M3BN) by conversion to process intermediate pentenenitrile. The invention provides a process for generating catalysts useful for carrying out the hydrocyanation of butadiene to adiponitrile, the process comprising contacting the 2M3BN and a solution of a nickel-ligand catalyst in cis-2-pentenenitrile (cis-2PN), trans-2-pentenenitrile (trans-2PN), or a mixture thereof. The improved methods of the invention can provide improved catalyst solubility for bidentate ligands without a requirement for a Lewis acid catalyst promoter such as zinc chloride to be present.

Abstract translation: 本发明提供了用于将丁二烯氢化成己二腈的工业规模工艺中用于通过转化为中间体戊烯腈再循环不需要的副产物2-甲基-3-丁烯腈（2M 3 BN）的方法。 本发明提供了一种用于产生用于进行丁二烯至己二腈的氢氰化的催化剂的方法，该方法包括使2M3BN与镍 - 配位体催化剂在顺式-2-戊烯腈（顺式-2PN），反式-2- 戊烯腈（反式-2PN）或其混合物。 本发明的改进方法可以提供改进的二齿配体的催化剂溶解度，而不需要存在路易斯酸催化剂促进剂如氯化锌。

公开(公告)号：US09126191B2

公开(公告)日：2015-09-08

申请号：US12962490

申请日：2010-12-07

Applicant: Qinghua Yin ,  Xiwang Qi ,  Maximilian A. Biberger

Inventor： Qinghua Yin ,  Xiwang Qi ,  Maximilian A. Biberger

IPC: B01J21/00 ,  B01J21/04 ,  B01J23/00 ,  B01J23/02 ,  B01J23/08 ,  B01J23/40 ,  B01J23/42 ,  B01J23/44 ,  B01J23/56 ,  B01J20/00 ,  B01J23/89 ,  B01J35/00 ,  B01J37/00 ,  B01J37/32 ,  B01J37/34 ,  B28B23/00 ,  B32B7/12 ,  B32B37/14 ,  B82Y30/00 ,  B82Y40/00 ,  C23C4/12 ,  B01J37/02

CPC classification number: B01J23/8926 ,  B01J21/04 ,  B01J23/42 ,  B01J23/44 ,  B01J23/464 ,  B01J35/0013 ,  B01J35/04 ,  B01J37/00 ,  B01J37/009 ,  B01J37/0211 ,  B01J37/32 ,  B01J37/349 ,  B28B23/0087 ,  B32B7/12 ,  B32B37/14 ,  B82Y30/00 ,  B82Y40/00 ,  C23C4/134 ,  Y02T10/22

Abstract: Embodiments of present inventions are directed to an advanced catalyst. The advanced catalyst includes a honeycomb structure with an at least one nano-particle on the honeycomb structure. The advanced catalyst used in diesel engines is a two-way catalyst. The advanced catalyst used in gas engines is a three-way catalyst. In both the two-way catalyst and the three-way catalyst, the at least one nano-particle includes nano-active material and nano-support. The nano-support is typically alumina. In the two-way catalyst, the nano-active material is platinum. In the three-way catalyst, the nano-active material is platinum, palladium, rhodium, or an alloy. The alloy is of platinum, palladium, and rhodium.

Abstract translation: 本发明的实施方案涉及先进的催化剂。 先进的催化剂包括在蜂窝结构上具有至少一个纳米颗粒的蜂窝结构。 用于柴油发动机的先进催化剂是双向催化剂。 燃气发动机中使用的先进催化剂是三元催化剂。 在双向催化剂和三元催化剂中，至少一种纳米颗粒包括纳米活性材料和纳米支撑体。 纳米载体通常是氧化铝。 在双向催化剂中，纳米活性材料是铂。 在三元催化剂中，纳米活性材料是铂，钯，铑或合金。 该合金是铂，钯和铑。

公开(公告)号：US20150141236A1

公开(公告)日：2015-05-21

申请号：US14485545

申请日：2014-09-12

Applicant: SDCmaterials, Inc.

Inventor： Qinghua YIN ,  Xiwang QI ,  Maximilian A. BIBERGER

IPC: B01J37/34 ,  B01J21/04 ,  B01J23/46

CPC classification number: B01J23/8926 ,  B01J21/04 ,  B01J23/42 ,  B01J23/44 ,  B01J23/464 ,  B01J35/0013 ,  B01J35/04 ,  B01J37/00 ,  B01J37/009 ,  B01J37/0211 ,  B01J37/32 ,  B01J37/349 ,  B28B23/0087 ,  B32B7/12 ,  B32B37/14 ,  B82Y30/00 ,  B82Y40/00 ,  C23C4/134 ,  Y02T10/22

Abstract: Embodiments of present inventions are directed to an advanced catalyst. The advanced catalyst includes a honeycomb structure with an at least one nano-particle on the honeycomb structure. The advanced catalyst used in diesel engines is a two-way catalyst. The advanced catalyst used in gas engines is a three-way catalyst. In both the two-way catalyst and the three-way catalyst, the at least one nano-particle includes nano-active material and nano-support. The nano-support is typically alumina. In the two-way catalyst, the nano-active material is platinum. In the three-way catalyst, the nano-active material is platinum, palladium, rhodium, or an alloy. The alloy is of platinum, palladium, and rhodium.

Abstract translation: 本发明的实施方案涉及先进的催化剂。 先进的催化剂包括在蜂窝结构上具有至少一个纳米颗粒的蜂窝结构。 用于柴油发动机的先进催化剂是双向催化剂。 燃气发动机中使用的先进催化剂是三元催化剂。 在双向催化剂和三元催化剂中，至少一种纳米颗粒包括纳米活性材料和纳米支撑体。 纳米载体通常是氧化铝。 在双向催化剂中，纳米活性材料是铂。 在三元催化剂中，纳米活性材料是铂，钯，铑或合金。 该合金是铂，钯和铑。

公开(公告)号：US08992820B1

公开(公告)日：2015-03-31

申请号：US12962533

申请日：2010-12-07

Applicant: Qinghua Yin ,  Xiwang Qi ,  Maximilian A. Biberger ,  David Leamon

Inventor： Qinghua Yin ,  Xiwang Qi ,  Maximilian A. Biberger ,  David Leamon

IPC: B28B3/02

CPC classification number: H05K1/0306 ,  B01J23/42 ,  B01J23/8926 ,  B01J37/00 ,  B22F2001/0092 ,  B28B3/025 ,  B28B23/0081 ,  B28B23/0087 ,  B32B5/30 ,  B32B7/12 ,  B32B37/14 ,  B32B2037/1253 ,  B32B2262/0253 ,  B32B2264/104 ,  B32B2264/107 ,  B32B2307/558 ,  B32B2571/02 ,  B82Y30/00 ,  B82Y40/00 ,  C01B33/027 ,  C23C4/134 ,  C23C18/14 ,  F41H1/02 ,  F41H5/0471 ,  F41H5/0492 ,  H01B1/02 ,  H01L21/6835 ,  H01L23/64 ,  H01L2924/0002 ,  H05K1/16 ,  Y02E60/122 ,  Y02P70/54 ,  Y10T428/12576 ,  Y10T428/24983 ,  Y10T428/25 ,  Y10T428/252 ,  Y10T428/26 ,  Y10T428/28 ,  Y10T428/2916 ,  H01L2924/00

Abstract: A method of making ceramics is provided. The method comprises preparing a dispersion of a nano-material. A slurry of a ceramic matrix material is prepared. The nano-dispersion is mixed with the matrix slurry to form a nano-dispersion/slurry mixture. The nano-dispersion/slurry mixture is dried. The nano-dispersion/slurry mixture is pressed into a final manufacture comprising a granular structure including the nano-material bonded within and uniformly distributed throughout the granular structure. The manufacture comprises an increased fracture toughness compared with a conventional manufacture produced without bonding the nano-material within the granular structure. The nano-material has a size on the order of tens of nanometers. The matrix material has a size on the order of several micrometers. Five percent of the nano-dispersion/slurry mixture comprises the nano-material dispersion. Sintering is performed on the final form using a sintering process following the pressing step. The sintering process includes a hot isostatic pressing process.

Abstract translation: 提供了制造陶瓷的方法。 该方法包括制备纳米材料的分散体。 制备陶瓷基体材料的浆料。 将纳米分散体与基质浆料混合以形成纳米分散体/浆料混合物。 将纳米分散体/浆料混合物干燥。 将纳米分散体/浆料混合物压制成包括颗粒结构的最终制造，所述颗粒结构包括结合在整个颗粒结构内并均匀分布在整个颗粒结构内的纳米材料。 与不在颗粒结构内粘合纳米材料而制造的常规制造相比，该制造方法具有增加的断裂韧性。 纳米材料的尺寸约为数十纳米。 基质材料具有几微米量级的尺寸。 5％的纳米分散体/浆料混合物包含纳米材料分散体。 使用压制步骤之后的烧结工艺在最终形式上进行烧结。 烧结过程包括热等静压法。

公开(公告)号：US08900536B2

公开(公告)日：2014-12-02

申请号：US13975073

申请日：2013-08-23

Applicant: Cristal USA Inc.

Inventor： Steve M. Augustine ,  David M. Chapman ,  Dennis F. Clark

IPC: B01D53/56 ,  B01D53/86 ,  B01J8/00 ,  C01B21/00 ,  B01J37/30 ,  B01J27/198 ,  B01J27/19 ,  B01J27/182 ,  B01J21/00 ,  B01J21/04 ,  B01J23/02 ,  B01J27/199 ,  B01J23/28 ,  B01J21/06 ,  B01J27/051 ,  B01J35/10 ,  B01J37/02

CPC classification number: B01J23/28 ,  B01D53/565 ,  B01D53/9418 ,  B01D2255/20707 ,  B01D2255/20769 ,  B01D2255/30 ,  B01J21/063 ,  B01J23/22 ,  B01J27/051 ,  B01J27/19 ,  B01J27/199 ,  B01J35/1014 ,  B01J37/00 ,  B01J37/0201 ,  B01J2523/00 ,  B01J2523/41 ,  B01J2523/47 ,  B01J2523/68

Abstract: Catalyst support materials, catalysts, methods of making such and uses thereof are described. Methods of making catalyst support material include combining anatase titania slurry with i) a low molecular weight form of silica; and ii) a source of Mo to form a TiO2—MoO3—SiO2 mixture. Catalyst support material include from about 86% to about 94% weight anatase titanium dioxide; from about 0.1% to about 10% weight MoO3; and from about 0.1% to about 10% weight SiO2. Low molecular weight forms of silica include forms of silica having a volume weighted median size of less than 4 nm and average molecular weight of less than 44,000, either individually or in a combination of two or more thereof. Catalyst include such catalyst support material with from about 0.1 to about 3% weight of V2O5 and optionally from about 0.01% to about 2.5% weight P.

Abstract translation: 描述了催化剂载体材料，催化剂，制备方法和用途。 制备催化剂载体材料的方法包括将锐钛型二氧化钛浆料与i）低分子量形式的二氧化硅组合; 和ii）Mo的源以形成TiO 2 -MoO 3 -SiO 2混合物。 催化剂载体材料包括约86％至约94％重量的锐钛矿型二氧化钛; 约0.1重量％至约10重量％的MoO 3; 和约0.1％至约10％重量的SiO 2。 二氧化硅的低分子量形式包括体积加权中值大小小于4nm，平均分子量小于44,000的二氧化硅的形式，单独地或两种或更多种的组合。 催化剂包括这样的催化剂载体材料，其具有约0.1至约3重量％的V 2 O 5和任选的约0.01重量％至约2.5重量％的P.

公开(公告)号：US20140318318A1

公开(公告)日：2014-10-30

申请号：US14328360

申请日：2014-07-10

Applicant: SDCmaterials, Inc.

Inventor： FREDERICK P. LAYMAN ,  David Leamon

IPC: H01J37/32 ,  B22F1/00

CPC classification number: H01J37/32055 ,  B01J23/42 ,  B01J23/8926 ,  B01J37/00 ,  B22F1/0085 ,  B28B23/0087 ,  B32B7/12 ,  B32B37/14 ,  C23C4/134 ,  H05H1/42

Abstract: A plasma gun system comprising: a plasma gun comprising an outlet, wherein the plasma gun is configured to generate a plasma stream and provide the plasma stream to the outlet; and a plasma gun extension assembly configured to be coupled to the plasma gun, wherein the plasma gun extension assembly comprises an extension chamber and a port, the extension chamber having an interior diameter defined by a chamber wall and being configured to receive the plasma stream from the outlet of the plasma gun and to enable the plasma stream to expand upon entering the extension chamber, and the port being configured to introduce a powder to the expanded plasma stream at a location outside of the plasma gun.

Abstract translation: 一种等离子枪系统，包括：等离子体枪，其包括出口，其中所述等离子体枪被配置为产生等离子体流并将等离子流提供给所述出口; 以及等离子体枪延伸组件，其被配置为耦合到所述等离子体枪，其中所述等离子体枪延伸组件包括延伸室和端口，所述延伸室具有由室壁限定的内部直径，并且被配置为从 等离子体枪的出口并且使等离子体流在进入延伸室时能够膨胀，并且该端口构造成在等离子体枪外部的位置处将粉末引入到扩展的等离子体流中。

公开(公告)号：US20140200349A1

公开(公告)日：2014-07-17

申请号：US14342545

申请日：2012-09-20

Applicant: Dow Corning Corporation

Inventor： Kurt Brandstadt ,  Simon Cook ,  Avril Surgenor ,  Richard Taylor ,  Binh Nguyen ,  Ming-Shin Tzou

IPC: C07F13/00 ,  C07F7/08

CPC classification number: B01J31/2295 ,  B01J31/0272 ,  B01J31/22 ,  B01J31/24 ,  B01J31/2414 ,  B01J31/2433 ,  B01J37/00 ,  B01J2231/323 ,  B01J2531/16 ,  B01J2531/17 ,  B01J2531/46 ,  B01J2531/49 ,  B01J2531/56 ,  B01J2531/64 ,  B01J2531/74 ,  B01J2531/821 ,  B01J2531/827 ,  B01J2531/842 ,  B01J2531/845 ,  B01J2531/847 ,  C07C209/66 ,  C07C213/08 ,  C07C217/92 ,  C07D213/32 ,  C07D213/38 ,  C07D213/53 ,  C07D215/12 ,  C07D271/06 ,  C07D295/135 ,  C07D307/52 ,  C07D333/22 ,  C07D413/10 ,  C07D413/14 ,  C07F1/00 ,  C07F1/005 ,  C07F1/08 ,  C07F3/06 ,  C07F7/00 ,  C07F7/0805 ,  C07F7/0838 ,  C07F7/0872 ,  C07F7/0879 ,  C07F7/0889 ,  C07F7/0896 ,  C07F7/1804 ,  C07F7/1876 ,  C07F9/5045 ,  C07F9/60 ,  C07F11/005 ,  C07F13/00 ,  C07F13/005 ,  C07F15/0033 ,  C07F15/0046 ,  C07F15/02 ,  C07F15/065 ,  C08G77/08 ,  C09K3/00 ,  G07F13/00

Abstract: A composition contains (A) a hydrosilylation reaction catalyst and (B) an aliphatically unsaturated compound having an average, per molecule, of one or more aliphatically unsaturated organic groups capable of undergoing hydrosilylation reaction. The composition is capable of reacting via hydrosilylation reaction to form a reaction product, such as a silane, a gum, a gel, a rubber, or a resin. Ingredient (A) contains a metal-ligand complex that can be prepared by a method including reacting a metal precursor and a ligand.

Abstract translation: 组合物含有（A）氢化硅烷化反应催化剂和（B）具有每分子平均能够进行氢化硅烷化反应的一种或多种脂族不饱和有机基团的脂族不饱和化合物。 组合物能够通过氢化硅烷化反应反应形成反应产物，例如硅烷，胶，凝胶，橡胶或树脂。 成分（A）含有可以通过使金属前体和配体反应的方法制备的金属 - 配体络合物。

公开(公告)号：US20140127093A1

公开(公告)日：2014-05-08

申请号：US14111673

申请日：2012-04-12

Applicant: Kyung Byung Yoon ,  Hyun Sung Kim

Inventor： Kyung Byung Yoon ,  Hyun Sung Kim

IPC: B01D53/22 ,  B01J37/02 ,  B01J37/00 ,  B01J15/00

CPC classification number: B01D53/22 ,  B01D69/10 ,  B01D69/145 ,  B01D71/36 ,  B01D71/52 ,  B01J15/005 ,  B01J37/00 ,  B01J37/0242 ,  C01B3/042 ,  C01B3/503 ,  C01B3/505 ,  C01B2203/0405 ,  C01B2203/061 ,  C01B2203/066 ,  C01B2203/068 ,  Y02E60/364

Abstract: The present application relates to a hydrogen ion transport membrane, which is formed by using a porous thin film having a plurality of holes which are regularly aligned, a membrane for generating hydrogen, and a method for manufacturing the hydrogen ion transport membrane and the membrane for generating hydrogen.

Abstract translation: 本申请涉及通过使用具有规则排列的多个孔的多孔薄膜和用于产生氢的膜形成的氢离子传输膜，以及用于制造氢离子迁移膜和膜的方法 产生氢气。