COMBUSTION PROCESS FOR FUEL CONTAINING VANADIUM COMPOUNDS
    21.
    发明申请
    COMBUSTION PROCESS FOR FUEL CONTAINING VANADIUM COMPOUNDS 有权
    含有VANADIUM化合物的燃料的燃烧过程

    公开(公告)号:US20150184853A1

    公开(公告)日:2015-07-02

    申请号:US14414860

    申请日:2013-07-22

    Applicant: ITEA S.p.A.

    Abstract: Oxycombustion process wherein low ranking, gaseous, liquid, solid, optionally solid melting hydrocarbon fractions are used as fuels, having a vanadium content in an amount by weight from 50 to 5,000 ppm or higher, for producing energy, wherein magnesium is added as oxide, or as a water-soluble salt, the combustor being refractored and isotherm or quasi isotherm, flameless, working at temperatures comprised between 1,250° C. and 1,450° C. and under pressurized conditions, wherein the oxidant is oxygen, the oxidant being used in admixture with water or steam such that the ratio by moles oxidant:(water-steam) is comprised between about 1:0.4 and about 1:3 or the oxidant is used in admixture with flue gases recycled from the flue gases outletting the energy recovery equipments, wherein the water amount is higher than 30% by volume, optionally by adding water, the molar ratio oxidant:(water/steam) in flue gases being comprised from about 1:0.4 to about 1:3; the low ranking hydrocarbon fraction containing vanadium is fed in admixture with water or steam, such that the amount of water/steam in the mixture is at least 30% by weight with respect to the hydrocarbon fraction.

    Abstract translation: 使用低等级的气态,液态,固体,任选的固体熔融烃馏分作为燃料,其钒含量为50-5000ppm或更高的重量,用于产生能量,其中镁作为氧化物加入, 或作为水溶性盐,燃烧器被折射和等温或准等温线,无焰,在温度为1250℃至1450℃之间并在加压条件下工作,其中氧化剂为氧,氧化剂用于 与水或蒸汽混合,使得氧化剂的摩尔比(水蒸气)为约1:0.4至约1:3,或氧化剂与废气再循环的废气混合使用,出口能量回收设备 ,其中水量高于30体积%,任选地通过加入水,烟道气中的氧化剂:(水/蒸汽)的摩尔比为约1:0.4至约1:3; 含有钒的低级烃馏分与水或蒸汽混合进料,使得混合物中的水/蒸汽的量相对于烃馏分为至少30重量%。

    COMBUSTION PROCESS FOR FUEL CONTAINING VANADIUM COMPOUNDS
    22.
    发明申请
    COMBUSTION PROCESS FOR FUEL CONTAINING VANADIUM COMPOUNDS 有权
    含有VANADIUM化合物的燃料的燃烧过程

    公开(公告)号:US20150153043A1

    公开(公告)日:2015-06-04

    申请号:US14416011

    申请日:2013-07-22

    Applicant: ITEA S.P.A.

    Abstract: Oxycombustion process for producing energy wherein low ranking gaseous, liquid, solid, optionally solid melting hydrocarbon fractions are used as fuels, having a vanadium content in amounts by weight from 50 to 5,000 ppm or higher, and alkaline metals Ma in amounts from 20 to 10,000 ppm, wherein magnesium is added as oxide, or as a magnesium compound forming MgO in the combustion process, or mixtures thereof and a silico-aluminate wherein the molar ratio SiO2:Al2O3 ranges from 2:1 to 6:1; the combustor being refractored, isotherm or quasi-isotherm, flameless, working at temperatures in the range 1,250°-1,450° C. and under pressurized conditions, wherein the oxidant being used in admixture with water or steam, the ratio by moles oxidant:(water/steam) being comprised between about 1:0.4 and about 1:3, or the oxidant is used in admixture with flue gases recycled from the flue gases outletting the energy recovery equipments, wherein the water/steam amount is higher than 30% by volume, optionally by adding water to the recycled flue gases, the molar ratio oxidant:(water/steam) in flue gases being comprised from about 1:0.4 to about 1:3; the hydrocarbon fraction being fed in admixture with water or steam, the amount of water/steam being at least 30% by weight with respect to the hydrocarbon fraction.

    Abstract translation: 用于生产能量的氧燃烧方法,其中使用低等级的气态,液体,固体,任选地固体熔融烃馏分作为燃料,其钒含量以重量计为50至5,000ppm或更高,碱金属Ma的量为20至10,000 ppm,其中镁作为氧化物加入,或作为在燃烧过程中形成MgO的镁化合物,或其混合物和硅铝酸盐,其中SiO 2 :Al 2 O 3的摩尔比为2:1至6:1; 燃烧器被折射,等温或准等温线,无焰,在1,250°-1,450℃的温度和加压条件下工作,其中氧化剂与水或蒸汽混合使用,摩尔氧化剂的比例:( 水/蒸汽)在约1:0.4至约1:3之间,或者氧化剂与从排出能量回收设备的烟道气再循环的废气混合使用,其中水/蒸汽量高于30% 任选地通过向回收的烟道气中加入水,烟道气中的氧化剂(水/蒸汽)的摩尔比为约1:0.4至约1:3; 烃馏分与水或蒸汽混合进料,水/蒸汽的量相对于烃馏分为至少30重量%。

    Fuel Borne Catalysts for Sulfur Rich Fuels
    23.
    发明申请
    Fuel Borne Catalysts for Sulfur Rich Fuels 审中-公开
    用于富硫燃料的燃料催化剂

    公开(公告)号:US20140298714A1

    公开(公告)日:2014-10-09

    申请号:US13856873

    申请日:2013-04-04

    Applicant: Barry Sprague

    Inventor: Barry Sprague

    CPC classification number: C10L1/1216 C10L10/02 C10L2270/026

    Abstract: Fuel Borne Catalysts of use in High Sulfur Fuels are disclosed, where formulations may include any number of suitable platinum group metals, transition metals, rare earth metals, and alkaline earth metals, including platinum, palladium, iron, manganese, cerium, yttrium, lithium, sodium, calcium, strontium, vanadium, silver and combinations thereof.

    Abstract translation: 公开了用于高硫燃料的燃料催化剂,其中制剂可以包括任何数量的合适的铂族金属,过渡金属,稀土金属和碱土金属,包括铂,钯,铁,锰,铈,钇,锂 ,钠,钙,锶,钒,银及其组合。

    METHOD OF OPERATING A COMBUSION INSTALLATION AND USE OF SUCH A METHOD FOR INHIBITING VANADIUM CORROSION
    25.
    发明申请
    METHOD OF OPERATING A COMBUSION INSTALLATION AND USE OF SUCH A METHOD FOR INHIBITING VANADIUM CORROSION 审中-公开
    操作燃烧安装的方法和使用这种抑制钒酸盐腐蚀的方法

    公开(公告)号:US20130213282A1

    公开(公告)日:2013-08-22

    申请号:US13877339

    申请日:2011-10-04

    CPC classification number: C10L1/12 C10L1/1216 C10L1/1233 C10L1/1291 F23J7/00

    Abstract: A method of operating a thermal installation other than a gas turbine and use of such a method for inhibiting vanadic corrosion is disclosed herein. Embodiments of the invention relate to a method of operating a thermal installation comprising a combustion chamber fed with a fuel contaminated with vanadium, with sulfur and possibly with sodium. The combustion chamber is also fed with boron and with magnesium, in quantities such that the magnesium molar ratio m=MgO/V2O5 and the boron molar ratio b=B2O3/V2O5 satisfy the conditions (i) m≧2+b; (ii) m≦3+2b; (iii) b≧0.5 and (iv) b≦2, so that the combustion products comprise magnesium vanadate, mixed magnesium boron oxide and possibly sodium borate.

    Abstract translation: 本文公开了操作燃气轮机以外的热设备的方法以及使用这种抑制钒腐蚀的方法。 本发明的实施例涉及一种操作热设备的方法,该热设备包括燃烧室,该燃烧室供给被污染了钒的燃料,硫和可能的钠。 燃烧室还用硼和镁进料,其量使得镁摩尔比m = MgO / V2O5和硼摩尔比b = B2O3 / V2O5满足条件(i)m> = 2 + b; (ii)m @ 3 + 2b; (iii)b> = 0.5和(iv)b @ 2,使得燃烧产物包含钒酸镁,混合的镁氧化硼和可能的硼酸钠。

    Fuel compositions exhibiting improved fuel stability
    27.
    发明授权
    Fuel compositions exhibiting improved fuel stability 失效
    显示燃料稳定性提高的燃料组合物

    公开(公告)号:US07572303B2

    公开(公告)日:2009-08-11

    申请号:US10722063

    申请日:2003-11-24

    Applicant: William C. Orr

    Inventor: William C. Orr

    Abstract: A fuel composition of the present invention exhibits minimized hydrolysis and increased fuel stability, even after extended storage at 65° F. for 6-9 months. The composition, which is preferably not strongly alkaline (3.0 to 10.5), is more preferably weakly alkaline to mildly acidic (4.5 to 8.5) and most preferably slightly acidic (6.3 to 6.8), includes a lower dialkyl carbonate, a combustion improving amount of at least one high heating combustible compound containing at least one element selected from the group consisting of aluminum, boron, bromine, bismuth, beryllium, calcium, cesium, chromium, cobalt, copper, francium, gallium, germanium, iodine, iron, indium, lithium, magnesium, manganese, molybdenum, nickel, niobium, nitrogen, phosphorus, potassium, palladium, rubidium, sodium, tin, zinc, praseodymium, rhenium, silicon, vanadium, or mixture, and a hydrocarbon base fuel.

    Abstract translation: 本发明的燃料组合物即使在65°F下延长储存6-9个月之后,表现出最小化的水解和增加的燃料稳定性。 优选不强碱性(3.0〜10.5)的组合物更优选弱碱性至弱酸性(4.5〜8.5),最优选微酸性(6.3〜6.8),包括低级碳酸二烷基酯,燃烧改善量 含有选自铝,硼,溴,铋,铍,钙,铯,铬,钴,铜,ium,镓,锗,碘,铁,铟的至少一种元素的至少一种高加热可燃化合物, 锂,镁,锰,钼,镍,铌,氮,磷,钾,钯,铷,钠,锡,锌,镨,铼,硅,钒或混合物,以及烃类燃料。

    Fuel composition in fuel cartridges for DMFCs
    28.
    发明授权
    Fuel composition in fuel cartridges for DMFCs 有权
    用于DMFC的燃料盒中的燃料组成

    公开(公告)号:US07314493B2

    公开(公告)日:2008-01-01

    申请号:US10688711

    申请日:2003-10-17

    Abstract: Fuel mixtures for direct methanol fuel cells are disclosed. The fuels include methanol and additives that react with water to produce methanol and other easily electro-oxidizable compounds including dimethyloxymethane, methylorthoformate, tetramethylorthocarbonate, trimethylborate, and tetramethylorthosilicate. Other additives to improve safety and efficiency of the fuel cell include sulfonated activated carbon particles and metal hydrides, such as LiAlH4, NaBH4, LiBH4, (CH3)2 NHBH3, NaAlH4, B2H6, NaCNBH3, CaH2, LiH, NaH, KH or sodium bis (2-methoxyethoxy) dihydridaluminate.

    Abstract translation: 公开了用于直接甲醇燃料电池的燃料混合物。 燃料包括与水反应以产生甲醇的甲醇和添加剂,以及其它易于电氧化的化合物,包括二甲氧基甲烷,原甲酸甲酯,原碳酸四甲酯,硼酸三甲酯和原硅酸四甲酯。 提高燃料电池的安全性和效率的其它添加剂包括磺化活性炭颗粒和金属氢化物,例如LiAlH 4,NaBH 4,LiBH 4,/ >,(CH 3 3)2 NHBH 3,NaAlH 4,B 2, H 6,NaCNBH 3,CaH 2,LiH,NaH,KH或双(2-甲氧基乙氧基)二氢铝酸钠。

    Fuel additive
    30.
    发明授权
    Fuel additive 失效
    燃料添加剂

    公开(公告)号:US4482352A

    公开(公告)日:1984-11-13

    申请号:US586408

    申请日:1984-03-05

    Abstract: A novel nonacidic fuel additive which is soluable in gasoline, diesel fuels and other liquid aliphatic hydrocarbons, and which comprises the product produced by mixing ketone peroxides, ketones, a Group III metal, an alcohol, and borontrifloride, or liquid cobalt, or a chlorobenzine. The fuel additive further comprises a ketone solvent, said ketones preferrably being methyl ethyl ketones and their peroxides and solvents. The fuel additive of the present invention, serves to increase power output, lower the ignition point of the carrier fuel, increase mileage, and, especially when used with diesel, reduces the effect of cold temperatures on the viscosity, turbidity, and color of the diesel fuel to temperatures as severe as -40.degree. C.

    Abstract translation: 一种新型的非酸性燃料添加剂,其可溶于汽油,柴油燃料和其它液体脂族烃,并且包括通过混合酮过氧化物,酮,III族金属,醇和硼三氟化物或液体钴或氯代苯 。 燃料添加剂还包含酮溶剂,所述酮优选为甲基乙基酮及其过氧化物和溶剂。 本发明的燃料添加剂用于增加功率输出,降低载体燃料的点燃点,增加里程,特别是当与柴油一起使用时,降低了冷温度对粘度,浊度和颜色的影响 柴油燃料温度至-40℃。

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