公开(公告)号：US20070180761A1

公开(公告)日：2007-08-09

申请号：US10576898

申请日：2004-10-15

Applicant: Hiltrud Täubert ,  Wolfgang Haubold ,  Konrad Buhler ,  Torsten Meyer

Inventor： Hiltrud Täubert ,  Wolfgang Haubold ,  Konrad Buhler ,  Torsten Meyer

IPC: C10L1/18

CPC classification number: C08F8/14 ,  C08F8/00 ,  C08F8/32 ,  C10L1/143 ,  C10L1/1616 ,  C10L1/1691 ,  C10L1/1881 ,  C10L1/191 ,  C10L1/1963 ,  C10L1/1966 ,  C10L1/1973 ,  C10L1/1981 ,  C10L1/1985 ,  C10L1/2222 ,  C10L1/2225 ,  C10L1/224 ,  C10L1/2364 ,  C10L10/08 ,  C10L10/14 ,  C10M145/22 ,  C10M161/00 ,  C10M2205/022 ,  C10M2205/04 ,  C10M2209/062 ,  C10M2209/084 ,  C10M2209/086 ,  C10M2209/102 ,  C10M2217/024 ,  C10N2220/021 ,  C10N2220/023 ,  C10N2220/03 ,  C10N2230/08 ,  F17D1/16 ,  C08F210/02 ,  C08F255/026 ,  C08F222/06 ,  C08F212/12 ,  C08F212/08

Abstract: Mineral oil compositions with trace portions of additives contain as additive a comb polymer containing ester linkages, either based on a) ethylene-vinylester copolymers modified by hydroxy groups or glycidyl groups with molecular mass weight averages from 3000 to 50000 and an ethylene portion of 50 to 90 mass %, and b) partially imidated and/or partially esterified maleic anhydride copolymers, wherein in the comb polymer based on a) and b) the modified ethylene-vinylester copolymer component is connected by means of ester linkages to the partially imidated and/or partially esterified maleic anhydride copolymer component, or a comb polymer containing ester linkages based on c) ethylene-vinylester copolymers modified by acid and/or acid anhydride groups with molecular mass weight averages from 3000 to 50000 and an ethylene portion of 50 to 90 mass %, and d) polyalcohols partially esterified with C12-C40-monocarboxylic acids wherein in the comb polymer based on c) and d) the ethylene-vinylester copolymer component modified by acid and/or acid anhydride groups is connected by means of ester linkages with the polyalcohol component partially esterified with C2-C40-monocarboxylic acids. The mineral oil compositions are suitable as flowable media to be transported at low temperatures and as mineral oil fuels with high lubricity and flowability.

Abstract translation: 具有痕量部分添加剂的矿物油组合物含有作为添加剂的含有酯键的梳形聚合物，其基于a）通过羟基或缩水甘油基改性的乙烯 - 乙烯基酯共聚物，分子质量平均值为3000-50000，乙烯部分为50〜 90质量％，和b）部分酰亚胺化和/或部分酯化的马来酸酐共聚物，其中在基于a）和b）的梳型聚合物中，改性的乙烯 - 乙烯基酯共聚物组分通过酯键连接到部分酰亚胺化和/ 或部分酯化的马来酸酐共聚物组分，或含有酯键的梳形聚合物，基于c）通过酸和/或酸酐基改性的乙烯 - 乙烯基酯共聚物，分子质量平均值为3000-50000，乙烯部分为50-90质量％ ％，和d）与C 12 -C 40单 - 一元羧酸部分酯化的多元醇，其中在梳型聚合物中基于c）a 和d）通过酸和/或酸酐基团改性的乙烯 - 乙烯基酯共聚物组分通过酯键连接到与C 2 -C 40部分酯化的多元醇组分 单 - 羧酸。 矿物油组合物适合作为在低温下运输的可流动介质和具有高润滑性和流动性的矿物油燃料。

公开(公告)号：US20070173419A1

公开(公告)日：2007-07-26

申请号：US11703972

申请日：2007-02-08

Applicant: Stephen Mead ,  Rodney Cravey ,  Mohammad Rahman

Inventor： Stephen Mead ,  Rodney Cravey ,  Mohammad Rahman

IPC: C10M169/04

CPC classification number: C10L10/16 ,  C10L1/224 ,  C10L1/232 ,  C10L1/2364 ,  C10L10/14 ,  C10M149/06 ,  C10M2203/1006 ,  C10M2205/028 ,  C10M2207/2805 ,  C10M2207/401 ,  C10N2230/08 ,  C10M2209/086 ,  C10N2260/09

Abstract: The present invention generally relates to oil compositions, primarily to fuel oil and petroleum compositions produced there from susceptible to wax formation at low temperatures, to polymeric imides for use with such fuel oil compositions, and to methods for their manufacture.

Abstract translation: 本发明一般涉及油组合物，主要涉及在低温下易于形成蜡的燃料油和石油组合物，以及与这种燃料油组合物一起使用的聚合酰亚胺及其制备方法。

公开(公告)号：US20070130821A1

公开(公告)日：2007-06-14

申请号：US10576897

申请日：2004-10-15

Applicant: Hiltrud Täubert ,  Wolfgang Haubold ,  Erhard Brauer ,  Torsten Meyer ,  Irene Klimek ,  Dietrich Wense

Inventor： Hiltrud Täubert ,  Wolfgang Haubold ,  Erhard Brauer ,  Torsten Meyer ,  Irene Klimek ,  Dietrich Wense

IPC: C10L1/18

CPC classification number: C10L10/08 ,  C10L1/143 ,  C10L1/146 ,  C10L1/1817 ,  C10L1/1905 ,  C10L1/1915 ,  C10L1/1973 ,  C10L1/1983 ,  C10L1/2364

Abstract: An additive mixture as component of compositions of mineral oil as the main component and trace portions of an additive mixture contains the additive components a) ethylene-vinylester copolymers with molecular mass weight averages from 3000 to 50000 and an ethylene proportion of 50 to 90 mass %, and b) mixed esters of glycerine in which 50 to 80 mol % of the hydroxy groups are esterified with unsaturated C12-C40 monocarboxylic acids and 20 to 50 mol % of the hydroxy groups are esterified with partially imidated and/or partially esterified maleic anhydride copolymers, and/or c) partially and/or completely imidated copolymers consisting of maleic anhydride and α-methylstyrene with molecular mass number averages from 1500 to 15000 and at least one terminal group based on dimeric α-methyl styrene, and/or d) wax compositions based on natural starting materials of type d1) wax-like oligomeric esters based on glyceryl monostearate and dimeric acid and/or d2) wax esters with vaseline-like consistency, based on at least two different straight-chain and/or branched C14-C36-alcohols and dimeric acid whereby the content of the additive mixture in the mineral oil is 0.005 to 1 mass % and the mass proportion of the additive components a/b or a/c or a/d is in the range from 10:90 to 90:10, respectively. The mineral oil compositions are suitable as flowable media to be transported at low temperatures and as mineral oil fuels with high lubricity and flowability.

Abstract translation: 作为添加剂组合物的矿物油组成的添加剂混合物和添加剂混合物的痕量部分的添加剂混合物含有添加剂成分a）分子质量平均为3000〜50000，乙烯比例为50〜90质量％的乙烯 - 乙烯基酯共聚物， ，和b）甘油的混合酯，其中50-80摩尔％的羟基与不饱和C 12 -C 40单羧酸酯化和20-50摩尔％ 的羟基被部分亚酰化和/或部分酯化的马来酸酐共聚物酯化，和/或c）部分和/或完全酰亚胺化的共聚物，其由马来酸酐和α-甲基苯乙烯组成，分子量平均值为1500至15000，至少 基于二聚α-甲基苯乙烯的一个末端基团和/或d）基于d1型天然起始材料的蜡组合物基于单硬脂酸甘油酯和二聚酸的蜡状低聚酯和/或d2）蜡 基于至少两种不同的直链和/或支链C 14 -C 36 - 醇和二聚酸，其中含有凡士林样稠度的酯，由此添加剂的含量 矿物油中的混合物为0.005〜1质量％，添加成分a / b或a / c或a / d的质量比例分别为10:90〜90:10。 矿物油组合物适合作为在低温下运输的可流动介质和具有高润滑性和流动性的矿物油燃料。

公开(公告)号：US06969746B2

公开(公告)日：2005-11-29

申请号：US10748011

申请日：2003-12-30

Applicant: Matthias Krull ,  Werner Reimann ,  Wilhelm Zoller ,  Di Heinz Dieter Bühnen ,  Gerhard Bettermann

Inventor： Matthias Krull ,  Werner Reimann ,  Wilhelm Zoller ,  Di Heinz Dieter Bühnen ,  Gerhard Bettermann

IPC: C10L1/192 ,  B01J3/04 ,  B01J19/24 ,  C08F2/00 ,  C08F2/02 ,  C08F210/02 ,  C08F210/16 ,  C10L1/14 ,  C10L1/16 ,  C10L1/18 ,  C10L1/195 ,  C10L1/196 ,  C10L1/197 ,  C10L1/22

CPC classification number: B01J3/042 ,  B01J19/2415 ,  B01J2219/00168 ,  B01J2219/00184 ,  B01J2219/00186 ,  C08F210/02 ,  C08F210/16 ,  C10L1/143 ,  C10L1/1608 ,  C10L1/1616 ,  C10L1/1641 ,  C10L1/195 ,  C10L1/1955 ,  C10L1/1963 ,  C10L1/1966 ,  C10L1/1973 ,  C10L1/1985 ,  C10L1/221 ,  C10L1/224 ,  C10L1/2364 ,  C08F2/00 ,  C08F218/08 ,  C08F218/10 ,  C08F210/14

Abstract: Process for the preparation of ethylene copolymers, and their use as additives to mineral oil and mineral oil distillates.The invention relates to a process for the preparation of terpolymers of ethylene and at least 2 further olefinically unsaturated compounds by polymerization in a tubular reactor fitted with at least one side branch, wherein the fresh monomer components, which are introduced into the tubular reactor via the reactor inlet (the primary stream) or via the side branch or side branches (secondary stream or secondary streams), in each of the streams contain ethylene and at most one further olefinically unsaturated compound.

Abstract translation: 制备乙烯共聚物的方法及其作为矿物油和矿物油馏出物添加剂的用途。 本发明涉及一种通过在装有至少一个侧枝的管式反应器中聚合制备乙烯和至少2种其它烯属不饱和化合物的三元共聚物的方法，其中新鲜单体组分通过 反应器入口（主流）或经由侧分支或副分支（二级流或二级流）在每个流中含有乙烯和至多一种其它烯属不饱和化合物。

公开(公告)号：US20050181959A1

公开(公告)日：2005-08-18

申请号：US10779970

申请日：2004-02-17

Applicant: Carl Esche

Inventor： Carl Esche

IPC: C10L1/16 ,  C10L1/192 ,  C10L1/195 ,  C10L1/22 ,  C10L1/224 ,  C10L1/234 ,  C10L1/236 ,  C10L1/238 ,  C10L1/2383 ,  C10L1/2387 ,  C10L10/00 ,  C10M129/34 ,  C10M129/93 ,  C10M133/04 ,  C10M133/16 ,  C10M133/56 ,  C10M145/10 ,  C10M149/06 ,  C10M149/22 ,  C10M159/12 ,  C10M159/16 ,  C10M169/04 ,  C10N20/04 ,  C10N30/02 ,  C10N30/04 ,  C10N40/04 ,  C10N40/25

CPC classification number: C10L1/2387 ,  C10L1/2364 ,  C10L1/2366 ,  C10L1/238 ,  C10L1/2383 ,  C10L10/04 ,  C10L10/08 ,  C10M133/16 ,  C10M133/56 ,  C10M149/06 ,  C10M159/12 ,  C10M159/16 ,  C10M2215/08 ,  C10M2215/086 ,  C10M2217/024 ,  C10M2217/043 ,  C10N2220/021 ,  C10N2230/04 ,  C10N2230/06 ,  C10N2240/042 ,  C10N2240/045 ,  C10N2240/08 ,  C10N2240/102 ,  C10N2240/104

Abstract: A composition for use as an additive for fuels or lubricants. The composition includes a reaction product of a treated amine and a compound selected from the group consisting of hydrocarbyl succinic anhydrides, Mannich adducts derived from hydrocarbyl-substituted phenols reacted with formaldehydes, ethylene-propylene copolymers grafted with ethylenically unsaturated carboxylic groups, copolymers of unsaturated acids and polyolefins, and acid or ester functionalized hydrocarbon polymers. The reaction product is oil soluble and has a number average molecular weight ranging from about 900 to about 50,000 as determined by gel permeation chromatography. The treated amine includes an aliphatic or aromatic amine containing at least one primary or secondary amino group reacted with an aliphatic or aromatic nitrile and hydrogen.

Abstract translation: 用作燃料或润滑剂添加剂的组合物。 该组合物包括经处理的胺和选自烃基琥珀酸酐的化合物的反应产物，衍生自与甲醛反应的烃基取代的酚的曼尼希加成物，用烯属不饱和羧酸接枝的乙烯 - 丙烯共聚物，不饱和酸的共聚物 和聚烯烃，以及酸或酯官能化的烃聚合物。 反应产物是油溶性的，并且通过凝胶渗透色谱测定的数均分子量为约900至约50,000。 经处理的胺包括含有至少一个与脂族或芳族腈和氢反应的伯或仲氨基的脂族或芳族胺。

公开(公告)号：US20050000152A1

公开(公告)日：2005-01-06

申请号：US10495559

申请日：2002-11-02

Applicant: Matthias Krull ,  Martina Hess

Inventor： Matthias Krull ,  Martina Hess

IPC: C10L1/18 ,  C10L1/14 ,  C10L1/16 ,  C10L1/183 ,  C10L1/19 ,  C10L1/192 ,  C10L1/197 ,  C10L1/22 ,  C10L1/222 ,  C10L1/224 ,  C10L10/14 ,  C10L10/18

CPC classification number: C10L1/192 ,  C10L1/143 ,  C10L1/1616 ,  C10L1/191 ,  C10L1/1973 ,  C10L1/1981 ,  C10L1/1985 ,  C10L1/221 ,  C10L1/224 ,  C10L1/2364

Abstract: The invention relates to additives for middle distillates with a maximum sulfur content of 0.05 percent by weight, containing at least one fatty acid ester of alkoxylated polyols with at least 3 OH groups (A) and at least one alkylphenol-aldehyde resin (C).

Abstract translation: 本发明涉及最大硫含量为0.05重量％的中间馏分的添加剂，其含有至少一种具有至少3个OH基团（A）和至少一种烷基酚醛树脂（C）的烷氧基​​化多元醇的脂肪酸酯。

公开(公告)号：US20040107635A1

公开(公告)日：2004-06-10

申请号：US10310427

申请日：2002-12-05

Inventor： Cyrus Pershing Henry JR.

IPC: C10L001/24

CPC classification number: C10L1/146 ,  C10L1/1963 ,  C10L1/2225 ,  C10L1/2364 ,  C10L1/2437 ,  C10L1/2475

Abstract: It has been discovered that less expensive, and in some cases synergistically effective anti-static additive blends may be added to hydrocarbon fuels to improve the conductivity thereof. The blend includes an anti-static amount of at least one hydrocarbon soluble copolymer of an alkylvinyl monomer and a cationic vinyl monomer and an anti-static amount of at least one hydrocarbon soluble polysulfone copolymer of at least one olefin and sulfur dioxide. Optional ingredients include polymeric polyamines and aryl sulfonic acids.

Abstract translation: 已经发现，较便宜的，并且在一些情况下，协同有效的抗静电添加剂共混物可以加入到烃燃料中以提高其导电性。 共混物包括抗静电量的至少一种烷基乙烯基单体和阳离子乙烯基单体的可溶于烃的共聚物和至少一种至少一种至少一种烯烃和二氧化硫的可溶于烃的聚砜共聚物的抗静电量。 任选成分包括聚合多胺和芳基磺酸。

公开(公告)号：US20040006912A1

公开(公告)日：2004-01-15

申请号：US10458906

申请日：2003-06-11

Applicant: Clariant GmbH

Inventor： Matthias Krull

IPC: C08K005/10 ,  C10L001/18

CPC classification number: C10L10/08 ,  C10L1/143 ,  C10L1/1835 ,  C10L1/19 ,  C10L1/1905 ,  C10L1/1981 ,  C10L1/221 ,  C10L1/224 ,  C10L1/2364 ,  C10M169/04 ,  C10M169/044 ,  C10M2205/022 ,  C10M2207/282 ,  C10M2209/101 ,  C10N2220/024 ,  C10N2220/026 ,  C10N2230/06 ,  C10N2230/10 ,  C10N2230/43

Abstract: The present invention provides oily liquids comprising A) at least one ester of fatty acids whose carbon chain lengths are between 8 and 30 carbon atoms, and a monohydric C1-C5-alcohol, at least 50% of the fatty acid radicals containing at least one double bond, and B) at least one alkylphenol-aldehyde resin, obtainable by condensing (i) at least one alkylphenol having at least one C6-C24-alkyl or C6-C24-alkenyl radical and (ii) at least one aldehyde or ketone nullto a degree of condensation of between 2 and 50 alkylphenol units.

Abstract translation: 本发明提供油性液体，其包含A）至少一种碳链长度为8至30个碳原子的脂肪酸酯和一元C 1 -C 5醇，至少50％的脂肪酸​​基团含有至少一个 双键，和B）至少一种烷基酚醛树脂，可通过将（i）至少一种具有至少一个C 6 -C 24 - 烷基或C 6 -C 24 - 烯基的烷基酚和（ii）至少一种醛或酮 达到2至50个烷基酚单元的缩合度。

公开(公告)号：US06610111B2

公开(公告)日：2003-08-26

申请号：US09993590

申请日：2001-11-16

Applicant: Matthias Krull ,  Werner Reimann

Inventor： Matthias Krull ,  Werner Reimann

IPC: C10L118

CPC classification number: C10L1/143 ,  C10L1/14 ,  C10L1/1616 ,  C10L1/1824 ,  C10L1/1852 ,  C10L1/1855 ,  C10L1/1881 ,  C10L1/1883 ,  C10L1/1885 ,  C10L1/1888 ,  C10L1/19 ,  C10L1/191 ,  C10L1/1966 ,  C10L1/1981 ,  C10L1/221 ,  C10L1/2222 ,  C10L1/2225 ,  C10L1/224 ,  C10L1/2364 ,  C10L1/238 ,  C10L1/2383 ,  C10L1/2387 ,  C10L10/04 ,  C10L10/08 ,  C10L10/14

Abstract: The invention relates to low-temperature-stabilized additives for fuel oils having a sulfur content of up 0.05% by weight, comprising fatty acid mixtures of A1) from 1 to 99% by weight of at least one saturated mono- or dicarboxylic acid having from 6 to 50 carbon atoms, A2) from 1 to 99% by weight of at least one unsaturated mono- or dicarboxylic acid having from 6 to 50 carbon atoms, and B) at least one polar nitrogen-containing compound which is effective as paraffin dispersant in middle distillates, in an amount of from 0.01 to 90% by weight, based on the total weight of A1), A2) and B), and to the use of said mixtures for improving the lubrication properties of low-sulfur middle distillates.

Abstract translation: 本发明涉及具有高于0.05重量％硫含量的燃料油的低温稳定添加剂，其包含1至99重量％的至少一种饱和的单羧酸或二羧酸的脂肪酸混合物，其具有6 至少50个碳原子，A2）1至99重量％的至少一种具有6至50个碳原子的不饱和单羧酸或二羧酸，和B）至少一种极性含氮化合物，其在中间作为石蜡分散剂是有效的 基于A1），A2）和B）的总重量，0.01至90重量％的馏出物，以及所述混合物用于改善低硫中间馏分的润滑性能的用途。

公开(公告)号：US06599335B1

公开(公告)日：2003-07-29

申请号：US09706656

申请日：2000-11-06

Applicant: Matthias Krull ,  Markus Kupetz ,  Raimund Wildfang

Inventor： Matthias Krull ,  Markus Kupetz ,  Raimund Wildfang

IPC: C10L118

CPC classification number: C10L1/1973 ,  C08F210/00 ,  C08F210/02 ,  C10L1/143 ,  C10L1/1608 ,  C10L1/1616 ,  C10L1/195 ,  C10L1/1966 ,  C10L1/1985 ,  C10L1/221 ,  C10L1/224 ,  C10L1/2364 ,  C10M145/02 ,  C10M145/08 ,  C10M149/06 ,  C10M157/04 ,  C10M2205/00 ,  C10M2209/04 ,  C10M2209/06 ,  C10M2209/062 ,  C10M2209/086 ,  C10M2209/108 ,  C10M2215/08 ,  C10M2215/082 ,  C10M2215/12 ,  C10M2215/28 ,  C10M2217/024 ,  C10M2217/028 ,  C10M2217/06 ,  C08F218/04

Abstract: Copolymers based on ethylene and unsaturated carboxylic esters and their use as mineral oil additives. The invention relates to copolymers of low olefins and vinyl esters, containing a) from 85 to 97 mol % of bivalent structural units of the formula 1 —CH2—CR1R2—  1  in which R1 and R2, independently of one another, are hydrogen or methyl, and b) at least 3 mol % of bivalent structural units of the formula 2  in which R3 is saturated, branched C6-C16-alkyl which has a tertiary carbon atom, wherein R3 is bonded by its tertiary carbon atom to the carboxyl function. The copolymers according to the invention are used as flow improvers for mineral oil distillates.

Abstract translation: 基于乙烯和不饱和羧酸酯的共聚物及其作为矿物油添加剂的用途本发明涉及低级烯烃和乙烯基酯的共聚物，其包含a）85至97mol％的式1的二价结构单元，其中R 1和R 2， 相互独立的是氢或甲基，和b）至少3mol％的式2的二价结构单元，其中R 3是具有叔碳原子的饱和的支链C 6 -C 16 - 烷基，其中R 3通过其键合 叔碳原子与羧基官能团。根据本发明的共聚物用作矿物油馏出物的流动改进剂。