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    Process for the preparation of polyether polyols
    31.
    发明授权
    Process for the preparation of polyether polyols 失效
    制备聚醚多元醇的方法

    公开(公告)号：US06492565B2

    公开(公告)日：2002-12-10

    申请号：US09827655

    申请日：2001-04-06

    Applicant: Uwe Denninger ,  Jörg Hofmann ,  Pramod Gupta

    Inventor： Uwe Denninger ,  Jörg Hofmann ,  Pramod Gupta

    IPC: C07C4103

    CPC classification number: C08G65/2654 ,  B01J31/0211 ,  B01J31/0227 ,  B01J31/0228 ,  B01J31/0252 ,  B01J31/0255 ,  B01J31/0257 ,  B01J2231/48 ,  C07F5/069

    Abstract: The present invention relates to a process for the preparation of polyether polyols by the reaction of alkylene oxides and compounds containing active hydrogens, in the presence of specific Lewis acid metal compounds as catalysts, novel bis(perfluoroalkylsulfonic acid) compounds of Group 13 of the Periodic Table of the Elements, and to a process for the preparation thereof and the use thereof as catalysts for ring-opening polymerization of cyclic ethers.

    Abstract translation: 本发明涉及在特定的路易斯酸金属化合物作为催化剂的存在下，通过环氧烷和含有活性氢的化合物的反应制备聚醚多元醇的方法，所述周期的第13族的新的双（全氟烷基磺酸）化合物 表格，以及其制备方法及其作为环醚开环聚合的催化剂的用途。

    TRANSITION METAL COMPLEXES FOR ENANTIOSELECTIVE CATALYSIS OF CARBON-CARBON, CARBON-HETEROATOM, AND CARBON-HYDROGEN BOND FORMING REACTIONS
    36.
    发明申请
    TRANSITION METAL COMPLEXES FOR ENANTIOSELECTIVE CATALYSIS OF CARBON-CARBON, CARBON-HETEROATOM, AND CARBON-HYDROGEN BOND FORMING REACTIONS 审中-公开
    过渡金属络合物，用于碳碳，碳 - 杂交和碳氢键形成反应的选择性催化

    公开(公告)号：US20170044198A1

    公开(公告)日：2017-02-16

    申请号：US15243054

    申请日：2016-08-22

    Applicant: Kyle G. LEWIS ,  John A. GLADYSZ ,  Subrata K. GHOSH

    Inventor： Kyle G. LEWIS ,  John A. GLADYSZ ,  Subrata K. GHOSH

    IPC: C07F15/06 ,  B01J31/22 ,  B01J31/18

    CPC classification number: C07F15/065 ,  B01J31/0255 ,  B01J31/146 ,  B01J31/1805 ,  B01J31/22 ,  B01J31/2295 ,  B01J2231/32 ,  B01J2231/323 ,  B01J2231/341 ,  B01J2531/845 ,  C07B53/00 ,  C07C211/65 ,  C07F5/027

    Abstract: In some embodiments, the present disclosure pertains to a compound, comprising a transition metal complex having the formula Φ-[M (x,y)-L1 (w,v)-L2 (t,u)-L3]p+An−mZ−p-m. In an embodiment of the present disclosure Φ may be Λ. In another embodiment Φ may be Λ. In some embodiments of the present disclosure, M is a transition metal. In a related embodiment, p is an integer corresponding to the oxidation state of M. In some embodiments of the present disclosure, each of x, y, w, v, t, and u independently comprise R. In other embodiments, each of x, y, w, v, t, and u independently comprise S. In an embodiment of the present disclosure, each of L1, L2, and L3 independently is a ligand comprising a substituted diamine. In some embodiments, An− comprises a lipophilic anion, where m is from 1 to 3, and where Z− comprises an optional second anion.

    Abstract translation: 在一些实施方案中，本公开涉及包含具有式Φ-[M（x，y）-L1（w，v）-L2（t，u）-L3] p + An- mZ-pm。 在本公开的实施例中，Φ可以是Λ。 在另一个实施例中，Φ可以是Λ。 在本公开的一些实施方案中，M是过渡金属。 在相关实施方案中，p是对应于M的氧化态的整数。在本公开的一些实施方案中，x，y，w，v，t和u中的每一个独立地包含R.在其它实施方案中，x ，y，w，v，t和u独立地包括S.在本公开的实施方案中，L1，L2和L3中的每一个独立地是包含取代的二胺的配体。 在一些实施方案中，An-包含亲脂性阴离子，其中m为1至3，并且其中Z-包含任选的第二阴离子。

    METHOD FOR PRODUCING HYDROGEN GAS FROM FORMIC ACID
    37.
    发明申请
    METHOD FOR PRODUCING HYDROGEN GAS FROM FORMIC ACID 有权
    从酸性酸生产氢气的方法

    公开(公告)号：US20160009553A1

    公开(公告)日：2016-01-14

    申请号：US14772944

    申请日：2013-03-06

    Applicant: GRANIT S.A.

    Inventor： Weijia GAN ,  J. Paul DYSON ,  Gabor LAURENCZY

    IPC: C01B3/22 ,  B01J31/02 ,  B01J31/24

    CPC classification number: C01B3/22 ,  B01J23/462 ,  B01J31/0255 ,  B01J31/0267 ,  B01J31/24 ,  B01J37/0209 ,  B01J2531/821 ,  C01B2203/0277 ,  C01B2203/1047 ,  C01B2203/1064 ,  C01B2203/1211

    Abstract: A method for producing A hydrogen gas from formic acid, characterized in that at least one heterogeneous catalyst is used to transform the formic acid into hydrogen gas. The at least one heterogeneous catalyst contains heterogenised ruthenium. According to a first aspect of the invention, the at least one heterogeneous catalyst contains at least one hydrophilic phosphine ligand which is m-TPPTS (meta-trisulfonated triphenylphosphine). The at least one heterogeneous catalyst is preferably obtained by mixing an aqueous solution of RuCl3 with hydrophilic phosphine, firstly activated by carrying out a homogeneous reaction with formic acid and by adding at least one solid structure.

    Abstract translation: 一种从甲酸生产氢气的方法，其特征在于使用至少一种非均相催化剂将甲酸转化为氢气。 至少一种非均相催化剂含有异源化钌。 根据本发明的第一方面，所述至少一种非均相催化剂含有至少一种亲水性膦配体，其为m-TPPTS（间三磺化三苯基膦）。 所述至少一种非均相催化剂优选通过将RuCl 3的水溶液与亲水性磷化氢混合而获得，首先通过与甲酸进行均匀反应并加入至少一种固体结构来活化。

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