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公开(公告)号：US09839903B2
公开(公告)日：2017-12-12
申请号：US14262835
申请日：2014-04-28
Applicant: IFP ENERGIES NOUVELLES
Inventor： Thibault Alphazan , Audrey Bonduelle , Christele Legens , Pascal Raybaud , Christophe Coperet
IPC: B01J23/00 , B01J23/883 , C07C5/11 , C10G47/02 , C07C4/06 , B01J37/20 , B01J37/02 , B01J23/28 , B01J31/02 , B01J31/22 , C10G45/08 , C10G47/12 , B01J23/881 , B01J23/882 , C10G45/00 , C10G45/10 , B01J35/10 , B01J37/00
CPC classification number: B01J23/883 , B01J23/28 , B01J23/881 , B01J23/882 , B01J31/0211 , B01J31/0212 , B01J31/0228 , B01J31/2226 , B01J31/2234 , B01J35/10 , B01J35/1019 , B01J37/0009 , B01J37/0203 , B01J37/0205 , B01J37/0207 , B01J37/0213 , B01J37/20 , B01J2531/64 , B01J2531/847 , C07C4/06 , C07C5/11 , C10G45/00 , C10G45/08 , C10G45/10 , C10G47/02 , C10G47/12
Abstract: The invention concerns a process for the preparation of a catalyst for carrying out hydrogenation reactions in hydrotreatment and hydrocracking processes. Said catalyst is prepared from at least one mononuclear precursor based on molybdenum (Mo), in its monomeric or dimeric form, having at least one Mo═O or Mo—OR bond or at least one Mo═S or Mo—SR bond where [R=CxHy where x≧1 and (x−1)≦y≦(2x+1) or R=Si(OR′)3 or R=Si(R′)3 where R′=Cx′Hy′ where x′≧1 and (x′−1)≦y′≦(2x′+1)], and optionally from at least one promoter element from group VIII. Said precursors are deposited onto an oxide support which is suitable for the process in which it is used, said catalyst being dried at a temperature of less than 200° C. then advantageously being sulphurized before being deployed in said process.
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2.发明申请PROCESS FOR THE PREPARATION OF A CATALYST BASED ON TUNGSTEN FOR USE IN HYDROTREATMENT OR IN HYDROCRACKING 有权用于在水力发电或水力发电中使用的催化剂制备催化剂的方法公开(公告)号：US20140323779A1
公开(公告)日：2014-10-30
申请号：US14265655
申请日：2014-04-30
Applicant: IFP ENERGIES NOUVELLES
Inventor： Thibault ALPHAZAN , Audrey BONDUELLE , Christele LEGENS , Pascal RAYBAUD , Christophe COPERET
IPC: B01J27/051 , B01J27/047 , B01J27/049 , B01J31/26
CPC classification number: B01J31/26 , B01J23/30 , B01J23/888 , B01J31/0211 , B01J31/0212 , B01J31/0228 , B01J31/2226 , B01J31/2234 , B01J35/10 , B01J35/1019 , B01J37/0009 , B01J37/0203 , B01J37/0205 , B01J37/0207 , B01J37/0213 , B01J37/20 , B01J2531/64 , B01J2531/66 , B01J2531/847 , C07C2529/072 , C07C2529/076 , C10G45/00 , C10G45/08 , C10G47/12
Abstract: The invention concerns a process for the preparation of a catalyst based on tungsten intended for hydrotreatment or hydrocracking processes.The invention concerns a process for the preparation of a catalyst for carrying out hydrogenation reactions in hydrotreatment and hydrocracking processes. Said catalyst is prepared from at least one mononuclear precursor compound based on tungsten (W), in its monomeric or dimeric form, having at least one W═O or W—OR bond or at least one W═S or W—SR bond where [R═CxHy where x≧1 and (x−1)≦y≦(2x+1) or R═Si(OR′)3 or R═Si(R′)3 where R′═Cx′Hy′ where x′≧1 and (x′−1)≦y′≦(2×t+1)], optionally at least one Mo precursor and optionally at least one promoter element from group VIII. Said precursors are deposited onto an oxide support which is suitable for the process in which it is used, said catalyst advantageously being sulphurized before being deployed in said process.
Abstract translation: 本发明涉及制备用于加氢处理或加氢裂化方法的基于钨的催化剂的方法。 本发明涉及制备用于在加氢处理和加氢裂化过程中进行氢化反应的催化剂的方法。 所述催化剂由至少一种基于钨（W）的单体前体化合物制备，其单体或二聚体形式具有至少一个W = O或W-OR键或至少一个W = S或W-SR键，其中 [R = C×Hy，其中x≥1和（x-1）＆nlE; y＆nlE;（2x + 1）或R = Si（OR'）3或R = Si（R'）3，其中R'≡Cx'Hy' x'≥1和（x'-1）＆nlE; y'＆nlE;（2×t + 1）]，任选地至少一种Mo前体和任选地至少一种来自VIII族的启动子元件。 所述前体沉积在氧化物载体上，其适用于其使用的方法，所述催化剂有利地在所述方法部署之前进行硫化。
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公开(公告)号：US08735522B2
公开(公告)日：2014-05-27
申请号：US13580312
申请日：2011-02-16
Applicant: Shu Kobayashi , Hiroyuki Miyamura
Inventor： Shu Kobayashi , Hiroyuki Miyamura
CPC classification number: C07D455/04 , B01J23/52 , B01J31/0227 , B01J31/0228 , B01J31/165 , B01J31/226 , B01J35/0013 , B01J2231/326 , B01J2231/342 , B01J2231/346 , B01J2231/4205 , B01J2531/0222 , B01J2531/18 , B01J2531/35 , B01J2540/325 , B01J2540/345 , C07C45/75 , C07D491/22 , C07C49/82
Abstract: The present invention provides a Scandium catalyst that can be used in water or water-soluble organic solvent with no leaching of Scandium. Provided is a gold-polymer nanostructure-immobilized Scandium catalyst, which is formed by preparing, in liquid phase, a mixture comprising gold clusters with from 1 to 50 nm of diameter, disulfide monomer, sulfonic acid salt of disulfide and Lewis acid metal compound represented by ScY3, wherein Y is OSO2CF3 etc., and polymerizing the mixture in the presence of a radical polymerization initiator, wherein the disulfide monomer is represented by the formula below: CH2═CH—R1—S—S—R1—CH═CH2 wherein R1 represents a divalent hydrocarbon, which may contain an ether bond, and the sulfonic acid salt of disulfide is represented by the formula below: MO3S—R2—S—S—R2—SO3M wherein R2 represents a divalent hydrocarbon, which may contain an ether bond, and M represents an alkali metal. This catalyst is useful as a catalyst for aldol reactions, cyanolation reactions, allylation reactions, Michael reactions, Mannich reactions, Diels Alder reactions and Friedel Crafts reactions in water or water-soluble organic solvent.
Abstract translation: 本发明提供了可用于水或水溶性有机溶剂中的钪催化剂，而不会浸出钪。 提供了一种金 - 聚合物纳米结构固定的钪催化剂，其通过在液相中制备包含直径为1至50nm的金簇的混合物，二硫化物单体，二硫化物磺酸盐和路易斯酸金属化合物 其中Y是OSO 2 CF 3等，并且在自由基聚合引发剂存在下聚合混合物，其中二硫化物单体由下式表示：CH 2 = CH-R 1 -S-S-R 1 -CH = CH 2其中 R1表示可以含有醚键的二价烃，二硫化物的磺酸盐由下式表示：MO 3 S-R 2 -S-S-R 2 -SO 3 M其中R 2表示可以含有醚的二价烃 键，M表示碱金属。 该催化剂可用作醛醇反应，硅烷醇化反应，烯丙基化反应，迈克尔反应，曼尼希反应，狄尔斯阿尔德反应和弗里德尔·卡夫在水或水溶性有机溶剂中的反应的催化剂。
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4.发明授权Process for production of zinc toluenesulfonate, zinc toluenesulfonate, and process for production of carbamate 有权甲苯磺酸锌，甲苯磺酸锌的生产方法和氨基甲酸酯的生产方法公开(公告)号：US08664420B2
公开(公告)日：2014-03-04
申请号：US13517022
申请日：2011-01-07
Applicant: Kazuhiro Kosumi , Takeshi Fukuda , Masaaki Sasaki
Inventor： Kazuhiro Kosumi , Takeshi Fukuda , Masaaki Sasaki
IPC: C07F3/06 , C07C269/00
CPC classification number: C07C271/28 , B01J31/0228 , B01J31/2252 , B01J31/2256 , B01J2531/26
Abstract: A process for producing zinc toluenesulfonate comprising reacting a zinc compound comprising Zn(OH)2 with toluenesulfonic acid and/or a salt thereof in the presence of an alcohol having 1 to 20 carbon atoms in total at a temperature higher than 60° C.
Abstract translation: 一种生产甲苯磺酸锌的方法，包括在高于60℃的温度下，在含有1至20个碳原子的醇的存在下使包含Zn（OH）2的锌化合物与甲苯磺酸和/或其盐反应。
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公开(公告)号：US06906147B2
公开(公告)日：2005-06-14
申请号：US10102162
申请日：2002-03-20
Applicant: Yi-Feng Wang , Peter D. Phelps
Inventor： Yi-Feng Wang , Peter D. Phelps
CPC classification number: B01J31/2239 , B01J31/0214 , B01J31/0228 , B01J31/223 , B01J31/2243 , B01J2231/14 , B01J2531/46 , C07F7/003 , C08G63/82 , C08G63/85 , C08G63/87 , Y10T428/31786
Abstract: This invention relates to single-component and multi-component catalytic systems using aryl titanates. Aryl titanate compounds are useful as catalysts and co-catalysts in single-component and multi-component catalytic systems (e.g., for the polymerization of macrocyclic oligoesters and the depolymerization of polyesters). Multi-component catalytic systems using aryl titanates allow increased versatility in applications such as liquid molding.
Abstract translation: 本发明涉及使用芳基钛酸盐的单组分和多组分催化体系。 钛酸酯化合物可用作单组分和多组分催化体系中的催化剂和助催化剂（例如，用于大环低聚酯的聚合和聚酯的解聚）。 使用芳基钛酸盐的多组分催化体系允许在诸如液体成型的应用中增加多功能性。
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Patent Agency Ranking
公开(公告)号：US3450662A
公开(公告)日：1969-06-17
申请号：US3450662D
申请日：1966-11-18
Applicant: MONSANTO CO
Inventor： TIERNEY PAUL A
CPC classification number: B01J31/0228 , B01J31/0215 , B01J31/0252 , C08G69/20
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7.发明授权Hydrogen compounds of elements of the third and fourth main group of the periodic system and organo-substituted derivatives thereof 失效周期性体系的第三和第四主要元素的元素的氢化合物及其有机取代的衍生物
公开(公告)号：US3378344A
公开(公告)日：1968-04-16
申请号：US37627364
申请日：1964-06-18
Applicant: BAYER AG
Inventor： ELMAR-MANFRED HORN , KARL JOHN , KONARD LANG
IPC: B01J21/02 , B01J27/24 , B01J31/02 , B01J31/12 , B01J31/14 , C01B6/00 , C07F5/00 , C07F5/02 , C07F7/08 , C10L1/30
CPC classification number: C10L1/303 , B01J21/02 , B01J27/24 , B01J31/0228 , B01J31/146 , C01B6/00 , C07F5/00 , C07F5/02 , C07F7/0896
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8.发明申请公开(公告)号：US20130059999A1
公开(公告)日：2013-03-07
申请号：US13580312
申请日：2011-02-16
Applicant: Shu Kobayashi , Hiroyuki Miyamura
Inventor： Shu Kobayashi , Hiroyuki Miyamura
CPC classification number: C07D455/04 , B01J23/52 , B01J31/0227 , B01J31/0228 , B01J31/165 , B01J31/226 , B01J35/0013 , B01J2231/326 , B01J2231/342 , B01J2231/346 , B01J2231/4205 , B01J2531/0222 , B01J2531/18 , B01J2531/35 , B01J2540/325 , B01J2540/345 , C07C45/75 , C07D491/22 , C07C49/82
Abstract: The present invention provides a Scandium catalyst that can be used in water or water-soluble organic solvent with no leaching of Scandium. Provided is a gold-polymer nanostructure-immobilized Scandium catalyst, which is formed by preparing, in liquid phase, a mixture comprising gold clusters with from 1 to 50 nm of diameter, disulfide monomer, sulfonic acid salt of disulfide and Lewis acid metal compound represented by ScY3, wherein Y is OSO2CF3 etc., and polymerizing the mixture in the presence of a radical polymerization initiator, wherein the disulfide monomer is represented by the formula below: CH2═CH—R1—S—S—R1—CH═CH2 wherein R1 represents a divalent hydrocarbon, which may contain an ether bond, and the sulfonic acid salt of disulfide is represented by the formula below: MO3S—R2—S—S—R2—SO3M wherein R2 represents a divalent hydrocarbon, which may contain an ether bond, and M represents an alkali metal. This catalyst is useful as a catalyst for aldol reactions, cyanolation reactions, allylation reactions, Michael reactions, Mannich reactions, Diels Alder reactions and Friedel Crafts reactions in water or water-soluble organic solvent.
Abstract translation: 本发明提供了可用于水或水溶性有机溶剂中的钪催化剂，而不会浸出钪。 提供了一种金 - 聚合物纳米结构固定的钪催化剂，其通过在液相中制备包含直径为1至50nm的金簇的混合物，二硫化物单体，二硫化物磺酸盐和路易斯酸金属化合物 其中Y是OSO 2 CF 3等，并且在自由基聚合引发剂存在下聚合混合物，其中二硫化物单体由下式表示：CH 2 = CH-R 1 -S-S-R 1 -CH = CH 2其中 R1表示可以含有醚键的二价烃，二硫化物的磺酸盐由下式表示：MO 3 S-R 2 -S-S-R 2 -SO 3 M其中R 2表示可以含有醚的二价烃 键，M表示碱金属。 该催化剂可用作醛醇反应，硅烷醇化反应，烯丙基化反应，迈克尔反应，曼尼希反应，狄尔斯阿尔德反应和弗里德尔·卡夫在水或水溶性有机溶剂中的反应的催化剂。
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9.发明授权Magnetic nanoparticle-supported glutathione as a sustainable organocatalyst 失效磁性纳米粒子支持的谷胱甘肽作为可持续的有机催化剂公开(公告)号：US08324125B2
公开(公告)日：2012-12-04
申请号：US12553681
申请日：2009-09-03
Applicant: Rajender S. Varma , Vivek Polshettiwar
Inventor： Rajender S. Varma , Vivek Polshettiwar
IPC: C07F15/04 , C07F15/06 , C07C321/04 , C07D207/323 , C07D401/06 , C07D207/325
CPC classification number: B01J31/0271 , B01J31/0228 , B01J31/0254 , B01J35/0033 , B01J37/0209 , C07C227/10 , C07C323/60 , C07D207/323 , C07D207/325 , C07D405/06 , C07C229/12 , C07C229/14 , C07C229/18
Abstract: This invention relates to the use of nano-organocatalysts, and, more specifically, to the use of magnetic nanomaterial-supported organocatalysts. It is an object of the present invention to provide “green” catalysts and protocols. According to one embodiment of the invention, a nano-organocatalyst in the form of a magnetic nanomaterial-supported organocatalyst is provided. According to other embodiments of the invention, glutathione and cysteine are provided as organocatalysts and magnetic nanomaterial-supported glutathione and magnetic nanomaterial-supported cysteine are provided for use as nano-organocatalysts. According to another embodiment of the invention, a method of using a recyclable magnetic nanomaterial-supported organocatalyst using a totally benign aqueous protocol, without using any organic solvent in the reaction or during the workup, is provided. According to a further embodiment of the invention, a recyclable magnetic nanomaterial-supported organocatalyst for various organocatalytic reactions, including but not limited to Paal-Knorr reactions, aza-Michael addition and pyrazole synthesis, is provided.
Abstract translation: 本发明涉及纳米有机催化剂的用途，更具体地说，涉及使用磁性纳米材料负载的有机催化剂。 本发明的目的是提供绿色催化剂和方案。 根据本发明的一个实施方案，提供了纳米材料负载有机催化剂形式的纳米有机催化剂。 根据本发明的其它实施方案，提供谷胱甘肽和半胱氨酸作为有机催化剂，并提供磁性纳米材料负载的谷胱甘肽和磁性纳米材料负载的半胱氨酸用作纳米有机催化剂。 根据本发明的另一个实施方案，提供了使用完全良性水溶液方案使用可回收的磁性纳米材料负载的有机催化剂的方法，而不在反应中或在后处理中使用任何有机溶剂。 根据本发明的另一个实施方案，提供了用于各种有机催化反应的可回收的磁性纳米材料负载的有机催化剂，包括但不限于Paal-Knorr反应，aza-Michael加成和吡唑合成。
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公开(公告)号：US06624321B2
公开(公告)日：2003-09-23
申请号：US10277615
申请日：2002-10-22
Applicant: Uwe Denninger , Jörg Hofmann , Pramod Gupta
Inventor： Uwe Denninger , Jörg Hofmann , Pramod Gupta
IPC: C07F506
CPC classification number: C08G65/2654 , B01J31/0211 , B01J31/0227 , B01J31/0228 , B01J31/0252 , B01J31/0255 , B01J31/0257 , B01J2231/48 , C07F5/069
Abstract: The present invention relates to a process for the preparation of polyether polyols by the reaction of alkylene oxides and compounds containing active hydrogens, in the presence of specific Lewis acid metal compounds as catalysts, novel bis(perfluoroalkylsulfonic acid) compounds of Group 13 of the Periodic Table of the Elements, and to a process for the preparation thereof and the use thereof as catalysts for ring-opening polymerization of cyclic ethers.
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