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    Gold complexes
    2.
    发明授权
    Gold complexes 有权
    金色复合体

    公开(公告)号：US09464097B2

    公开(公告)日：2016-10-11

    申请号：US13580772

    申请日：2011-03-02

    Applicant: Steven P. Nolan

    Inventor： Steven P. Nolan

    IPC: C07F1/12 ,  B01J31/22 ,  B01J31/02 ,  B01J31/24

    CPC classification number: C07F1/12 ,  B01J31/0211 ,  B01J31/181 ,  B01J31/2273 ,  B01J31/24 ,  B01J2531/18 ,  C07C45/26 ,  C07C67/333 ,  C07C231/065 ,  C07C231/10 ,  C07C2601/08 ,  C07C2601/10 ,  C07D207/06 ,  C07D213/81 ,  C07F1/00

    Abstract: Gold (I) hydroxide complexes of the form Z—Au—OH and digold complexes of the form Z—Au-(μOH)—Au—Z where groups Z are two electron donors are provided. The groups Z may be carbenes, for example nitrogen containing heterocyclic carbenes (NHCs), phosphines or phosphites. The complexes can be used as catalysts, for example in reactions such as hydration of nitriles, skeletal arrangement of enynes, alkoxycyclization of enynes, alkyne hydration, the Meyer-Shuster reaction, 3,3′ rearrangement of allylic acetates, cyclization of propargylic acetates, Beckman rearrangements and hydroamination. The complexes can be used in medicine, for example in the treatment of cancer.

    Abstract translation: 提供Z-Au-OH形式的金（I）氢氧化物络合物和Z-Au-（μOH）-Au-Z形式的二价配合物，其中基团Z是两个电子给体。 基团Z可以是卡宾，例如含氮杂环卡宾（NHC），膦或亚磷酸酯。 络合物可以用作催化剂，例如在诸如腈水合，烯炔的骨架排列，烯炔的烷基环化，炔烃水合，Meyer-Shuster反应，烯丙基乙酸酯的3,3'重排，炔丙基乙酸酯的环化， 贝克曼重排和水文。 该复合物可用于医学中，例如用于治疗癌症。

    Process for production of ethers
    4.
    发明授权
    Process for production of ethers 失效
    醚的生产工艺

    公开(公告)号：US07314961B2

    公开(公告)日：2008-01-01

    申请号：US10542890

    申请日：2004-01-20

    Applicant: Hiroshige Ishino ,  Hideharu Iwasaki

    Inventor： Hiroshige Ishino ,  Hideharu Iwasaki

    IPC: C07C41/05 ,  C07C41/06

    CPC classification number: B01J31/0212 ,  B01J31/0211 ,  B01J31/0215 ,  B01J31/0239 ,  B01J31/0268 ,  B01J31/1805 ,  B01J2231/20 ,  B01J2531/824 ,  B01J2531/98 ,  C07C41/06 ,  C07C43/15

    Abstract: According to the present invention, a method of producing ethers, which includes subjecting a conjugated diene compound and an alcohol to a telomerization reaction in the presence of a composition containing a palladium compound, an isocyanide represented by the formula (I) R1R2R3CNC   (I) and a base represented by the formula (II) M(OR4)n   (II) as a catalyst is provided. According to the method of the present invention, by telomerization reaction of a conjugated diene compound and an alcohol, ethers can be produced industrially advantageously. (In the above-mentioned formulas, each symbol is as defined in the specification.)

    Abstract translation: 根据本发明，一种生产醚的方法，其包括在含有钯化合物，由式（I）表示的异氰酸酯的组合物存在下使共轭二烯化合物和醇进行调聚反应< line-formula description =“In-line Formulas”end =“lead”？> R＆lt; 1＆lt; 2＆gt; 2＆lt; 3＆gt; 3（I） ？in-line-formula description =“In-line Formulas”end =“tail”？>和由公式（II）表示的基数<？in-line-formula description =“In-line Formulas”end =“lead （II）<？in-line-formula description =“In-line Formulas”end =“tail”？> as a 提供催化剂。 根据本发明的方法，通过共轭二烯化合物和醇的调聚反应，可以在工业上有利地制备醚。 （在上述公式中，每个符号如说明书中所定义）

    Catalyst and process
    6.
    发明申请
    Catalyst and process 审中-公开
    催化剂和工艺

    公开(公告)号：US20060020099A1

    公开(公告)日：2006-01-26

    申请号：US10535046

    申请日：2003-11-12

    Applicant: Bruno Stengel ,  David Jenkins

    Inventor： Bruno Stengel ,  David Jenkins

    IPC: C08G18/00

    CPC classification number: B01J31/2213 ,  B01J31/0211 ,  B01J31/04 ,  B01J31/2234 ,  B01J2531/31 ,  B01J2531/46 ,  B01J2531/48 ,  B01J2531/49 ,  B01J2531/842 ,  B01J2531/845 ,  C07F7/003 ,  C08G18/222

    Abstract: The invention concerns an organometallic compound of formula RO-M(L1)X (L2)Y (L3)Z wherein M is a metal selected from titanium, zirconium, hafnium, iron (III), cobalt (III) or aluminium; L1 and L2 are each independently selected from a diketonate, an ester or amide of acetoacetic acid, a hydroxycarboxylic acid or ester thereof, R1COO— where R1 is substituted or unsubstituted C5-C30 branched or linear alkyl, substituted or unsubstituted aryl including polycyclic structures such as naphthyl or anthracyl, phosphate, phosphinate, phosphonate, siloxy or sulphonato, provided that when L1 is a ligand which forms two covalent bonds with the metal atom, and x=1 then y=0; L3 is selected from substituted or unsubstituted aryloxy, R2COO— where R2 is a linear or branched C6-C30 alkyl or a substituted or unsubstituted aryl, a polyoxyalkyl or hydroxyalkoxyalkylgroup; R is alkyl or hydroxy-alkyl hydroxyalkoxyalkyl, or (hydroxy)polyoxyalkyl group, x, y and z are each either 0 or 1 (x+y+z)≦V−1, where V=the valency of the metal M. The invention further concerns compositions and processes for the manufacture of polyurethane articles using the organometallic compounds as catalysts to provide cured articles having a comparable performance to those produced using a commercial mercury-based catalyst.

    Abstract translation: 本发明涉及式RO-M（L 1）X（L 2））Y的有机金属化合物（L 2） 其中M是选自钛，锆，铪，铁（III），钴（III）或铝的金属; L 1和L 2各自独立地选自乙酰乙酸的二酮酸酯，酯或酰胺，羟基羧酸或其酯，R 1， > COO-其中R 1是取代或未取代的C 5 -C 30支链或直链烷基，取代或未取代的芳基，包括多环结构如 萘基或蒽基，磷酸酯，次膦酸酯，膦酸酯，甲硅烷氧基或磺酸酯，条件是当L 1是与金属原子形成两个共价键的配体时，x = 1，然后y = 0; L 3选自取代或未取代的芳氧基R 2 COO，其中R 2是直链或支链C 6 - 取代或未取代的芳基，聚氧烷基或羟基烷氧基烷基; R是烷基或羟基烷基羟基烷氧基烷基，或（羟基）聚氧烷基，x，y和z各自为0或1（x + y + z）≤= V-1，其中V =金属M的化合价。 本发明还涉及使用有机金属化合物作为催化剂制备聚氨酯制品的组合物和方法，以提供具有与使用商业汞基催化剂制备的那些性能相当的性能的固化制品。

    Preparation of dehydroxlated supports
    8.
    发明授权
    Preparation of dehydroxlated supports 失效
    脱氢化载体的制备

    公开(公告)号：US5391531A

    公开(公告)日：1995-02-21

    申请号：US258396

    申请日：1994-06-13

    Applicant: David G. Ward

    Inventor： David G. Ward

    IPC: B01J21/08 ,  B01J35/00 ,  B01J37/02 ,  C08F10/00 ,  B01J20/22

    CPC classification number: C08F10/00 ,  B01J21/08 ,  B01J31/0211 ,  B01J37/0207 ,  B01J35/1014 ,  B01J35/1023 ,  B01J35/1038

    Abstract: Dehydroxylated oxide (e.g. silica) particles are obtained by reacting oxide particles, having surface hydroxyl groups, with a dialkylcarbonate or diarylcarbonate. The resulting products have surface alkoxy or aryloxy groups and significantly reduced hydroxyl content. The treated oxide particles are especially suitable for use as catalyst supports, and especially as polyolefin catalyst supports.

    Abstract translation: 通过使具有表面羟基的氧化物颗粒与碳酸二烷基酯或碳酸二芳基酯反应获得脱羟基化氧化物（例如二氧化硅）颗粒。 所得产物具有表面烷氧基或芳氧基并显着降低羟基含量。 经处理的氧化物颗粒特别适合用作催化剂载体，特别是作为聚烯烃催化剂载体。

    Novel catalyst for hydrogenation of polymer and process for hydrogenating polymer with the catalyst
    9.
    发明授权
    Novel catalyst for hydrogenation of polymer and process for hydrogenating polymer with the catalyst 失效
    用于氢化聚合物的新型催化剂和用催化剂氢化聚合物的方法

    公开(公告)号：US4980421A

    公开(公告)日：1990-12-25

    申请号：US343580

    申请日：1989-04-26

    Applicant: Toshio Teramoto ,  Kunio Goshima ,  Mikio Takeuchi

    Inventor： Toshio Teramoto ,  Kunio Goshima ,  Mikio Takeuchi

    IPC: C08F8/04 ,  B01J31/02 ,  B01J31/12 ,  B01J31/14 ,  B01J31/22 ,  C08C19/02

    CPC classification number: C08C19/02 ,  B01J31/0211 ,  B01J31/128 ,  B01J31/143 ,  B01J31/2295 ,  B01J2231/645 ,  B01J2531/46

    Abstract: A hydrogenation catalyst consisting essentially of (A) at least one bis(cyclopentadienyl)titanium compound represented by the formula (1): ##STR1## wherein R.sup.1 and R.sup.2, which may be the same or different, represent halogen atoms, hydrocarbon groups, aryloxy groups, alkoxy groups or carbonyl groups, and (B) at least one lithium compound represented by the formula (2):R.sup.3 O--Li (2)wherein R.sup.3 represents a hydrocarbon group, or a reaction mixture of an organolithium compound with an alcoholic or phenolic hydroxyl group-containing compound, the (A) component/the (B) component molar ratio being 1/0.5 to 1/20, and optionally (C) at least one reducing organometallic compound selected from the group consisting of aluminum compounds, zinc compounds and magnesium compounds, the (A) component/the (C) component molar ratio being 1/0.5 to 1/20. The above hydrogenation catalyst is effectively applied to the hydrogenation of a polymer having olefinic double bonds to produce a hydrogenated polymer having a high degree of hydrogenation at a high hydrogenation rate with a high reproducibility.

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