公开(公告)号：US12024488B2

公开(公告)日：2024-07-02

申请号：US17755905

申请日：2020-11-04

Applicant: Evonik Operations GmbH

Inventor： Jens Elsner ,  Horst-Werner Zanthoff ,  Fikri Sen

IPC: C07C5/02 ,  B01J21/12 ,  B01J35/61 ,  C07C5/25 ,  C07C11/02

CPC classification number: C07C5/2512 ,  B01J21/12 ,  B01J35/613 ,  B01J35/615 ,  C07C11/02 ,  C07C2521/12

Abstract: A method for the isomerization of alpha-olefins to the corresponding internal olefins uses a heterogenous catalyst containing silicon-aluminum mixed oxide in a continuous fixed-bed operation mode.

公开(公告)号：US12011710B1

公开(公告)日：2024-06-18

申请号：US18344380

申请日：2023-06-29

Applicant: Chevron U.S.A. Inc.

Inventor： Xiaoying Ouyang ,  Viorel Duma ,  Alexander Kuperman ,  Ibrahim Uckung ,  Theodorus Ludovicus Michael Maesen ,  Axel Brait ,  Charles Wilson

IPC: B01J37/20 ,  B01J23/89 ,  B01J35/31 ,  B01J35/61 ,  B01J35/63 ,  B01J37/00 ,  B01J37/03 ,  B01J37/04 ,  B01J37/08 ,  C07C5/10 ,  C10G45/00 ,  C10G47/00 ,  C10G49/00

CPC classification number: B01J23/8993 ,  B01J35/31 ,  B01J35/615 ,  B01J35/633 ,  B01J37/0045 ,  B01J37/031 ,  B01J37/04 ,  B01J37/08 ,  B01J37/20 ,  C07C5/10 ,  C10G45/00 ,  C10G47/00 ,  C10G49/00 ,  C10G2300/1055 ,  C10G2300/1074 ,  C10G2300/4006 ,  C10G2300/4012 ,  C10G2300/4018 ,  C10G2300/42 ,  C10G2300/70

Abstract: Bulk catalysts comprised of nickel, molybdenum, tungsten and titanium and methods for synthesizing bulk catalysts are provided. The catalysts are useful for hydroprocessing, particularly hydrodesulfurization and hydrodenitrogenation, of hydrocarbon feedstocks.

公开(公告)号：US11992826B2

公开(公告)日：2024-05-28

申请号：US17414725

申请日：2019-12-10

Applicant: IFP Energies nouvelles

Inventor： Elodie Devers ,  Etienne Girard ,  Philibert Leflaive

IPC: B01J23/882 ,  B01J23/94 ,  B01J27/16 ,  B01J35/10 ,  B01J35/61 ,  B01J37/02 ,  B01J38/02 ,  B01J38/12 ,  B01J38/52 ,  C10G45/04

CPC classification number: B01J23/94 ,  B01J23/882 ,  B01J27/16 ,  B01J35/613 ,  B01J35/615 ,  B01J38/02 ,  B01J38/12 ,  B01J38/52 ,  C10G45/04 ,  C10G2300/207 ,  C10G2300/4081 ,  C10G2300/706

Abstract: A process for rejuvenating an at least partially spent catalyst resulting from a hydrodesulfurization process of a sulfur-containing olefinic gasoline cut, where the at least partially spent catalyst result is from a fresh catalyst a metal from group VIII, a metal from group VIb, and an oxide support, where the process includes



a) regenerating the at least partially spent catalyst in an oxygen-containing gas stream at a temperature between 350° C. and 550° C.,
b) the regenerated catalyst is brought into contact with an impregnation solution containing a compound containing a metal from group VIb, the molar ratio of the metal from group VIb added per metal from group VIb already present in the regenerated catalyst being between 0.15 and 2.5 mol/mol,
c) a drying stage is carried out at a temperature of less than 200° C., and
the use of the rejuvenated catalyst in a hydrodesulfurization process.

公开(公告)号：US11986813B2

公开(公告)日：2024-05-21

申请号：US17707115

申请日：2022-03-29

Applicant: ALBEMARLE CATALYSTS COMPANY B. V.

Inventor： Marcel Adriaan Jansen ,  Henk Jan Tromp ,  Bob Gerardus Oogjen ,  Sander Hendrikus Lambertus Thoonen ,  Jan Nieman ,  Wilhelmus Clemens Jozef Veerman

IPC: B01J37/00 ,  B01J21/02 ,  B01J23/85 ,  B01J23/882 ,  B01J23/883 ,  B01J27/188 ,  B01J35/61 ,  B01J35/63 ,  B01J35/64 ,  B01J37/02 ,  B01J37/20 ,  C10G45/08

CPC classification number: B01J37/0009 ,  B01J21/02 ,  B01J23/85 ,  B01J23/882 ,  B01J23/883 ,  B01J27/188 ,  B01J35/613 ,  B01J35/615 ,  B01J35/633 ,  B01J35/635 ,  B01J35/638 ,  B01J35/647 ,  B01J37/0203 ,  B01J37/0207 ,  B01J37/0219 ,  C10G45/08 ,  B01J37/20 ,  C10G2300/70

Abstract: A catalyst having at least one Group VIB metal component, at least one Group VIII metal component, a phosphorus component, and a boron-containing carrier component. The amount of the phosphorus component is at least 1 wt %, expressed as an oxide (P2O5) and based on the total weight of the catalyst, and the amount of boron content is in the range of about 1 to about 13 wt %, expressed as an oxide (B2O3) and based on the total weight of the catalyst. In one embodiment of the invention, the boron-containing carrier component is a product of a co-extrusion of at least a carrier and a boron source. A method for producing the catalyst and its use for hydrotreating a hydrocarbon feed are also described.

公开(公告)号：US11981622B2

公开(公告)日：2024-05-14

申请号：US17288382

申请日：2019-10-28

Applicant: SHOWA DENKO K.K.

Inventor： Wataru Oguchi ,  Gen Inoue ,  Toshihiro Kimura ,  Masafumi Koyano ,  Takuya Kuzutani

IPC: C07C29/17 ,  B01J21/08 ,  B01J23/30 ,  B01J35/61 ,  B01J35/64 ,  B01J37/04 ,  B01J37/08 ,  C07C29/04

CPC classification number: C07C29/172 ,  B01J21/08 ,  B01J23/30 ,  B01J35/615 ,  B01J35/647 ,  B01J35/651 ,  B01J35/653 ,  B01J37/04 ,  B01J37/082 ,  C07C29/04

Abstract: A method and catalyst for producing an alcohol, which method includes supplying water and a C2-C5 olefin to a reactor and performing hydration in a gas phase using a solid acid catalyst. The solid acid catalyst is one in which a heteropolyacid or a salt thereof is supported on a silica carrier. The silica carrier is obtained by kneading a fumed silica obtained by a combustion method, a silica gel obtained by a gel method, and a colloidal silica obtained by a sol-gel method or a water glass method; molding the resulting kneaded product; and calcining the resulting molded body.

公开(公告)号：US11981615B1

公开(公告)日：2024-05-14

申请号：US18183821

申请日：2023-03-14

Applicant: KING FAHD UNIVERSITY OF PETROLEUM AND MINERALS

Inventor： Aniz Chennampilly Ummer ,  Galal Atef Ahmed Nasser ,  Syed Ahmed Ali ,  Mohammed Ahmed Yahya Sanhoob ,  Akolade Idris Bakare

IPC: C07C1/12 ,  B01J6/00 ,  B01J21/16 ,  B01J35/61 ,  B01J35/63 ,  B01J37/00 ,  B01J37/02

CPC classification number: C07C1/12 ,  B01J6/001 ,  B01J21/16 ,  B01J35/612 ,  B01J35/613 ,  B01J35/615 ,  B01J35/633 ,  B01J37/0009 ,  B01J37/0201 ,  B01J37/0203 ,  B01J37/0236 ,  C07C2521/16

Abstract: A method for chemically reducing carbon dioxide (CO2) with a red mud catalyst composition is provided includes introducing a gaseous mixture of CO2 and H2 into a reactor containing particles of the red mud catalyst composition. The method further includes reacting at least a portion of the CO2 and H2 in the gaseous mixture in the presence of the red mud catalyst composition at a temperature of 200 to 800° C., and under a pressure ranging from 5 to 100 bar to form a gaseous product including a chemical reduction product of the CO2. A volume ratio of the CO2 to the H2 in the gaseous mixture is in a range of 1:10 to 10:1.

公开(公告)号：US20240123431A1

公开(公告)日：2024-04-18

申请号：US18285669

申请日：2021-07-05

Applicant: University of Ulsan Foundation for Industry Cooperation

Inventor： Byeong Kyu LEE ,  Milad JOURSHABANI

IPC: B01J23/28 ,  B01J23/22 ,  B01J23/30 ,  B01J27/24 ,  B01J35/39 ,  B01J35/61 ,  B01J35/63 ,  B01J35/64 ,  B01J37/08

CPC classification number: B01J23/28 ,  B01J23/22 ,  B01J23/30 ,  B01J27/24 ,  B01J35/39 ,  B01J35/615 ,  B01J35/635 ,  B01J35/651 ,  B01J37/08

Abstract: The present invention relates to a novel supramolecular self-assembly, a carbon nitride and a photocatalyst using same, and a manufacturing method therefor. The present invention can provide, by using a supramolecular self-assembly, a carbon nitride having a high N—C═N bonding ratio, a photocatalyst having excellent photocatalytic activity under visible light, and a manufacturing method therefor, the supramolecular self-assembly comprising: a plurality of complex units formed by hydrogen bonding two or more nitrogen-containing compounds to each other; and linker units connecting the plurality of complex units by hydrogen bonds, wherein the nitrogen-containing compounds and the linker units are each independently a —NH group and capable of hydrogen bonding with the —NH group, and the supramolecular self-assembly contains one or more heteroatoms selected from the group consisting of N, S, and O.

公开(公告)号：US20240360056A1

公开(公告)日：2024-10-31

申请号：US18756640

申请日：2024-06-27

Applicant: MEXICHEM AMANCO HOLDINGS S.A. DE C.V.

Inventor： Andrew P. SHARRATT

IPC: C07C17/087 ,  B01J23/26 ,  B01J35/61 ,  B01J37/03 ,  B01J37/26 ,  C07C17/10 ,  C07C17/20

CPC classification number: C07C17/087 ,  B01J23/26 ,  B01J37/03 ,  B01J37/26 ,  C07C17/10 ,  C07C17/206 ,  B01J35/613 ,  B01J35/615

Abstract: A new chromium-containing fluorination catalyst is described. The catalyst comprises an amount of zinc that promotes activity and from 0.1 to 8.0% by weight of the chromium in the catalyst based on the total weight of the chromium is present as chromium (VI). The use of the zinc-promoted, chromium-containing catalyst in a fluorination process in which a hydrocarbon or halogenated hydrocarbon is reacted with hydrogen fluoride in the vapour-phase at elevated temperatures is also described.

公开(公告)号：US20240359166A1

公开(公告)日：2024-10-31

申请号：US18682704

申请日：2022-02-08

Applicant: KOREA UNIVERSITY RESEARCH AND BUSINESS FOUNDATION

Inventor： Ki Bong LEE ,  Kwan Young LEE ,  Hyun Wook KIM

IPC: B01J23/89 ,  B01D53/94 ,  B01J21/04 ,  B01J23/42 ,  B01J23/63 ,  B01J35/30 ,  B01J35/61 ,  B01J35/63 ,  B01J37/02 ,  B01J37/08

CPC classification number: B01J23/894 ,  B01D53/9413 ,  B01J21/04 ,  B01J23/42 ,  B01J23/63 ,  B01J23/8926 ,  B01J35/394 ,  B01J35/615 ,  B01J35/635 ,  B01J37/0205 ,  B01J37/0236 ,  B01J37/024 ,  B01J37/08 ,  B01D2255/1021 ,  B01D2255/2065 ,  B01D2255/20761 ,  B01D2255/9207 ,  B01D2257/404 ,  B01D2258/012

Abstract: The present invention discloses a low-temperature nitrogen oxide adsorber based on a metal oxide-impregnated platinum/gamma-alumina catalyst and a method for preparing the same. According to the present invention, the present invention provides a method for preparing a passive nitrogen oxide adsorber for removing nitrogen oxide from a diesel engine, comprising the steps of: (a) impregnating a gamma-alumina support with an aqueous solution of the noble metal catalyst precursor and drying it repeatedly up to a preset number of times; (b) obtaining a noble metal/gamma-alumina catalyst by sintering at a predetermined temperature after step (a) is completed; (c) impregnating the noble metal/gamma-alumina catalyst with an aqueous solution of a metal oxide precursor and drying it repeatedly up to a preset number of times; and (d) preparing a passive nitrogen oxide adsorber composed of Ax-B/γ-alumina by sintering at a predetermined temperature after step (c) is completed, wherein the A is a noble metal catalyst, x is the mass percent of the noble metal catalyst, and the B is a metal.

公开(公告)号：US20240359156A1

公开(公告)日：2024-10-31

申请号：US18691984

申请日：2022-08-26

Applicant: ExxonMobil Technology and Engineering Company

Inventor： Allen W. Burton ,  Hilda B. Vroman

IPC: B01J20/18 ,  B01J20/30 ,  B01J29/70 ,  B01J35/61 ,  B01J35/63

CPC classification number: B01J20/18 ,  B01J20/3057 ,  B01J29/70 ,  B01J35/615 ,  B01J35/638

Abstract: Aluminosilicate zeolites, designated as EMM-63, characterized by a unique powder XRD pattern or unique connectivities, methods of making the same, and uses thereof.