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    Method of preparing chiral ketones from aldehydes
    42.
    发明授权
    Method of preparing chiral ketones from aldehydes 有权
    从醛制备手性酮的方法

    公开(公告)号：US09120721B2

    公开(公告)日：2015-09-01

    申请号：US14359847

    申请日：2012-12-13

    Applicant: Nanyang Technological University

    Inventor： Yonggui Chi ,  Bhoopendra Tiwari

    IPC: C07C211/00 ,  C07C205/00 ,  C07C207/00 ,  C07C221/00 ,  C07C201/12 ,  C07C205/02 ,  C07C205/44 ,  C07B41/06 ,  C07C225/14 ,  C07C225/16

    CPC classification number: C07C221/00 ,  C07B41/06 ,  C07C201/12 ,  C07C205/02 ,  C07C205/44 ,  C07C225/14 ,  C07C225/16

    Abstract: Present invention relates to a method of preparing a chiral α- or β-substituted ketone from the corresponding β- or γ-substituted aldehyde, wherein the ketone has formula (I), (III) or (V), and the corresponding aldehyde has formula (II), (IV) or (VI), respectively, the method comprising reacting the aldehyde of formula (II), (IV) or (VI) in the presence of an amine, oxygen and an organic solvent, wherein the reaction is carried out in the absence of a metal-based catalyst or a metal-based oxidant, wherein: R is H, a substituted or unsubstituted C1-C10 alkyl, substituted or unsubstituted C2-C15 alkenyl, substituted or unsubstituted C2-C15 alkynyl, substituted or unsubstituted C3-C15 cycloalkyl, substituted or unsubstituted C3-C15 cycloalkenyl, substituted or unsubstituted C3-C15 heterocycloalkyl, substituted or unsubstituted C3-C15 heterocycloalkenyl, substituted or unsubstituted C6-C15 aryl, or substituted or unsubstituted C6-C15 heteroaryl; and R′ is H, a substituted or unsubstituted C1-C10 alkyl, substituted or unsubstituted C2-C15 alkenyl, substituted or unsubstituted C2-C15 alkynyl, substituted or unsubstituted C3-C15 cycloalkyl, substituted or unsubstituted C3-C15 cycloalkenyl, substituted or unsubstituted C3-C15 heterocycloalkyl, substituted or unsubstituted C3-C15 heterocycloalkenyl, substituted or unsubstituted C6-C15 aryl, or substituted or unsubstituted C6-C15 heteroaryl.

    Abstract translation: 本发明涉及从相应的β-取代醛或γ-取代醛制备手性α-或β-取代的酮的方法，其中酮具有式（I），（III）或（V），和相应的 醛分别具有式（II），（IV）或（VI），所述方法包括在胺，氧和有机溶剂的存在下使式（II），（IV）或（VI）的醛反应，其中 该反应在不存在金属类催化剂或金属类氧化剂的情况下进行，其中：R为H，取代或未取代的C 1 -C 10烷基，取代或未取代的C 2 -C 15烯基，取代或未取代的C 2 -C 15 取代或未取代的C 3 -C 15环烯基，取代或未取代的C 3 -C 15环烯基，取代或未取代的C 3 -C 15杂环烷基，取代或未取代的C 3 -C 15杂环烯基，取代或未取代的C 6 -C 15芳基或取代或未取代的C 6 -C 15杂芳基 ; 取代或未取代的C 1 -C 15烷基，取代或未取代的C 2 -C 15烯基，取代或未取代的C 2 -C 15炔基，取代或未取代的C 3 -C 15环烷基，取代或未取代的C 3 -C 15环烯基，取代或未取代的 C 3 -C 15杂环烷基，取代或未取代的C 3 -C 15杂环烯基，取代或未取代的C 6 -C 15芳基或取代或未取代的C 6 -C 15杂芳基。

    DERIVATISATION OF CARBON
    43.
    发明申请
    DERIVATISATION OF CARBON 审中-公开
    碳的衍生物

    公开(公告)号：US20150197481A1

    公开(公告)日：2015-07-16

    申请号：US14665832

    申请日：2015-03-23

    Applicant: SCHLUMBERGER TECHNOLOGY CORPORATION

    Inventor： Fenglou Zou ,  Nathan Lawrence ,  Timothy Jones

    IPC: C07C201/12

    CPC classification number: C07C201/12 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/156 ,  C01B32/174 ,  C01B32/194 ,  C01B32/20 ,  C01B32/21 ,  C01B32/28 ,  C01B32/354 ,  G01N27/308

    Abstract: A molecular species is covalently attached to elemental carbon by exposing the carbon to a reaction mixture containing a strong base and a compound of the formulaor in which X denotes a covalently attached atom or group capable of forming an X− anion and each Z is a moiety comprising a plurality of atoms, but which does not have a hydrogen atom directly attached to the atom which itself is directly attached to the —CH2X or —CHX group. The carbon substrate may be graphite or carbon nanotubes.

    Abstract translation: 通过将碳暴露于含有强碱和下式化合物的反应混合物中，分子物质与元素碳共价连接，或其中X表示共价连接的能够形成X-阴离子的原子或基团，并且每个Z为 部分包含多个原子，但不具有与本身直接连接至-CH 2 X或-CHX基团的原子直接相连的氢原子。 碳衬底可以是石墨或碳纳米管。

    AZOLE DERIVATIVES, METHODS FOR PRODUCING THE SAME, INTERMEDIATE THEREOF, AGRO-HORTICULTURAL AGENTS
    50.
    发明申请
    AZOLE DERIVATIVES, METHODS FOR PRODUCING THE SAME, INTERMEDIATE THEREOF, AGRO-HORTICULTURAL AGENTS 审中-公开
    氨基酸衍生物，其生产方法，其中间体，农业生物代理

    公开(公告)号：US20140213794A1

    公开(公告)日：2014-07-31

    申请号：US14213240

    申请日：2014-03-14

    Applicant: KUREHA CORPORATION

    Inventor： Nobuyuki ARAKI ,  Toru YAMAZAKI ,  Nobuyuki KUSANO ,  Eiyu IMAI ,  Hisashi KANNO ,  Masaru MORI ,  Taiji MIYAKE

    IPC: C07D405/06 ,  C07C201/12 ,  C07C67/31

    CPC classification number: C07C67/31 ,  A01N37/10 ,  A01N43/50 ,  A01N43/653 ,  C07C201/12 ,  C07C2601/08 ,  C07D405/06

    Abstract: An azole derivative according to the invention is represented by Formula (I), wherein each of Ra and Rb denotes a hydrogen atom, or a C1-C6 alkyl group, a C2-C6 alkenyl group or a C2-C6 alkynyl group; Ra and Rb may be substituted with Xa or Xb which is a halogen atom; each of na and nb denotes 0 or the number of Xa- or Xb-substituted hydrogen atoms among the hydrogen atoms in Ra or Rb; each Y denotes a halogen atom, a C1-C4 alkyl group, a C1-C4 haloalkyl group, a C1-C4 alkoxy group, a C1-C4 haloalkoxy group, a phenyl group, a cyano group or a nitro group; m denotes 0 to 5; and A denotes a nitrogen atom or a methyne group. As a result, an azole derivative contained as an active ingredient in an agro-horticultural agent having an excellent controlling effect on diseases can be provided.

    Abstract translation: 根据本发明的唑衍​​生物由式（I）表示，其中R a和R b各自表示氢原子或C 1 -C 6烷基，C 2 -C 6烯基或C 2 -C 6炔基; Ra和Rb可以被Xa或Xb取代，Xb或Xb是卤素原子; na和nb中的每一个表示0或Ra或Rb中的氢原子中的X a或X b取代的氢原子的数目; 每个Y表示卤素原子，C1-C4烷基，C1-C4卤代烷基，C1-C4烷氧基，C1-C4卤代烷氧基，苯基，氰基或硝基; m表示0〜5; A表示氮原子或甲炔基。 结果，可以提供在对疾病具有优异控制作用的农业园艺剂中作为活性成分含有的唑衍生物。

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