公开(公告)号：US20200040215A1

公开(公告)日：2020-02-06

申请号：US16487954

申请日：2018-03-13

Applicant: SIKA TECHNOLOGY AG

Inventor： Edis KASEMI ,  Andreas KRAMER ,  Ursula STADELMANN ,  Urs BURCKHARDT

IPC: C09D163/00 ,  C08G59/50 ,  C08G59/18 ,  C08G59/24

Abstract: A process for preparing a curing agent for epoxy resins, in which an amine mixture including at least one parent amine of the formula (I) and at least one alkylated amine of the formula (II) is reacted or adducted with at least one glycidyl ether of the formula (III). The amine mixture is especially a reaction mixture from the partial alkylation of the amine of the formula (I). The process described enables, with low energy expenditure and high space-time yield, curing agents of low odor, low toxicity, low viscosity and high reactivity for epoxy resins and epoxy resin products that cure rapidly at ambient temperatures and especially also under cold conditions and at the same time enable high-quality coatings having an even, shiny surface.

公开(公告)号：US20190048127A1

公开(公告)日：2019-02-14

申请号：US15746911

申请日：2016-08-30

Applicant: SIKA TECHNOLOGY AG

Inventor： Edis KASEMI ,  Andreas KRAMER ,  Ursula STADELMANN ,  Urs BURCKHARDT

IPC: C08G59/50 ,  C08G59/18 ,  C09D163/00

Abstract: An epoxy resin composition, the curing components of which contain at least one amine of formula (I) and optionally at least one amine A which is, in particular, an adduct of a polyamine and an epoxide. The amine for formula (I) is used in particular in the form of a reaction product of the reductive alkylation of 1,2-ethylenediamine and an aldehyde or ketone. The epoxy resin composition is used in particular as a low-emission, room-temperature-curing epoxy-resin coating. It is characterised by good processibility, quick curing, high hardness, a nice surface and a low tendency to yellowing.

公开(公告)号：US20190002628A1

公开(公告)日：2019-01-03

申请号：US15752814

申请日：2016-09-16

Applicant: SIKA TECHNOLOGY AG

Inventor： Edis KASEMI ,  Andreas KRAMER ,  Ursula STADELMANN ,  Urs BURCKHARDT

IPC: C08G59/50 ,  C08G59/24 ,  C08G59/18 ,  C09D163/00

Abstract: The use of an amine of formula (I) as a component of a hardener for epoxy resins, hardeners for epoxy resins containing the amine of formula (I), and resultant epoxy resin compositions which can particularly be used as low-emission room-temperature-curing epoxy-resin coatings with high hardness and surface quality. The amine of formula (I) is low-odour and a very successful diluent for epoxy resin compositions. It is particularly obtained by reductive alkylation from 1,2-ethylenediamine or 1,2-propylenediamine and an aldehyde or ketone.

公开(公告)号：US20180079710A1

公开(公告)日：2018-03-22

申请号：US15558496

申请日：2016-03-23

Applicant: SIKA TECHNOLOGY AG

Inventor： Edis KASEMI ,  Andreas KRAMER ,  Ursula STADELMANN ,  Urs BURCKHARDT

IPC: C07C215/50 ,  C08G59/64 ,  C09D7/12 ,  C09D163/00

CPC classification number: C09J163/00 ,  B32B27/38 ,  C07C215/50 ,  C07C2601/14 ,  C08G59/245 ,  C08G59/36 ,  C08G59/4007 ,  C08G59/5026 ,  C08G59/5033 ,  C08G59/64 ,  C08K5/07 ,  C08K5/17 ,  C08L63/00 ,  C09D7/63 ,  C09D163/00

Abstract: An amine of formula (I) which is particularly suitable for use as a curing agent for epoxy resins. The amine of formula (I) is devoid of non-incorporable toxic phenols, and is low-viscosity and pale in colour. It allows the production of easily-workable, low-emission or emission-free epoxy resin products which cure rapidly even at relatively low ambient temperatures thus obtaining a high degree of hardness and a nice surface with hardly any yellowing. This is particularly suited to use in floor or top coatings.

公开(公告)号：US20170240688A1

公开(公告)日：2017-08-24

申请号：US15519307

申请日：2015-11-23

Applicant: SIKA TECHNOLOGY AG

Inventor： Andreas KRAMER ,  Urs BURCKHARDT

IPC: C08G18/83 ,  C08G18/48 ,  C08G18/75 ,  C09D175/08 ,  C08G18/10 ,  C08G18/22 ,  C09J175/08 ,  C08L75/08 ,  C08G18/76

CPC classification number: C08G18/837 ,  C08G18/10 ,  C08G18/227 ,  C08G18/4866 ,  C08G18/718 ,  C08G18/755 ,  C08G18/7621 ,  C08G65/336 ,  C08G2190/00 ,  C08L71/02 ,  C08L75/08 ,  C08L2205/025 ,  C09D175/08 ,  C09J175/08 ,  C08G18/289

Abstract: A composition containing two different silane-functional polymers, only one of the two polymers having terminal groups of formula (I). The composition has a surprisingly rapid skin forming time and low viscosity, crosslinks quickly even without the use of EHS-critical catalysts such as organotin compounds or DBU, and cures to a non-sticky material with good strength and elasticity. Also relates to a method for accelerating the curing of a silane-crosslinking composition by adding to it a further silane-functional polymer having terminal groups of formula (I).

公开(公告)号：US20170183444A1

公开(公告)日：2017-06-29

申请号：US15455865

申请日：2017-03-10

Applicant: SIKA TECHNOLOGY AG

Inventor： Edis KASEMI ,  Andreas KRAMER ,  Ursula STADELMANN ,  Urs BURCKHARDT

IPC: C08G59/56 ,  C08G59/18 ,  C09D163/00 ,  C08G59/22

CPC classification number: C08G59/56 ,  C08G59/184 ,  C08G59/223 ,  C08G2650/50 ,  C09D163/00

Abstract: Curing agents for epoxy resins, containing at least one adduct of a primary diamine and an aromatic monoepoxide, at least one primary diamine and at least one secondary diamine which is free of primary amino groups and free of hydroxyl groups, are disclosed. The curing agent is of low viscosity and cures, together with epoxy resins, rapidly and without blushing, even under damp, cold conditions, to form films of high hardness and low brittleness. It is particularly well suited for low-emission coatings that cure at room temperature.

公开(公告)号：US20170029364A1

公开(公告)日：2017-02-02

申请号：US15106921

申请日：2015-01-26

Applicant: SIKA TECHNOLOGY AG

Inventor： Edis KASEMI ,  Andreas KRAMER ,  Ursula STADELMANN ,  Urs BURCKHARDT

IPC: C07C217/30 ,  C08G59/64 ,  C09D163/00 ,  C07C213/08

CPC classification number: C07C217/30 ,  C07C213/08 ,  C08G59/184 ,  C08G59/5013 ,  C08G59/64 ,  C09D163/00 ,  C09D163/10

Abstract: The present invention relates to an amine of the formula (I) which is an adduct of 1,2-propylenediamine with an aryl monoglycidyl ether, to the use thereof as part of a hardener for epoxy resins, and to epoxy resin compositions obtained therewith. The amine of the formula (I) is preparable in a simple process in high purity, is of very low viscosity and is especially suitable for the curing of epoxy resins. It allows low-emission epoxy resin compositions which have good workability and which cure even under cold and damp conditions, quickly and without blushing effects, to form very hard products of high surface quality that display virtually no yellowing on exposure to light.

Abstract translation: 本发明涉及作为1,2-丙二胺与芳基单缩水甘油醚的加合物的式（I）的胺，其用作环氧树脂用固化剂的一部分，以及由其获得的环氧树脂组合物。 式（I）的胺可以在高纯度的简单方法中制备，具有非常低的粘度，特别适用于环氧树脂的固化。 它允许具有良好可加工性的低排放环氧树脂组合物，并且即使在寒冷和潮湿的条件下，快速且没有发白的影响也能固化，以形成高表面质量的非常硬的产品，在暴露于光下几乎不显示黄变。

公开(公告)号：US20160096983A1

公开(公告)日：2016-04-07

申请号：US14890199

申请日：2013-11-25

Applicant: SIKA TECHNOLOGY AG

Inventor： Urs BURCKHARDT ,  Andreas KRAMER

IPC: C09J175/06

CPC classification number: C09J175/06 ,  C08G18/12 ,  C08G18/289 ,  C08G18/4202 ,  C08G18/4238 ,  C08G18/7671 ,  C08G2170/20

Abstract: A method for producing a hot melt adhesive containing silane groups, in which at least one polyurethane polymer which contains isocyanate groups and is solid at room temperature is reacted with at least one hydroxysilane that is devoid of urea and thiourethane groups. The hot melt adhesive containing silane groups obtained from the method allows a low hazard classification, has a good degree of thermal resistance when melted such that, even upon application under prolonged heating, it does not tend towards premature thickening, releases no unpleasant odours, and crosslinks at room temperature without bubbles under the influence of moisture, resulting in an optically and mechanically high-quality and resistant adhesive connection.

Abstract translation: 一种含有硅烷基团的热熔粘合剂的制造方法，其中至少含有异氰酸酯基的聚氨酯聚合物在室温下为固体，与至少一种不含脲和硫代氨基甲酸酯的羟基硅烷反应。 由该方法获得的含有硅烷基团的热熔粘合剂允许低危险性分类，熔融时具有良好的耐热性，使得即使在长时间加热下使用也不会发生过早增稠，不会产生不愉快的气味，并且 在水分的影响下在室温下无气泡交联，从而获得光学和机械上高质量和耐性的粘合剂连接。

公开(公告)号：US20160016888A1

公开(公告)日：2016-01-21

申请号：US14843274

申请日：2015-09-02

Applicant: SIKA TECHNOLOGY AG

Inventor： Juergen FINTER ,  Ulrich GERBER ,  Edis KASEMI ,  Andreas KRAMER

IPC: C07C217/44 ,  C08G73/02

CPC classification number: C07C217/44 ,  C08G14/06 ,  C08G59/50 ,  C08G59/5006 ,  C08G59/5033 ,  C08G59/504 ,  C08G59/623 ,  C08G65/2612 ,  C08G73/024 ,  C08L63/00 ,  C09D163/00 ,  C09J11/08 ,  C09J163/00

Abstract: A condensation product of at least one (hydroxymethyl)phenol and at least one polyoxyalkylene diamine and a process for the preparation thereof and the use thereof in the curing of epoxy resin systems are described.

公开(公告)号：US20130253094A1

公开(公告)日：2013-09-26

申请号：US13904542

申请日：2013-05-29

Applicant: SIKA TECHNOLOGY AG

Inventor： Karsten FRICK ,  Ulrich GERBER ,  Juergen FINTER ,  Andreas KRAMER

IPC: C08G65/26

CPC classification number: C08G65/2672 ,  C08G18/3848 ,  C08G59/686 ,  Y10T428/31515

Abstract: A hem-curing epoxy resin composition, that includes an epoxy resin A having more than one epoxy group per molecule on average; a curing agent B for epoxy resins, which is activated at a temperature in a range of 100° C. to 220° C.; and an activator C for epoxy resin compositions, wherein activator C is a compound of formula (I), or is a reaction product between a compound of formula (Ia) and an isocyanate or an epoxide.

Abstract translation: 一种硫化环氧树脂组合物，其包含平均每分子具有多于一个环氧基的环氧树脂A; 用于环氧树脂的固化剂B，其在100℃至220℃的温度范围内活化; 和用于环氧树脂组合物的活化剂C，其中活化剂C是式（I）的化合物，或者是式（Ia）化合物与异氰酸酯或环氧化物之间的反应产物。