公开(公告)号：US20140113806A1

公开(公告)日：2014-04-24

申请号：US14113684

申请日：2012-04-25

Applicant: Alfred Hagemeyer ,  Gerhard Mestl ,  Peter Scheck ,  Peter Bauer ,  Andreas Pritzl

Inventor： Alfred Hagemeyer ,  Gerhard Mestl ,  Peter Scheck ,  Peter Bauer ,  Andreas Pritzl

IPC: B01J23/66

CPC classification number: B01J23/66 ,  B01J21/066 ,  B01J21/08 ,  B01J23/44 ,  B01J23/52 ,  B01J35/002 ,  B01J35/0026 ,  B01J35/026 ,  B01J35/08 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1061 ,  B01J37/0205 ,  B01J37/0207 ,  C07C67/055 ,  C07C69/15

Abstract: A catalyst support body containing an SiO2-containing material and a metal selected from the group consisting of alkali metals, alkaline earth metals, rare earth metals and mixtures thereof, wherein the total metal content lies in the range of from 0.5 to 10 wt.-%, relative to the total weight of the catalyst support. Also, a catalyst that comprises a catalyst support body according to the invention and a catalytically active metal, in particular palladium and/or gold. Also, a method for producing a catalyst support, wherein an SiO2-containing material is treated with a metal-containing compound, dried and then calcined. Also, a method for producing a catalyst, in which a solution having a precursor compound of a catalytically active metal is applied to a catalyst support body.

Abstract translation: 一种催化剂载体，其含有含SiO 2的材料和选自碱金属，碱土金属，稀土金属及其混合物的金属，其中总金属含量在0.5-10重量％的范围内， ％，相对于催化剂载体的总重量。 而且，包含根据本发明的催化剂载体和催化活性金属，特别是钯和/或金的催化剂。 另外，制备催化剂载体的方法，其中含金属的材料用含金属的化合物处理，干燥然后煅烧。 另外，在催化剂载体上涂布具有催化活性金属的前体化合物的溶液的催化剂的制造方法。

公开(公告)号：US20140005042A1

公开(公告)日：2014-01-02

申请号：US13981763

申请日：2012-02-06

Applicant: Mark Robert Feaviour

Inventor： Mark Robert Feaviour

IPC: B01J23/63

CPC classification number: B01J23/63 ,  B01J23/42 ,  B01J23/44 ,  B01J23/462 ,  B01J23/464 ,  B01J23/52 ,  B01J23/72 ,  B01J23/755 ,  B01J23/83 ,  B01J23/892 ,  B01J35/008 ,  B01J35/08 ,  B01J37/0036 ,  B01J37/0045 ,  B01J37/0221 ,  C01B3/326 ,  C01B3/40 ,  C01B2203/0233 ,  C01B2203/0244 ,  C01B2203/1058 ,  C01B2203/1064 ,  C01B2203/107 ,  C01B2203/1217 ,  C01B2203/1223 ,  C01B2203/1229 ,  C01B2203/1235 ,  C01B2203/1241 ,  C01B2203/1247 ,  Y02P20/52

Abstract: A method is described for preparing a catalyst suitable for use in a steam reforming process, including the steps of: (i) spraying a slurry containing a particulate catalyst compound, including one or more catalytic metals selected from the group consisting of Ni, Cu, Pt, Pd, Rh, Ru and Au, on to the surface of a shaped support in a pan coater to form a coated shaped support material having the catalytic metal in a surface layer, (ii) drying and optionally calcining the coated shaped support material to form a catalyst precursor, and (iii) optionally reducing the metal or metals in the catalyst precursor to a lower oxidation state to form the catalyst. The egg-shell catalyst is useful for performing a steam reforming reaction.

Abstract translation: 描述了一种制备适用于蒸汽重整方法的催化剂的方法，包括以下步骤：（i）喷涂含有颗粒催化剂化合物的浆料，其包括一种或多种选自Ni，Cu， Pt，Pd，Rh，Ru和Au在盘式涂布机中的成形支撑体的表面上形成在表面层中具有催化金属的涂覆形状的支撑材料，（ii）干燥并任选地煅烧涂覆的成形支撑材料 以形成催化剂前体，和（iii）任选地将催化剂前体中的金属或金属还原为较低的氧化态以形成催化剂。 蛋壳催化剂可用于进行蒸汽重整反应。

公开(公告)号：US08598065B2

公开(公告)日：2013-12-03

申请号：US12100123

申请日：2008-04-09

Applicant: Martin Dieterle ,  Klaus Joachim Müller-Engel

Inventor： Martin Dieterle ,  Klaus Joachim Müller-Engel

IPC: B01J27/198 ,  B01J23/00 ,  C07D307/89 ,  C07D307/36 ,  C07D303/00 ,  C07C51/16 ,  C07C45/00

CPC classification number: B01J8/06 ,  B01J8/0015 ,  B01J8/067 ,  B01J19/30 ,  B01J23/002 ,  B01J23/28 ,  B01J23/50 ,  B01J23/8876 ,  B01J23/8885 ,  B01J27/198 ,  B01J35/0006 ,  B01J35/023 ,  B01J35/08 ,  B01J37/0009 ,  B01J2208/00752 ,  B01J2208/00805 ,  B01J2219/30207 ,  B01J2219/30215 ,  B01J2219/30416 ,  B01J2219/30475 ,  B01J2523/00 ,  C07C45/35 ,  C07C51/252 ,  C07C51/265 ,  C07C47/22 ,  C07C57/04 ,  C07C63/16 ,  B01J2523/13 ,  B01J2523/41 ,  B01J2523/54 ,  B01J2523/68 ,  B01J2523/69 ,  B01J2523/842 ,  B01J2523/845

Abstract: A process for charging a longitudinal section of a catalyst tube with a homogeneous fixed catalyst bed section whose active composition is at least one multielement oxide or comprises elemental silver on an oxidic support body and whose geometric shaped catalyst bodies and shaped inert bodies have a specific inhomogeneity of their longest dimensions.

公开(公告)号：US20130261363A1

公开(公告)日：2013-10-03

申请号：US13547351

申请日：2012-07-12

Applicant: Manuela Serban ,  Mark P. Lapinski

Inventor： Manuela Serban ,  Mark P. Lapinski

IPC: B01J23/63 ,  C07C5/42 ,  B01J21/04 ,  B01J27/135 ,  B01J27/138 ,  B01J27/13

CPC classification number: B01J37/18 ,  B01J23/63 ,  B01J27/10 ,  B01J27/13 ,  B01J27/135 ,  B01J27/138 ,  B01J35/008 ,  B01J35/08 ,  B01J37/0072 ,  B01J37/0201 ,  C10G35/06 ,  C10G69/10 ,  C10G2300/1044 ,  C10G2400/02 ,  C10G2400/04

Abstract: One embodiment is a catalyst for catalytic reforming of naphtha. The catalyst can have a noble metal including one or more of platinum, palladium, rhodium, ruthenium, osmium, and iridium, an alkali or alkaline-earth metal, a lanthanide-series metal, and a support. Generally, an average bulk density of the catalyst is about 0.300 to about 1.00 gram per cubic centimeter. The catalyst has a platinum content of less than about 0.375 wt %, a tin content of about 0.1 to about 2 wt %, a potassium content of about 100 to about 600 wppm, and a cerium content of about 0.1 to about 1 wt %. The lanthanide-series metal can be distributed at a concentration of the lanthanide-series metal in a 100 micron surface layer of the catalyst less than two times a concentration of the lanthanide-series metal at a central core of the catalyst.

Abstract translation: 一个实施方案是用于石脑油催化重整的催化剂。 催化剂可以具有包括铂，钯，铑，钌，锇和铱中的一种或多种的贵金属，碱金属或碱土金属，镧系金属和载体。 通常，催化剂的平均体积密度为约0.300至约1.00克/立方厘米。 催化剂的铂含量小于约0.375重量％，锡含量为约0.1至约2重量％，钾含量为约100至约600wppm，铈含量为约0.1至约1重量％。 镧系元素金属可以在催化剂的100微米表面层中以镧系元素金属的浓度分布，其量小于催化剂中心核心处的镧系金属浓度的两倍。

公开(公告)号：US08497338B2

公开(公告)日：2013-07-30

申请号：US13285628

申请日：2011-10-31

Applicant: He Bai ,  Kevin L. Bobbitt ,  Michael R. Powell

Inventor： He Bai ,  Kevin L. Bobbitt ,  Michael R. Powell

IPC: C08G77/04 ,  C08G77/06 ,  C07F7/08 ,  C08K5/5419 ,  C08L75/04

CPC classification number: C08G77/20 ,  B01J23/38 ,  B01J23/42 ,  B01J23/96 ,  B01J35/023 ,  B01J35/08 ,  C08K5/5419 ,  Y02P20/584

Abstract: A process for manufacturing an organosilicon product having a stabilized low color and no formation of black particles during storage includes (a) reacting an unsaturated compound with a silicon compound having a reactive Si—H bond under hydrosilylation conditions in a reaction zone in the presence of a heterogeneous precious metal catalyst to provide an organosilicon product having a color of less than 40 pt/co; (b) separating the heterogeneous precious metal catalyst from the organosilicon product; and (c) recovering the heterogeneous precious metal catalyst.

Abstract translation: 在保存期间制造具有稳定的低颜色并且不形成黑色颗粒的有机硅产品的方法包括（a）在氢化硅烷化条件下在反应区中在不存在下存在下，使不饱和化合物与具有反应性Si-H键的硅化合物反应， 异源贵金属催化剂，以提供具有小于40pt / co的颜色的有机硅产品; （b）从有机硅产品中分离出异质贵金属催化剂; 和（c）回收异质贵金属催化剂。

公开(公告)号：US08487150B2

公开(公告)日：2013-07-16

申请号：US12485398

申请日：2009-06-16

Applicant: Lucia Koenigsmann ,  Ekkehard Schwab ,  Piotr Makarczyk ,  Kai Rainer Ehrhardt ,  Maximilian Vicari ,  Thomas Heidemann ,  Dirk Grossschmidt ,  Gerrit Waters

Inventor： Lucia Koenigsmann ,  Ekkehard Schwab ,  Piotr Makarczyk ,  Kai Rainer Ehrhardt ,  Maximilian Vicari ,  Thomas Heidemann ,  Dirk Grossschmidt ,  Gerrit Waters

IPC: C07C7/167

CPC classification number: B01J23/44 ,  B01J21/04 ,  B01J23/40 ,  B01J35/08 ,  B01J35/1038 ,  B01J35/1061 ,  C07C5/08 ,  C07C5/09 ,  C07C7/167 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2521/08 ,  C07C2523/44 ,  C07C9/10 ,  C07C11/08 ,  C07C11/24

Abstract: In the process for hydrogenating butadiyne over a catalyst which comprises at least one platinum group metal on an inorganic metal oxide as a support, the hydrogenation is performed at a pressure in the range from 1 to 40 bar and a temperature in the range from 0 to 100° C., and from 0.05 to 5% by weight, based on the overall catalyst, of platinum group metal is present on the support.

Abstract translation: 在包含在无机金属氧化物作为载体上的至少一种铂族金属的催化剂上氢化丁二炔的方法中，氢化在1至40巴的压力和0至 100℃，和0.05-5重量％，基于总催化剂，铂族金属存在于载体上。

公开(公告)号：US20130164536A1

公开(公告)日：2013-06-27

申请号：US13772774

申请日：2013-02-21

Applicant: University of South Carolina

Inventor： Fanglin Chen ,  Qiang Liu

IPC: B01J13/20

CPC classification number: B01J13/20 ,  B01J23/06 ,  B01J23/44 ,  B01J23/745 ,  B01J23/75 ,  B01J23/755 ,  B01J35/004 ,  B01J35/08 ,  B01J35/1061 ,  B01J37/0018 ,  B82Y30/00 ,  C01B13/185 ,  C01F17/0043 ,  C01G49/0018 ,  C01G49/009 ,  C01G49/06 ,  C01G51/006 ,  C01G51/70 ,  C01P2002/52 ,  C01P2004/34 ,  C01P2004/64 ,  C01P2006/12 ,  C01P2006/14 ,  C01P2006/16 ,  C01P2006/17 ,  C01P2006/40 ,  H01M4/9016 ,  H01M2008/1293 ,  Y02E60/50 ,  Y02E60/525 ,  Y10T428/2991 ,  Y10T428/2998

Abstract: Methods are generally disclosed for synthesis of porous particles from a solution formed from a leaving agent, a surfactant, and a soluble metal salt in a solvent. The surfactant congregates to form a nanoparticle core such that the metal salt forms about the nanoparticle core to form a plurality of nanoparticles. The solution is heated such that the leaving agent forms gas bubbles in the solution, and the plurality of nanoparticles congregate about the gas bubbles to form a porous particle. The porous particles are also generally disclosed and can include a particle shell formed about a core to define an average diameter from about 0.5 μm to about 50 μm. The particle shell can be formed from a plurality of nanoparticles having an average diameter of from about 1 nm to about 50 nm and defined by a metal salt formed about a surfactant core.

Abstract translation: 通常公开了从溶剂中由离去剂，表面活性剂和可溶性金属盐形成的溶液合成多孔颗粒的方法。 表面活性剂聚集形成纳米颗粒核，使得金属盐围绕纳米颗粒核心形成以形成多个纳米颗粒。 将溶液加热使得离去剂在溶液中形成气泡，并且多个纳米颗粒聚集在气泡周围以形成多孔颗粒。 多孔颗粒也通常被公开，并且可以包括围绕芯形成的颗粒壳，以限定平均直径为约0.5μm至约50μm。 颗粒壳可以由平均直径为约1nm至约50nm的多个纳米颗粒形成，并由围绕表面活性剂芯形成的金属盐限定。

公开(公告)号：US08460547B2

公开(公告)日：2013-06-11

申请号：US12669427

申请日：2008-07-14

Applicant: Delai Darren Sun ,  Pei Fung Lee ,  Xiwang Zhang ,  Jianhong Du ,  James O. Leckie

Inventor： Delai Darren Sun ,  Pei Fung Lee ,  Xiwang Zhang ,  Jianhong Du ,  James O. Leckie

IPC: C02F3/00

CPC classification number: C03B19/107 ,  A61K9/0092 ,  B01J35/002 ,  B01J35/004 ,  B01J35/06 ,  B01J35/08 ,  B01J35/1052 ,  B01J35/1061 ,  B01J35/1066 ,  B01J35/1071 ,  B01J35/1076 ,  B01J37/0045 ,  B82Y30/00 ,  C01G23/053 ,  C01P2002/72 ,  C01P2002/88 ,  C01P2004/03 ,  C01P2004/04 ,  C01P2004/16 ,  C01P2004/34 ,  C01P2004/61 ,  C01P2006/12 ,  C01P2006/17 ,  C02F1/32 ,  C02F1/725 ,  C04B30/02 ,  C04B35/624 ,  C04B35/62821 ,  C04B35/632 ,  C04B38/009 ,  C04B2111/0081 ,  C04B2111/00827 ,  C04B2235/441 ,  C08J5/005 ,  Y02W10/37 ,  Y10T428/2982 ,  C04B35/00 ,  C04B38/0045 ,  C04B38/0054 ,  C04B35/52 ,  C04B35/547

Abstract: The present invention refers to a hollow microsphere having a porous circumferential wall comprised of nanofilaments.

Abstract translation: 本发明涉及具有由纳米丝组成的多孔圆周壁的中空微球。

公开(公告)号：US20130098804A1

公开(公告)日：2013-04-25

申请号：US13317615

申请日：2011-10-24

Applicant: Yun-feng Chang ,  Lian Du

Inventor： Yun-feng Chang ,  Lian Du

IPC: C10G11/00 ,  B01J29/40 ,  B01J29/08 ,  B01J29/04

CPC classification number: B01J29/04 ,  B01J29/06 ,  B01J29/084 ,  B01J29/40 ,  B01J35/002 ,  B01J35/0026 ,  B01J35/023 ,  B01J35/08 ,  B01J37/0018 ,  B01J37/0036 ,  B01J2229/42 ,  C10G11/18 ,  C10G11/182 ,  C10G2300/305 ,  C10G2400/02 ,  C10G2400/20

Abstract: A catalyst composition that has superior attrition performance and a method that produces said catalyst composition to be used for fluid catalytic cracking processes to convert a heavy hydrocarbon fraction into mainly liquid fuels, particularly gasoline and light olefins. The catalyst composition has a moisture level or loss on ignition below 12 wt % and attrition rate below 3 wt. %/hr.

Abstract translation: 具有优异的磨耗性能的催化剂组合物和产生用于流化催化裂化方法的所述催化剂组合物以将重质烃馏分转化成主要是液体燃料，特别是汽油和轻质烯烃的方法。 催化剂组合物具有低于12重量％的水分含量或灼烧损失，并且磨耗率低于3重量％。 ％/小时。

公开(公告)号：US08343454B2

公开(公告)日：2013-01-01

申请号：US12452794

申请日：2008-06-25

Applicant: Woo-Ram Lee ,  Sang-Ho Kim ,  Sung-Ho Yoon

Inventor： Woo-Ram Lee ,  Sang-Ho Kim ,  Sung-Ho Yoon

IPC: C01G3/00

CPC classification number: C01G3/02 ,  B01J23/72 ,  B01J35/0013 ,  B01J35/08 ,  B01J37/16 ,  B82Y30/00 ,  C01P2002/72 ,  C01P2004/03 ,  C01P2004/04 ,  C01P2004/32 ,  C01P2004/50 ,  C01P2004/52 ,  C01P2004/61 ,  C01P2004/62 ,  H01L31/0328 ,  H01L31/035281 ,  Y02E10/50 ,  Y10T428/2991 ,  Y10T428/2998

Abstract: A Cu2O spherical assembly particle composition is composed of Cu2O spherical assembly particles, each of which is formed by agglomerating a plurality of Cu2O ultrafine particles that have an average diameter in the range from 1 to 100 nm and a standard deviation on the diameter in the range from 0 to 10%. The Cu2O spherical assembly particles have an average diameter in the range from 0.1 to 10 μm and a standard deviation on the diameter in the range from 0 to 40%. This Cu2O spherical assembly particle composition is composed of Cu2O assembly particles with excellent uniformity, so it shows excellent properties such as realizing a good electric conductivity during a curing process for wiring. Accordingly, the spherical Cu2O assembly particle composition may be usefully used as precursors for solar energy conversion, magnetic storage medium, catalyst, gas sensor, and copper wire formation.

Abstract translation: Cu2O球形组件颗粒组合物由Cu2O球形组件颗粒组成，每个颗粒通过使平均直径在1至100nm范围内的多个Cu 2 O超细颗粒聚集而形成，并且在该范围内的直径的标准偏差 从0到10％。 Cu2O球形组件颗粒的平均直径在0.1至10μm的范围内，直径的标准偏差在0至40％的范围内。 该Cu 2 O球形组合物颗粒组合物由均匀性良好的Cu 2 O组合颗粒组成，因此在布线固化过程中实现良好的导电性。 因此，球形Cu 2 O组合粒子组合物可以有用地用作太阳能转换，磁存储介质，催化剂，气体传感器和铜线形成的前体。