公开(公告)号：US20150112016A1

公开(公告)日：2015-04-23

申请号：US14398487

申请日：2012-05-04

Applicant: James C. Bohling ,  Qiaoqiao Cai ,  Edwin H. Nungesser ,  Morris C. Wills ,  Tingke Zhang

Inventor： James C. Bohling ,  Qiaoqiao Cai ,  Edwin H. Nungesser ,  Morris C. Wills ,  Tingke Zhang

IPC: C09D131/04 ,  C08K3/22 ,  C09D7/12

CPC classification number: C09D131/04 ,  C08F2/22 ,  C08F220/60 ,  C08K3/22 ,  C08K2003/2241 ,  C08L2201/50 ,  C08L2201/54 ,  C09D7/61 ,  C09D143/02 ,  C08F218/08 ,  C08F230/02 ,  C08F220/18 ,  C08F2220/585

Abstract: The present invention relates to a composition comprising and a method for preparing a stable aqueous dispersion of polymer particles comprising structural units of vinyl acetate and a phosphorous acid monomer. The composition of the present invention provides vinyl acetate/phosphorus acid based polymer particles that improve hiding efficiency in pigmented coatings formulations.

Abstract translation: 本发明涉及一种组合物，它包括一种制备包含乙酸乙烯酯和亚磷酸单体的结构单元的聚合物颗粒的稳定水分散体的方法。 本发明的组合物提供了改善着色涂料配方中遮盖效率的乙酸乙烯酯/磷酸基聚合物颗粒。

公开(公告)号：US08993111B2

公开(公告)日：2015-03-31

申请号：US12589587

申请日：2009-10-26

Applicant: Bonnie E. Baker ,  Arnold S. Brownell ,  Nancy P. Buford ,  Willie Lau ,  Joseph J. Spanier

Inventor： Bonnie E. Baker ,  Arnold S. Brownell ,  Nancy P. Buford ,  Willie Lau ,  Joseph J. Spanier

IPC: C08K5/52 ,  B05D3/10 ,  C09D143/02

CPC classification number: C09D143/02 ,  Y10T428/273 ,  Y10T428/31855 ,  Y10T428/31895

Abstract: The present invention provides surface treated articles comprising a recoatable surface treatment of an acrylic or vinyl polymer that does not change the appearance of the treated surface, and which imparts blocking resistance and/or stain and dirt pickup resistance to the treated surface. The one or more acrylic or vinyl polymer has a number average molecular weight of from 1,000 to 100,000, a glass transition temperature of −10° C. or higher, preferably, 30° C. or higher, and comprises the polymerization product of one or more non-ionic monomer, such as methyl methacrylate, with up to 47 wt. % of an ethylenically unsaturated acid monomer and, preferably, is non-migrating under use conditions. When dry, the surface treatments may form a layer of domains of polymer distributed all over the treated surface, rather than a film. Treated articles include coating or painted articles and elastomer films.

Abstract translation: 本发明提供了表面处理制品，其包括丙烯酸或乙烯基聚合物的可重复表面处理，其不会改变经处理的表面的外观，并且赋予对经处理的表面的抗粘连性和/或污渍和污垢拾取抗性。 一种或多种丙烯酸或乙烯基聚合物的数均分子量为1,000至100,000，玻璃化转变温度为-10℃或更高，优选为30℃或更高，并且包含一种或多种聚合产物 更多的非离子单体，如甲基丙烯酸甲酯，高达47wt。 ％的烯属不饱和酸单体，并且优选在使用条件下不迁移。 当干燥时，表面处理可以形成分布在整个处理过的表面上的聚合物的一层，而不是膜。 处理过的制品包括涂层或涂漆制品和弹性体膜。

公开(公告)号：US08969491B2

公开(公告)日：2015-03-03

申请号：US12089113

申请日：2006-10-04

Applicant: Christophe Fringant ,  Yves Vanderveken ,  Cedric Loubat ,  Gilles Boutevin

Inventor： Christophe Fringant ,  Yves Vanderveken ,  Cedric Loubat ,  Gilles Boutevin

IPC: C08L43/02 ,  C08L33/04 ,  C08L27/08 ,  C09D127/08 ,  C08L33/10 ,  C08L33/14 ,  C08L33/06 ,  C08L33/08 ,  C08L33/16 ,  C09D133/02 ,  C09D133/10 ,  C09D133/08 ,  C09D133/06 ,  C09D143/02

CPC classification number: C08L27/08 ,  C08L33/04 ,  C08L33/06 ,  C08L33/062 ,  C08L33/08 ,  C08L33/10 ,  C08L33/14 ,  C08L33/16 ,  C08L43/02 ,  C08L2666/04 ,  C09D127/08 ,  C09D133/02 ,  C09D133/064 ,  C09D133/08 ,  C09D133/10 ,  C09D143/02

Abstract: An aqueous dispersion containing a vinylidene chloride polymer (P1) containing vinylidene chloride in a proportion of at least 50% by weight, and at least one random, alternating or gradient copolymer (C1) having: a) at least one monomer unit (m1) carrying at least one phosphonate group —PO(OH)(OR1) with R1 being a hydrogen atom or an alkyl radical comprising from 1 to 11 carbon atoms, and b) monomer units (m2) which represent at least 50% by weight of the copolymer (C1), derived from at least one monomer (M2) chosen from styrene, maleic anhydride, itaconic acid and the (meth)acrylic monomers corresponding to the general formula CH2=CR2R3 in which R2 and R3 are described herein, copolymer (C1) not containing monomer units derived from vinylidene chloride.

Abstract translation: 包含含有至少50重量％的偏二氯乙烯的偏二氯乙烯聚合物（P1）和至少一种无规交替或梯度共聚物（C1）的水分散体，其具有：a）至少一种单体单元（m1） 携带至少一个膦酸酯基-PO（OH）（OR1），其中R1是氢原子或含有1至11个碳原子的烷基，b）单体单元（m2），其代表至少50重量％ 共聚物（C1），衍生自选自苯乙烯，马来酸酐，衣康酸和对应于其中R2和R3的通式CH 2 = CR 2 R 3的（甲基）丙烯酸单体）的至少一种单体（M2），其中R2和R3如本文所述，共聚物（C1 ）不包含衍生自偏二氯乙烯的单体单元。

公开(公告)号：US20140329957A1

公开(公告)日：2014-11-06

申请号：US14365673

申请日：2012-12-17

Applicant: Rohm and Haas Company

Inventor： James C. Bohling ,  Arnold S. Brownell ,  Catherine A. Finegan

IPC: C08L33/08 ,  C08K3/22

CPC classification number: C08L43/02 ,  C08F220/18 ,  C08F228/00 ,  C08F230/02 ,  C08F265/04 ,  C08F275/00 ,  C08K3/22 ,  C08K5/42 ,  C08K5/521 ,  C08K2003/2241 ,  C08L33/08 ,  C08L2201/54 ,  C09D143/02 ,  C08F212/14 ,  C08F220/34

Abstract: The present invention is a process for preparing a multistage polymer by contacting under emulsion polymerization conditions an acrylic monomer, a sulfur acid monomer, and a phosphorous acid monomer as described herein. The present invention is also a composition comprising a nonionic surfactant and a stable aqueous dispersion of polymer particles comprising structural units of butyl acrylate, methyl methacrylate, a sodium vinylbenzenesulfonate, and phosphoethyl methacrylate; wherein the polymer particles have a Tg of less than 10° C. The composition of the present invention is useful as a binder for coatings compositions.

Abstract translation: 本发明是一种通过在乳液聚合条件下与本文所述的丙烯酸类单体，硫酸单体和亚磷酸单体接触来制备多级聚合物的方法。 本发明还是一种包含非离子表面活性剂和稳定的聚合物颗粒的水性分散体的组合物，其包含丙烯酸丁酯，甲基丙烯酸甲酯，乙烯基苯磺酸钠和甲基丙烯酸磷酸乙酯的结构单元; 其中聚合物颗粒具有小于10℃的Tg。本发明的组合物可用作涂料组合物的粘合剂。

公开(公告)号：US08864916B2

公开(公告)日：2014-10-21

申请号：US12267212

申请日：2008-11-07

Applicant: Matthias Koch ,  Kerstin Motzkat

Inventor： Matthias Koch ,  Kerstin Motzkat

IPC: C23C22/18 ,  C23C22/36 ,  C23C22/05

CPC classification number: C09D4/00 ,  B05D7/51 ,  C09D5/08 ,  C09D133/14 ,  C09D143/02 ,  C23C22/364 ,  C23C22/44 ,  C23C22/83 ,  Y10T428/31678

Abstract: The invention relates to a method and coating agents used in the method which provide good adherence to and good corrosion protection of metal substrates; the coating coating agents are cross-linkable via radical polymerization. Adhesion promoting compounds are present in the conversion layer in a quantity of about 0.01 to 40 weight percent and contain, on average, one reactive unsaturated group and at least one H-active group per molecule.

Abstract translation: 本发明涉及在该方法中使用的方法和涂层剂，其对金属基材提供良好的粘附性和良好的防腐蚀保护; 涂层涂料通过自由基聚合可交联。 粘合促进化合物以约0.01至40重量％的量存在于转化层中，并且每个分子平均含有一个反应性不饱和基团和至少一个H-活性基团。

公开(公告)号：US20140272149A1

公开(公告)日：2014-09-18

申请号：US13815952

申请日：2013-03-18

Applicant: ACULON, INC.

Inventor： Eric L. Hanson

IPC: C09D133/16 ,  C09D141/00

CPC classification number: B05D5/086 ,  B05D1/38 ,  B05D3/002 ,  B05D7/50 ,  B05D7/52 ,  B05D2506/10 ,  C09D141/00 ,  C09D143/02 ,  Y10S977/882 ,  Y10S977/883

Abstract: A process for forming a polymer film on a substrate through an intermediate organometallic layer is disclosed. A self-assembled monolayer (SAM) containing an initiator for living polymerization such as controlled radical polymerization is formed on the organometallic layer followed by living polymerization such as controlled radical polymerization of a polymerizable monomer component.

Abstract translation: 公开了一种通过中间有机金属层在基底上形成聚合物膜的方法。 在有机金属层上形成含有活性聚合引发剂如自由基聚合的自组装单层（SAM），然后进行可聚合单体成分的受控自由基聚合等活性聚合。

公开(公告)号：US20140094563A1

公开(公告)日：2014-04-03

申请号：US13633854

申请日：2012-10-02

Applicant: SUNOCS LLC

Inventor： Cheng Qian Song ,  Rui Fang Sun ,  Min Liu ,  Hui Ling Song

IPC: C08L33/02 ,  C08L35/02 ,  C08K3/36 ,  C08K5/529

CPC classification number: C08L33/02 ,  C08F2/44 ,  C08K3/22 ,  C08K3/32 ,  C08K3/36 ,  C08K5/34 ,  C08K5/34924 ,  C08K5/34928 ,  C08K5/529 ,  C08K5/5313 ,  C08K9/08 ,  C08K2003/222 ,  C08K2003/2227 ,  C08K2003/2241 ,  C08K2003/323 ,  C08K2201/013 ,  C08L35/02 ,  C09D143/02 ,  C08F220/06 ,  C08F2222/1026 ,  C08L43/02

Abstract: The present invention generally relates to a process for making non-halogenated flame retardant polymeric composites with superabsorbent polymer coated nanoparticles to provide excellent flame retardant property, low toxicity and high loading efficiency. The flame retardant polymeric composites can be used as flame retarding foams, insulation sheeting materials or other composite materials.

Abstract translation: 本发明一般涉及一种制备具有超吸收聚合物涂层纳米颗粒的非卤化阻燃聚合物复合材料以提供优异的阻燃性能，低毒性和高负载效率的方法。 阻燃聚合物复合材料可用作阻燃泡沫，绝缘片材或其他复合材料。

公开(公告)号：US08436088B2

公开(公告)日：2013-05-07

申请号：US12444035

申请日：2007-09-21

Applicant: Ivan Cabrera ,  Thomas Fichtner ,  Stephan Krieger ,  Marc Theodorus Ratering

Inventor： Ivan Cabrera ,  Thomas Fichtner ,  Stephan Krieger ,  Marc Theodorus Ratering

IPC: C09D1/04 ,  C09D157/12 ,  C09D157/10

CPC classification number: C04B26/02 ,  C04B28/26 ,  C09D133/14 ,  C09D143/02 ,  C09D143/04 ,  C04B14/06 ,  C04B14/062 ,  C04B14/20 ,  C04B14/28 ,  C04B20/008 ,  C04B24/42 ,  C04B2103/54 ,  C04B24/2688 ,  C04B14/30 ,  C04B14/305 ,  C04B14/308 ,  C04B24/12 ,  C04B24/2641

Abstract: Plasters and renders and paints, copolymer dispersions and their use Compositions containing selected polymer dispersions, colloidal silica, fillers and pigments are described.These can be formulated to give plasters and renders or paints which are distinguished by excellent abrasion resistance, little tendency to soiling, high water vapor permeability, good adhesion and good weathering stability. The compositions according to the invention can be processed to give plasters and renders or paints which have a nanostructured surface and which differ from conventionally produced surfaces.

Abstract translation: 石膏和涂料和油漆，共聚物分散体及其用途描述了包含所选聚合物分散体，胶体二氧化硅，填料和颜料的组合物。 这些可以配制成具有优异的耐磨性，少的污染倾向，高透湿性，良好的粘合性和良好的耐候稳定性的膏药和油漆。 根据本发明的组合物可以加工成具有具有纳米结构表面并且与常规生产的表面不同的灰泥和涂料或涂料。

公开(公告)号：US07893151B2

公开(公告)日：2011-02-22

申请号：US12214637

申请日：2008-06-20

Applicant: Melissa Merlau Johnson ,  Andrew J. Swartz ,  Drew E. Williams

Inventor： Melissa Merlau Johnson ,  Andrew J. Swartz ,  Drew E. Williams

IPC: C08L41/00 ,  C08L85/02 ,  E04B1/74

CPC classification number: C08F275/00 ,  B60R13/08 ,  C08F230/02 ,  C09D143/02

Abstract: A liquid applied sound damping composition with a binder having from 0.05 wt. % to 20 wt. %, based on the total weight of polymer solids, of carboxy acid monomers, present as copolymerized monomers in pendant polyacid sidechain groups.

Abstract translation: 一种具有粘合剂的液体应用的阻尼组合物，其具有0.05wt。 ％至20重量％ 基于聚合物固体的总重量计，羧酸单体在侧链多酸侧链基团中作为共聚单体存在。

公开(公告)号：US20090191373A1

公开(公告)日：2009-07-30

申请号：US12085832

申请日：2006-11-27

Applicant: Koju Okazaki ,  Ryouichi Seki ,  Takazou Katou ,  Masatoshi Takagi

Inventor： Koju Okazaki ,  Ryouichi Seki ,  Takazou Katou ,  Masatoshi Takagi

IPC: B32B33/00 ,  C08F20/06 ,  B32B27/36 ,  C08G63/46

CPC classification number: G02B1/18 ,  B05D5/00 ,  C03C17/30 ,  C08J7/047 ,  C08J2367/00 ,  C08J2443/02 ,  C09D5/1668 ,  C09D133/14 ,  C09D143/02 ,  C09K3/16 ,  C09K3/18 ,  G02B1/16 ,  G02B27/0006 ,  Y10T428/14 ,  Y10T428/1476 ,  Y10T428/23 ,  Y10T428/263 ,  Y10T428/269 ,  Y10T428/28 ,  Y10T428/31 ,  Y10T428/31786 ,  Y10T428/31855

Abstract: A single layer film containing at least one anionic hydrophilic group selected from a sulfonic acid group, a carboxyl group and a phosphate group, wherein an anion concentration ratio (Sa/Da) of an anion concentration at a surface (Sa) to an anion concentration at a deep part (Da) is 1.1 or more. The single layer film is a copolymer prepared by polymerizing a composition containing a compound (I) represented by the general formula (1) ([X]s[M1]1[M2]m (1)) and a compound (II) having two or more (meth)acryloyl groups in a molecule at a molar ratio of 15:1 to 1:30 and having a water contact angle of 30° or less. Such a single layer film has high hydrophilicity and surface hardness and is excellent in antifogging property, antifouling property and antistatic property, thus is useful as an antifogging material, an antifouling material, an antistatic material and a multilayer body.

Abstract translation: 含有选自磺酸基，羧基和磷酸酯基的至少一个阴离子亲水基团的单层膜，其中表面处的阴离子浓度（Sa）与阴离子浓度的阴离子浓度比（Sa / Da） 在深部（Da）为1.1以上。 单层膜是通过使含有通式（1）表示的化合物（I）（[X] s [M1] 1 [M2] m（1））的化合物和具有式 分子中的摩尔比为15:1至1:30的两个或多个（甲基）丙烯酰基，并且具有30°或更低的水接触角。 这样的单层膜的亲水性和表面硬度高，防雾性，防污性，抗静电性优异，因此可用作防雾材料，防污材料，抗静电材料和多层体。