公开(公告)号：US4183620A

公开(公告)日：1980-01-15

申请号：US755590

申请日：1976-12-30

Applicant: Pedro B. Macedo ,  Mrinmay Samanta ,  Joseph H. Simmons

Inventor： Pedro B. Macedo ,  Mrinmay Samanta ,  Joseph H. Simmons

IPC: G02B6/00 ,  C03B5/425 ,  C03B8/00 ,  C03B37/014 ,  C03C3/06 ,  C03C3/076 ,  C03C3/078 ,  C03C3/102 ,  C03C11/00 ,  C03C13/00 ,  C03C13/04 ,  C03C23/00 ,  G02B6/028 ,  G02B5/14 ,  C03C3/04 ,  C03C25/02

CPC classification number: C03C23/0095 ,  C03C11/00 ,  C03C13/001 ,  C03C3/06 ,  C03C3/102 ,  C03C2201/10 ,  C03C2201/30 ,  C03C2201/50 ,  G02B6/0281

Abstract: A glass composition having at least 85 mole percent of SiO.sub.2, where the improvement comprises at least 7 wt percent of at least one member selected from the group consisting of PbO and Bi.sub.2 O.sub.3 and at least 1.5 mole percent of at least one member selected from the group consisting of K.sub.2 O, Rb.sub.2 O and Cs.sub.2 O.

Abstract translation: 一种玻璃组合物，其具有至少85摩尔％的SiO 2，其中改进包括至少7重量％的选自PbO和Bi 2 O 3中的至少一种，和至少1.5摩尔％的选自组中的至少一种 由K2O，Rb2O和Cs2O组成。

公开(公告)号：US4011006A

公开(公告)日：1977-03-08

申请号：US641651

申请日：1975-12-17

Applicant: James William Fleming, Jr. ,  Raymond Edward Jaeger ,  Thomas John Miller

Inventor： James William Fleming, Jr. ,  Raymond Edward Jaeger ,  Thomas John Miller

IPC: C03B19/10 ,  C03B37/012 ,  C03C1/02 ,  C03C3/06 ,  C03C13/04 ,  C03C3/08 ,  G02B5/14

CPC classification number: C03C3/06 ,  C03B19/1065 ,  C03B37/01291 ,  C03C1/02 ,  C03C13/04 ,  C03B2201/10 ,  C03B2201/31 ,  C03C2201/10 ,  C03C2201/31 ,  C03C2203/10 ,  Y10S501/90 ,  Y10T428/2929

Abstract: High silica content optical glasses, containing more volatile oxides such as GeO.sub.2 and B.sub.2 O.sub.3, are produced by plasma fusion of powders without inordinately high loss of the more volatile constituents. The powders are produced by a process including the heat treatment of intimately mixed materials, which include the glass forming constituents. Small quantities of GeO.sub.2 are included in borosilicate glass to suppress bubble formation. Pairs of glass compositions have been found, with sufficient index of refraction difference to produce guidance in optical transmission lines, while possessing sufficient thermal expansion match to reduce stresses in the line.

公开(公告)号：US3954431A

公开(公告)日：1976-05-04

申请号：US509652

申请日：1974-09-26

Applicant: James William Fleming, Jr. ,  Raymond Edward Jaeger ,  Thomas John Miller

Inventor： James William Fleming, Jr. ,  Raymond Edward Jaeger ,  Thomas John Miller

IPC: C03B19/01 ,  C03B37/012 ,  C03C1/02 ,  C03C3/00 ,  C03C3/06 ,  C03C3/089 ,  C03C13/04 ,  C03B1/00 ,  C03B23/20

CPC classification number: C03C3/089 ,  C03B19/01 ,  C03B37/01291 ,  C03C1/02 ,  C03C13/04 ,  C03C3/00 ,  C03C3/06 ,  C03B2201/10 ,  C03B2201/31 ,  C03C2201/10 ,  C03C2201/31 ,  C03C2203/10

Abstract: High silica content optical glasses, containing more volatile oxides such as GeO.sub.2 and B.sub.2 O.sub.3, are produced by plasma fusion of powders without inordinately high loss of the more volatile constituents. The powders are produced by a process including the heat treatment of intimately mixed materials, which include the glass forming constituents. Small quantities of GeO.sub.2 are included in borosilicate glass to suppress bubble formation. Pairs of glass compositions have been found, with sufficient index of refraction difference to produce guidance in optical transmission lines, while possessing sufficient thermal expansion match to reduce stresses in the line.

Abstract translation: 含有更多挥发性氧化物如GeO 2和B 2 O 3的高二氧化硅含量的光学玻璃通过粉末的等离子体熔融而没有较高挥发性组分的高损失而产生。 该粉末是通过包括玻璃形成成分在内的紧密混合材料的热处理的方法生产的。 少量的GeO 2被包括在硼硅酸盐玻璃中以抑制气泡形成。 已经发现了一对玻璃组合物，具有足够的折射率差异以在光学传输线中产生引导，同时具有足够的热膨胀匹配以减少线中的应力。

公开(公告)号：US3678144A

公开(公告)日：1972-07-18

申请号：US3678144D

申请日：1970-06-12

Applicant: CORNING GLASS WORKS

Inventor： SHOUP ROBERT D

IPC: C03B19/12 ,  C03C1/00 ,  C03C3/06 ,  B29H7/20

CPC classification number: C03C1/006 ,  C03B19/12 ,  C03C3/06 ,  C03C2201/06 ,  C03C2201/10 ,  C03C2201/28 ,  C03C2201/30 ,  C03C2201/31 ,  C03C2201/32 ,  C03C2201/80 ,  C03C2203/22 ,  C03C2203/24 ,  C03C2203/30 ,  Y10S65/901

Abstract: This invention relates to the discovery of a method for incorporating various oxides into silica-containing porous and nonporous glass materials by dissolving soluble compounds of the additive oxides, characterized as MxOy, into solutions, colloidal solutions, or suspensions of soluble silicates, reacting the mixture with an organic compound, and then firing the thus-formed body at temperatures below the softening point of the particular glass composition for a sufficient length of time to produce the porous body or non-porous glass body containing the added oxides intimately bonded to the silica network.

Abstract translation: 本发明涉及将各种氧化物掺入含二氧化硅的多孔和无孔玻璃材料中的方法的发现，通过将以MxOy为特征的添加剂氧化物的可溶性化合物溶解在可溶性硅酸盐的溶液，胶体溶液或悬浮液中，使混合物 与有机化合物反应，然后在低于特定玻璃组合物的软化点的温度下焙烧如此形成的本体足够长的时间以产生包含与二氧化硅紧密结合的添加氧化物的多孔体或无孔玻璃体 网络。

公开(公告)号：US2221709A

公开(公告)日：1940-11-12

申请号：US18777038

申请日：1938-01-29

Applicant: CORNING GLASS WORKS

Inventor： HOOD HARRISON P ,  NORDBERG MARTIN E

IPC: C03C3/06

CPC classification number: C03C3/06 ,  C03C2201/10 ,  C03C2201/50 ,  C03C2203/10

公开(公告)号：US11897812B2

公开(公告)日：2024-02-13

申请号：US17860443

申请日：2022-07-08

Applicant: AGC Inc.

Inventor： Hirofumi Tokunaga ,  Kazutaka Ono

IPC: C03C3/087 ,  C03C3/091

CPC classification number: C03C3/087 ,  C03C3/091 ,  C03C2201/10 ,  C03C2203/10

Abstract: An alkali free glass has an average coefficient of thermal expansion at 50 to 350° C. of 30×10−7 to 43×10−7/° C., a Young's modulus of 88 GPa or more, a strain point of 650 to 725° C., a temperature T4 at which a viscosity reaches 104 dPa·s of 1,290° C. or lower, a glass surface devitrification temperature (Tc) of T4+20° C. or lower, and a temperature T2 at which the viscosity reaches 102 dPa·s of 1,680° C. or lower. The alkali free glass contains, as represented by mol % based on oxides, 62 to 67% of SiO2, 12.5 to 16.5% of Al2O3, 0 to 3% of B2O3, 8 to 13% of MgO, 6 to 12% of CaO, 0.5 to 4% of SrO, and 0 to 0.5% of BaO. MgO+CaO+SrO+BaO is 18 to 22%, and MgO/CaO is 0.8 to 1.33.

公开(公告)号：US20190248696A1

公开(公告)日：2019-08-15

申请号：US16390139

申请日：2019-04-22

Applicant: Corning Incorporated

Inventor： Sezhian Annamalai ,  Carlos Alberto Duran ,  Kenneth Edward Hrdina ,  William Rogers Rosch

IPC: C03C3/076 ,  C03C3/06 ,  C03C3/112 ,  C03B19/12 ,  C03C3/089 ,  C03C23/00 ,  C03B19/14 ,  C03B25/00 ,  C03B25/02

CPC classification number: C03C3/076 ,  C03B19/12 ,  C03B19/1453 ,  C03B25/00 ,  C03B25/02 ,  C03B2201/10 ,  C03B2201/12 ,  C03B2201/42 ,  C03C3/06 ,  C03C3/089 ,  C03C3/112 ,  C03C23/007 ,  C03C2201/10 ,  C03C2201/12 ,  C03C2201/14 ,  C03C2203/52

Abstract: Annealing treatments for modified titania-silica glasses and the glasses produced by the annealing treatments. The annealing treatments include an isothermal hold that facilitates equalization of non-uniformities in fictive temperature caused by non-uniformities in modifier concentration in the glasses. The annealing treatments may also include heating the glass to a higher temperature following the isothermal hold and holding the glass at that temperature for several hours. Glasses produced by the annealing treatments exhibit high spatial uniformity of CTE, CTE slope, and fictive temperature, including in the presence of a spatially non-uniform concentration of modifier.

公开(公告)号：US20160236965A1

公开(公告)日：2016-08-18

申请号：US15003115

申请日：2016-01-21

Applicant: Corning Incorporated

Inventor： Sezhian Annamalai ,  Carlos Alberto Duran ,  Kenneth Edward Hrdina ,  William Rogers Rosch

IPC: C03C3/076 ,  C03B25/00 ,  C03C3/089 ,  C03C3/06 ,  C03C3/112

CPC classification number: C03C3/076 ,  C03B19/12 ,  C03B19/1453 ,  C03B25/00 ,  C03B25/02 ,  C03B2201/10 ,  C03B2201/12 ,  C03B2201/42 ,  C03C3/06 ,  C03C3/089 ,  C03C3/112 ,  C03C23/007 ,  C03C2201/10 ,  C03C2201/12 ,  C03C2201/14 ,  C03C2203/52

Abstract: Annealing treatments for modified titania-silica glasses and the glasses produced by the annealing treatments. The annealing treatments include an isothermal hold that facilitates equalization of non-uniformities in fictive temperature caused by non-uniformities in modifier concentration in the glasses. The annealing treatments may also include heating the glass to a higher temperature following the isothermal hold and holding the glass at that temperature for several hours. Glasses produced by the annealing treatments exhibit high spatial uniformity of CTE, CTE slope, and fictive temperature, including in the presence of a spatially non-uniform concentration of modifier.

Abstract translation: 改性二氧化钛 - 二氧化硅玻璃和通过退火处理制备的玻璃的退火处理。 退火处理包括促进由玻璃中改性剂浓度不均匀引起的虚构温度不均匀性均衡的等温保持。 退火处理还可以包括在等温保持之后将玻璃加热到更高的温度，并将玻璃保持在该温度下几个小时。 通过退火处理产生的玻璃表现出CTE，CTE斜率和假想温度的高空间均匀性，包括在存在空间不均匀的改性剂浓度的情况下。

公开(公告)号：US09382150B2

公开(公告)日：2016-07-05

申请号：US14637516

申请日：2015-03-04

Applicant: Corning Incorporated

Inventor： Sezhian Annamalai ,  Carlos Alberto Duran ,  Kenneth Edward Hrdina

IPC: C03C3/06 ,  C03C3/089 ,  C03C3/115 ,  C03C3/097 ,  C03C3/091 ,  C03B25/02

CPC classification number: C03C3/06 ,  C03B25/02 ,  C03C3/089 ,  C03C3/091 ,  C03C3/097 ,  C03C3/115 ,  C03C2201/10 ,  C03C2201/42 ,  C03C2203/40 ,  C03C2203/52 ,  G03F1/22 ,  G03F1/60

Abstract: A boron-doped titania-silica glass containing 0.1 wt % to 8.0 wt % boron, 9.0 wt % to 16.0 wt % TiO2, and 76.0 wt % to 90.9 wt % SiO2. The glass may further include F, Nb, Ta, Al, Li, Na, K, Ca, and Mg, individually or in combinations of two or more, at levels up to 4 wt %. The glass may have an OH concentration of more than 10 ppm. The glass features a CTE slope at 20° C. of less than 1 ppb/K2. The fictive temperature of the glass is less than 825° C. and the peak CTE of the glass is less than 30 ppb/K. The glass has two crossover temperatures and a wide temperature interval over which CTE is close to zero. The uniformity of each crossover temperature relative to its average over a volume of at least 50 cm3 is within ±5° C.

Abstract translation: 含有0.1重量％至8.0重量％硼，9.0重量％至16.0重量％TiO 2和76.0重量％至90.9重量％SiO 2的硼掺杂二氧化钛 - 二氧化硅玻璃。 玻璃还可包含F，Nb，Ta，Al，Li，Na，K，Ca和Mg，其含量可高达4wt％，分别或两种或多种组合。 玻璃的OH浓度可能超过10ppm。 玻璃在20°C时的CTE斜率小于1 ppb / K2。 玻璃的假想温度小于825℃，玻璃的峰值CTE小于30ppb / K。 玻璃具有两个交叉温度和CTE接近零的宽温度区间。 每个交叉温度相对于其在至少50cm 3的体积上的平均值的均匀度在±5℃以内

公开(公告)号：US09156733B2

公开(公告)日：2015-10-13

申请号：US13810008

申请日：2010-07-14

Applicant: Mingjie Zhou ,  Yanbo Qiao ,  Wenbo Ma

Inventor： Mingjie Zhou ,  Yanbo Qiao ,  Wenbo Ma

IPC: C09K11/77 ,  C03C3/083 ,  C03C4/12 ,  C03C21/00 ,  C03C3/06 ,  C03C23/00

CPC classification number: C03C21/005 ,  C03C3/06 ,  C03C4/12 ,  C03C23/0095 ,  C03C2201/10 ,  C03C2201/3423 ,  C03C2201/3458 ,  C03C2201/36 ,  C03C2201/54 ,  C03C2203/50 ,  C09K11/7774

Abstract: A preparation method of rare earth ions doped alkaline earth metal silicate luminescent glass is provided. The steps involve: step 1, mixing the source compounds of cerium, terbium and alkaline earth metals and putting the mixture into solvent to get a mixed solution; step 2, impregnating the nanometer pores glass with the mixed solution obtained in step 1; step 3: calcining the impregnated nanometer pores glass obtained in step 2 in a reducing atmosphere, cooling to room temperature, then obtaining the cerium and terbium co-doped alkaline earth metal silicate luminescent glass. Besides, the rare earth ions doped alkaline earth metal silicate luminescent glass prepared with aforesaid method is also provided. In the prepared luminescent glass, cerium ions can transmit absorbed energy to terbium ions under the excitation of UV light due to the co-doping of cerium ions. As a result, the said luminescent glass has higher luminous intensity than the glass only doped with terbium.

Abstract translation: 提供了稀土离子掺杂的碱土金属硅酸盐发光玻璃的制备方法。 步骤包括：步骤1，混合铈，铽和碱土金属的源化合物，并将混合物置于溶剂中以得到混合溶液; 步骤2，用步骤1中获得的混合溶液浸渍纳米孔玻璃; 步骤3：将在步骤2中获得的浸渍的纳米孔玻璃在还原气氛中煅烧，冷却至室温，然后获得共混掺杂的铈和铽的碱土金属硅酸盐发光玻璃。 此外，还提供了用上述方法制备的稀土离子掺杂的碱土金属硅酸盐发光玻璃。 在制备的发光玻璃中，由于铈离子的共同掺杂，铈离子可以在UV光的激发下将吸收的能量传递给铽离子。 结果，所述发光玻璃比仅掺杂铽的玻璃具有更高的发光强度。