Additive compositions and to fuel oils

    公开(公告)号:US10344239B2

    公开(公告)日:2019-07-09

    申请号:US15153796

    申请日:2016-05-13

    Abstract: An additive composition containing a polymer (A) and an anti-static additive (B).The polymer (A) has the following monomer components:(i) one or more compounds of formula (I) wherein R1 is hydrogen or CH3; and R2 is a hydrocarbon group having 6 to 30 carbon atoms and is a straight-chain or branched-chain alkyl group, or an aliphatic or aromatic cyclic group; (ii) one or more compounds of formula (II) wherein R1 has the meaning above and wherein R3 is hydrogen or C1-C22 alkyl; each R4 is independently hydrogen or C1-C22 alkyl; R5 is hydrogen, a substituted or unsubstituted aliphatic or aromatic cyclic group, or a substituted or unsubstituted straight-chain or branched-chain alkyl group having 1 to 22 carbon atoms; n=0 or an integer from 1 to 22; and m is an integer from 1 to 30; and (iii) one or more compounds of formula (III) wherein R6, R7, R8, R9 and R10 are each independently hydrogen, a straight-chain or branched-chain alkyl group having 1 to 20 carbon atoms which may be substituted or unsubstituted, hydroxyl, NH2, or wherein two or more of R6, R7, R8, R9 and R10 may together form an aliphatic or aromatic ring system, which ring system may be substituted or unsubstituted. The anti-static additive (B) is (iv) an olefin polysulfone and (v) a polymeric polyamine reaction product of epichlorohydrin and an aliphatic primary monoamine or an N-aliphatic hydrocarbyl alkylene diamine, or the sulfonic acid salt of the polymeric polyamine reaction product. The weight:weight ratio of the polymer (A) to the anti-static additive (B) in the additive composition is from about 1:1 to about 500:1.

    Fischer-Tropsch derived fuel compositions

    公开(公告)号:US10041013B2

    公开(公告)日:2018-08-07

    申请号:US14653389

    申请日:2013-12-19

    Abstract: A fuel composition comprising a Fischer-Tropsch derived middle distillate fuel and a middle distillate flow improver, the remainder being another fuel component or mixture of fuel components. The other fuel component is selected from petroleum derived middle distillate fuel, hydrogenated vegetable oil, fatty acid methyl esters, and other Fischer Tropsch products. The Fischer-Tropsch derived middle distillate fuel is more than 80% v/v of the total composition; the maximum weight content in the carbon number distribution of the n-paraffins in the Fischer-Tropsch derived middle distillate fuel is below C16 and the weight ratio of iso to normal paraffins in the Fischer-Tropsch derived middle distillate fuel is 3.5:1 or higher. The middle distillate flow improver is a substituted ethylene polymer.

    Fuel oils based on middle distillates and copolymers of ethylene and unsaturated carboxylic esters
    77.
    发明授权
    Fuel oils based on middle distillates and copolymers of ethylene and unsaturated carboxylic esters 失效
    基于中间馏分的燃料油和乙烯和不饱和羧酸酯的共聚物

    公开(公告)号:US06846338B2

    公开(公告)日:2005-01-25

    申请号:US09788261

    申请日:2001-02-19

    CPC classification number: C10L1/1955 C10L1/1963 C10L1/1973 C10L1/2364

    Abstract: A fuel oil comprising: A) a mineral oil having a cloud point of less than −8° C., a boiling range (90-20%) of less than 120° C. and a difference between CFPP and PP of less than 10° C., and B) one or more copolymers, wherein the copolymers comprise: a) bivalent structural unit (B1), wherein (B1) is a bivalent structural unit of formula (1) —CH2—CH2—  (1) and b) one or more bivalent structural units (B2), wherein (B2) is either a bivalent structural unit of formula (2) —CH2—CR1R2—  (2)  in which R1 is hydrogen or methyl, R2 is COOR3, OR3 or OCOR3, and R3 is an alkyl radical having at least 4 and at most 30 carbon atoms, or (B2) is a bivalent structural unit of formula (2a)  in which R3 is an alkyl radical having at least 4 and at most 30 carbon atoms.

    Abstract translation: 一种燃油,包括:A)浊点小于-8℃的矿物油,小于120℃的沸程(90-20%)和CFPP与PP之间的差异小于10 其中所述共聚物包括:a)二价结构单元(B1),其中(B1)是式(1)的二价结构单元,和b)一个或多个二价结构单元(B2) 其中(B2)是式(2)的二价结构单元,其中R 1是氢或甲基,R 2是COOR 3,OR 3或OCOR 3,R 3是 是具有至少4个且至多30个碳原子的烷基,或(B2)是式(2a)的二价结构单元,其中R 3是具有至少4个且至多30个碳原子的烷基。

    Fuel composition
    79.
    发明授权
    Fuel composition 失效
    燃油组成

    公开(公告)号:US6015441A

    公开(公告)日:2000-01-18

    申请号:US930399

    申请日:1997-09-30

    Abstract: A fuel oil composition comprising: (A) a major proportion of a middle distillate petroleum fuel having a wax content of less than 2 wt % at 10.degree. C. below the wax appearance point of the fuel, and either: (i) a final boiling point of greater than 355.degree. C. and either a (90-20%) distillation range of greater than 115 .degree. C. or a (FBP-90%) distillation range of 30.degree. C. or greater; or (ii) a final boiling point of greater than 360.degree. C. and either a (90-20%) distillation range of greater than 110.degree. C. or a (FBP-90%) distillation range of 25.degree. C. or greater; or (iii) a final boiling point of greater than 370.degree. C. and either a (90-20%) distillation range of greater than 100.degree. C. or a (FBP-90%) distillation range of 250.degree. C. or greater), and (B) a minor proportion of an additive comprising: (B1) an ethylene-unsaturated ester copolymer flow improver, other than an ethylene-vinyl acetate bipolymer, the flow improver having an unsaturated ester content of greater than 10 mole %; and, optionally, (B2) an ethylene-unsaturated ester copolymer that is different from (B1).

    Abstract translation: PCT No.PCT / EP96 / 01728 Sec。 371日期:1997年9月30日 102(e)1997年9月30日PCT 1996年4月23日PCT PCT。 公开号WO96 / 34073 日期:1996年10月31日燃料油组合物包含:(A)在燃料的蜡外观点以下10℃下蜡含量小于2重量%的中间馏分石油燃料的主要部分,以及: (i)最终沸点大于355℃,(90-20%)蒸馏范围大于115℃或(FBP-90%)蒸馏范围为30℃或更高; 或(ii)终沸点大于360℃,(90-20%)蒸馏范围大于110℃或(FBP-90%)蒸馏范围为25℃或更高 ; 或(iii)大于370℃的最终沸点和大于100℃的(90-20%)蒸馏范围或250℃或更高的(FBP-90%)蒸馏范围 )和(B)少量添加剂,其包含:(B1)不同于乙烯 - 乙酸乙烯酯共聚物的乙烯 - 不饱和酯共聚物流动改进剂,所述流动改进剂具有大于10摩尔%的不饱和酯含量; 和(B1)与(B1)不同的(B2)乙烯 - 不饱和酯共聚物。

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