Coated polydivinbenzene beads
    83.
    发明申请
    Coated polydivinbenzene beads 有权
    涂层聚丹宁苯珠

    公开(公告)号:US20080255269A1

    公开(公告)日:2008-10-16

    申请号:US12080269

    申请日:2008-04-01

    Abstract: The present invention provides novel, polymeric supports, methods of making, and methods of using the supports, that have a fluorinated, amidated surface. The supports include polymeric microbeads, thin layers or membranes, plates, monoliths and the like. The supports are useful as packing materials for normal phase, reverse phase, and size exclusion chromatography, and provide high speed separation of analytes with excellent resolution. The fluorinated, amidated surface may include a composition comprising a plurality of repeating units, for example, having the following structure:

    Abstract translation: 本发明提供具有氟化的酰胺化表面的新颖的聚合物载体,制备方法和使用载体的方法。 载体包括聚合物微珠,薄层或膜,板,整料等。 该载体可用作正相,反相和尺寸排阻层析的包装材料,并且以优异的分辨率提供分析物的高速分离。 氟化的酰胺化表面可以包括包含多个重复单元的组合物,例如具有以下结构:

    Surface-modified base matrices
    85.
    发明授权
    Surface-modified base matrices 失效
    表面修饰基础矩阵

    公开(公告)号:US07423070B2

    公开(公告)日:2008-09-09

    申请号:US10517293

    申请日:2003-06-18

    Abstract: The present invention is a surface-modified base matrix comprised of a porous polymeric base matrix onto which branched hydrophilic polyhydroxy-functional polymers have been covalently attached, wherein the polyhydroxy-functional polymers are hyperbranched polymers presenting a degree of branching (DB) of at least about 0.2 and each polymer is tethered to the base matrix at two or more points. The present matrix can for example be a cross-linked carbohydrate material, such as agarose, and the hyperbranched hydrophilic polymer can e.g. be a copolymer of epichiorohydrin and a sugar. The invention also relates to a method of surface-modification of a porous base matrix by activating functional hydroxy groups thereon and contacting the activated matrix with a hydrophilic hyperbranched hydroxy-functional polymer.

    Abstract translation: 本发明是由多孔聚合物基质基质组成的表面改性的基质基质,其上分支的亲水性多羟基官能聚合物已共价连接到其上,其中多羟基官能聚合物是具有至少一种支化度(DB)的超支化聚合物 约0.2,并且每个聚合物在两个或更多个点处连接到基础基质上。 本发明的基质可以例如是交联的碳水化合物材料,例如琼脂糖,并且超支化亲水性聚合物可以例如。 是表氯醇和糖的共聚物。 本发明还涉及通过在其上活化官能羟基并使活化的基质与亲水性超支化羟基官能聚合物接触来表面改性多孔基质基质的方法。

    Functionalized porous poly(aryl ether ketone) materials and their use
    87.
    发明授权
    Functionalized porous poly(aryl ether ketone) materials and their use 有权
    官能化多孔聚(芳醚酮)材料及其用途

    公开(公告)号:US07368526B2

    公开(公告)日:2008-05-06

    申请号:US11548078

    申请日:2006-10-10

    Abstract: Functionalized porous poly(aryl ether ketone) articles are prepared by reacting ketone groups in the backbone of poly(aryl ether ketone) polymer with a primary amine reagent. Preferred functional primary amines are primary aliphatic amines or substituted hydrazines containing one or more target functional groups including polar groups, such as hydroxyl groups, ˜OH, amino groups, ˜NH2, ˜NHR, ˜NRR′, and ethylene oxide groups, ˜OCH2CH2—, negatively or positively charged ionic groups, such as ˜SO3−, ˜COO−, and ˜NH4+ groups, hydrophobic groups such as siloxane or perfluorcarbone groups, and non-polar groups, such as linear or branched hydrocarbon groups. The functionalized porous poly(aryl ether ketone) article can be prepared by reacting primary amine with a pre-formed, shaped porous poly(aryl ether ketone) article or by functionalizing the surface of a non-porous precursor article that is subsequently converted into a porous article.

    Abstract translation: 官能化多孔聚(芳醚酮)制品是通过使聚(芳基醚酮)聚合物的主链中的酮基与伯胺试剂反应来制备的。 优选的官能伯胺是含有一个或多个靶官能团的主要脂族胺或取代肼,包括极性基团,例如羟基,-OH,氨基,〜NH 2,〜NHR,〜NRR' ,和环氧乙烷基团,-OCH 2 CH 2 - ,带正电或带正电荷的离子基团,例如SO 3 - 和/或者NH 4基团,疏水基团如硅氧烷或全氟咔唑基团,和非极性基团 基团,例如直链或支链烃基。 官能化的多孔聚(芳醚酮)制品可以通过使伯胺与预形成的多孔聚(芳醚酮)制品反应或通过官能化无孔前体制品的表面来制备,随后将其转化为 多孔制品。

    Oxygen absorber
    90.
    发明申请
    Oxygen absorber 有权
    吸氧剂

    公开(公告)号:US20070123647A1

    公开(公告)日:2007-05-31

    申请号:US10581196

    申请日:2004-11-26

    Abstract: The present invention provides an oxygen absorber which exhibits a high oxygen-absorbing ability even if a transition metal salt as a catalyst for making oxygen-absorbing ability high is not added thereto and further keeps a high mechanical strength even after the absorber absorbs oxygen. An oxygen absorber containing a cyclized conjugated diene polymer as an active ingredient. About the cyclized conjugated diene polymer, the percent decrease in unsaturated-bond amount is preferably 10% or more and the weight-average molecular weight preferably ranges 1,000 to 1,000,000. The oxygen absorber may further contain a thermoplastic resin. The content of an antioxidant in the oxygen absorber is preferably 500 ppm or lower. The oxygen absorber is in a film, sheet or powder.

    Abstract translation: 本发明提供即使在吸收剂吸收氧之后,即使作为吸氧能力高的催化剂的过渡金属盐也不会添加到氧吸收能力高的氧吸收剂,也能够保持高的机械强度。 含有环状共轭二烯聚合物作为活性成分的氧吸收剂。 关于环化共轭二烯聚合物,不饱和键的量的降低百分比优选为10%以上,重均分子量优选为1,000〜1,000,000。 氧吸收剂还可以含有热塑性树脂。 氧吸收剂中的抗氧化剂的含量优选为500ppm以下。 氧吸收剂是膜,片或粉末。

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