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    Polyamide-containing ligating agents bonded to inorganic and organic polymeric supports and methods of using the same for removing and concentrating desired metal ions from solutions
    81.
    发明授权
    Polyamide-containing ligating agents bonded to inorganic and organic polymeric supports and methods of using the same for removing and concentrating desired metal ions from solutions 失效
    与无机和有机聚合物载体结合的含聚酰胺的连接剂以及使用它们从溶液中除去和浓缩所需金属离子的方法

    公开(公告)号：US06506706B1

    公开(公告)日：2003-01-14

    申请号：US09406256

    申请日：1999-09-27

    Applicant: Ronald L. Bruening ,  Krzysztof E. Krakowiak

    Inventor： Ronald L. Bruening ,  Krzysztof E. Krakowiak

    IPC: B01J2022

    CPC classification number: B01J45/00

    Abstract: Compositions and methods for selectively binding metal ions from source solutions are disclosed. The composition is comprised of a polyamide-containing ligand covalently bonded to a particulate solid support through a hydrophilic spacer having the formula SS—A—X—L. In this formula, SS is a particulate solid support such as silica or a polymeric bead, A is a covalent linkage mechanism, X is a hydrophilic spacer grouping, and L is a polyamide-containing ligand having three or more amide groups and two or more amine nitrogens separated by at least two carbons with the proviso that when SS is a particulate organic polymer, A—X may be combined as a single covalent linkage. The separation is accomplished by passing a source solution containing the ions to be separated through a column containing the particulate composition, causing the selected ions to be complexed to the polyamide-containing ligands, and subsequently removing the selected ions from the column by passing an aqueous receiving solution through the column and quantitatively stripping the selected ions from the polyamide-containing ligand.

    Abstract translation: 公开了用于选择性地结合源溶液的金属离子的组合物和方法。 该组合物由含有通过具有式SS-A-X-L的亲水间隔物共价结合到颗粒固体支持物上的含聚酰胺的配体组成。 在该配方中，SS是颗粒状固体载体如二氧化硅或聚合物珠，A是共价连接机理，X是亲水间隔基，L是含有三个或更多个酰胺基团和两个或更多个酰胺基团的含聚酰胺的配体 通过至少两个碳原子分隔的胺氮，条件是当SS是颗粒状有机聚合物时，AX可以作为单一共价键组合。 通过将含有要分离的离子的源溶液通过含有颗粒组合物的柱进行分离，使所选择的离子与含有聚酰胺的配体络合，然后通过使水溶液 通过柱接收溶液并定量地从含聚酰胺的配体中剥离选定的离子。

    Process for performing polynucleotide separations
    82.
    发明授权
    Process for performing polynucleotide separations 失效
    进行多核苷酸分离的方法

    公开(公告)号：US06471866B1

    公开(公告)日：2002-10-29

    申请号：US09705084

    申请日：2000-11-02

    Applicant: Douglas T. Gjerde ,  Robert M. Haefele ,  David Togami

    Inventor： Douglas T. Gjerde ,  Robert M. Haefele ,  David Togami

    IPC: B01D1508

    CPC classification number: C12N15/101 ,  B01D15/12 ,  B01D15/366 ,  B01D15/38 ,  B01J45/00 ,  G01N30/14 ,  G01N2030/528

    Abstract: The invention recognizes the deleterious effects of trace, and even undetectable amounts of multivalent cations on the separation of mixtures of polynucleotides, especially double stranded polynucleotides, and provides an improved method for separating such mixtures on wide pore, non-polar separation media by eliminating multivalent cations from the all aspects of the separation process. This is accomplished by using components in the separation process which are materials which do not release metal cations. In addition, the use of cation capture resins and other methods to remove residual traces of multivalent cations from eluting solvents, sample solutions, separation media, and system components is described. It is also important to remove any traces or organic contaminants from solvents solutions and system parts. Taking similar steps to remove residual traces of multivalent cations and organic impurities from the separation process, the invention may also be used in a batch process to separate mixtures of polynucleotide fragments.

    Abstract translation: 本发明认识到痕量，甚至不可检测量的多价阳离子对多核苷酸，特别是双链多核苷酸混合物的分离的有害影响，并且提供了一种通过消除多价分离在宽孔非极性分离介质上分离这些混合物的改进方法 阳离子从分离过程的各个方面。 这是通过在分离过程中使用不释放金属阳离子的材料来实现的。 此外，描述了使用阳离子捕获树脂和其它方法从洗脱溶剂，样品溶液，分离介质和系统组分中除去多价阳离子的残留痕迹。 从溶剂溶液和系统部件中除去痕迹或有机污染物也很重要。 采取类似的步骤从分离过程中除去多价阳离子和有机杂质的残留痕迹，本发明也可以以分批方法用于分离多核苷酸片段的混合物。

    Solid-phase materials for chelating metal ions and methods of making and using same
    84.
    发明申请
    Solid-phase materials for chelating metal ions and methods of making and using same 失效
    用于螯合金属离子的固相材料及其制备和使用方法

    公开(公告)号：US20020114961A1

    公开(公告)日：2002-08-22

    申请号：US09745024

    申请日：2000-12-20

    Applicant: Bechtel BWTX Idaho, LLC

    Inventor： Mason K. Harrup ,  John E. Wey ,  Eric S. Peterson

    IPC: B32B009/04

    CPC classification number: C02F1/683 ,  B01J45/00 ,  C02F1/28 ,  C02F2101/20 ,  Y10T428/252

    Abstract: A solid material for recovering metal ions from aqueous streams, and methods of making and using the solid material, are disclosed. The solid material is made by covalently bonding a chelating agent to a silica-based solid, or in-situ condensing ceramic precursors along with the chelating agent to accomplish the covalent bonding. The chelating agent preferably comprises a oxime type chelating head, preferably a salicylaldoxime-type molecule, with an organic tail covalently bonded to the head. The hydrocarbon tail includes a carbon-carbon double bond, which is instrumental in the step of covalently bonding the tail to the silica-based solid or the in-situ condensation. The invented solid material may be contacted directly with aqueous streams containing metal ions, and is selective to ions such as copper (II) even in the presence of such ions as iron (III) and other materials that are present in earthen materials. The solid material with high selectivity to copper may be used to recover copper from mining and plating industry streams, to replace the costly and toxic solvent extraction steps of conventional copper processing.

    Abstract translation: 公开了一种用于从水流中回收金属离子的固体材料，以及制备和使用固体材料的方法。 固体材料通过将螯合剂共价键合到二氧化硅基固体上，或者与螯合剂一起原位冷凝陶瓷前体来实现共价键。 螯合剂优选包含肟型螯合头，优选水杨醛肟型分子，其共价键合到头上。 烃尾部包括碳 - 碳双键，其在将尾部共价键合到二氧化硅基固体或原位冷凝的步骤中起作用。 本发明的固体材料可以直接与含有金属离子的含水物流接触，即使在诸如铁（III）和其它存在于土壤材料中的其它材料的离子存在下，也可对离子（例如铜（II））进行选择。 对铜的高选择性的固体材料可用于从采矿和电镀工业流中回收铜，以代替常规铜加工的昂贵且有毒的溶剂萃取步骤。

    Method for concentrating, removing, and separating selected ions from source solutions using particulate solid supports functionalized with polyhydroxypyridinone ligands
    85.
    发明授权
    Method for concentrating, removing, and separating selected ions from source solutions using particulate solid supports functionalized with polyhydroxypyridinone ligands 失效
    使用用聚羟基吡啶酮配体官能化的颗粒固体支持物从源溶液中浓缩，除去和分离所选离子的方法

    公开(公告)号：US6432313B2

    公开(公告)日：2002-08-13

    申请号：US83213901

    申请日：2001-04-06

    Applicant: IBC ADVANCED TECH INC

    Inventor： BRUENING RONALD L ,  KRAKOWIAK KRZYSZTOF E

    IPC: B01J20/32 ,  B01J45/00 ,  B01D15/00

    CPC classification number: B01J45/00 ,  B01J20/3204 ,  B01J20/321 ,  B01J20/3219 ,  B01J20/3251 ,  B01J20/3255

    Abstract: Compositions and methods for selectively binding metal ions from a source solution comprise using a polyhydroxypyridinone-containing ligand covalently bonded to a particulate solid support through a hydrophilic spacer of the formula SS-A-X-L (HOPO)n where SS is a particulate solid support such as silica or a polymeric bead, A is a covalent linkage mechanism, X is a hydrophilic spacer grouping, L is a ligand carrier, HOPO is a hydroxypyridinone appropriately spaced on the ligand carrier to provide a minimum of six functional coordination metal binding sites, and n is an integer of 3 to 6 with the proviso that when SS is a particulate organic polymer, A-X may be combined as a single covalent linkage. The separation is accomplished by passing a source solution containing the ions to be separated through a column containing the particulate composition, causing the selected ions to be complexed to the HOPO ligands and subsequently removing the selected ions from the column by passing an aqueous receiving solution through the column and quantitatively stripping the selected ions from the HOPO ligand.

    Abstract translation: 用于选择性地结合来自源溶液的金属离子的组合物和方法包括使用通过式SS-AXL（HOPO）n的亲水间隔物共价键合到颗粒状固体载体上的聚羟基吡啶酮配体，其中SS是颗粒状固体载体如二氧化硅 或聚合物珠，A是共价连接机理，X是亲水间隔基，L是配体载体，HOPO是在配体载体上适当间隔开的羟基吡啶酮，以提供至少六个功能性配位金属结合位点，n是 3至6的整数，条件是当SS为颗粒状有机聚合物时，可将AX作为单一共价键组合。 通过将含有待分离的离子的源溶液通过含有颗粒组合物的柱，使所选择的离子与HOPO配体络合并随后通过使含水接收溶液通过而从柱中除去所选择的离子来实现分离 柱并定量地从HOPO配体中剥离选定的离子。

    Calixpyrroles, calixpyridinopyrroles, and calixpyridines
    86.
    发明申请
    Calixpyrroles, calixpyridinopyrroles, and calixpyridines 有权
    杯状吡咯，杯状吡啶并吡咯和卡吡啶

    公开(公告)号：US20020026047A1

    公开(公告)日：2002-02-28

    申请号：US09838998

    申请日：2001-04-20

    Inventor： Philip A. Gale ,  Jonathan L. Sessler ,  John W. Genge ,  Vladimir A. Kral ,  Andrei Andrievsky ,  Vincent Lynch ,  Petra I. Sansom ,  William E. Allen ,  Christopher T. Brown ,  Andreas Gebauer

    IPC: C07D487/22

    CPC classification number: G01N30/482 ,  B01J45/00 ,  B01J2220/54 ,  C07D487/22 ,  C07D495/22 ,  C07D498/22 ,  C07F17/02 ,  G01N30/02 ,  G01N30/88 ,  G01N2030/484 ,  G01N2030/8818 ,  G01N2030/8836 ,  G21F9/06 ,  G21F9/12 ,  B01D15/26

    Abstract: The present invention provides calixpyrrole, calixpyridinopyrrole, and calixpyridine macrocycles, having 4, 5, 6, 7, or 8 heterocyclic rings, as well as syntheses, derivatives. conjugates, multimers, and solid supports thereof. Such macrocycles have proved to be effective and selective ion- and neutral molecule-binding agents forming supramolecular ensembles, and ion- and neutral molecule-separation agents. The macrocycles are fully meso-non-hydrogen-substituted porphyrinogens, a few molecules of which were previously known but not recognized as possessing anion- or molecule-binding properties. The binding mode is noncovalent, primarily that of hydrogen-bonding, thereby providing a new mode for liquid chromatography, that of Hydrogen Bonding Liquid Chromatography. Further useful applications of the macrocycles provided herein include environmental remediation by removal of undesired ions or neutral molecules, and removal of phosphate for kidney dialysis.

    Abstract translation: 本发明提供具有4,5,6,7或8个杂环的杯状吡咯，杯状吡啶并吡咯和杯状吡啶大环，以及合成衍生物。 缀合物，多聚体和固体支持物。 已经证明这种大环化合物是有效和选择性的离子和中性分子结合剂形成超分子集合，以及离子和中性分子分离剂。 大环是完全中和非氢取代的卟啉原子，其中几个分子先前已知但不被认为具有阴离子或分子结合性质。 结合模式是非共价键，主要是氢键合，因此提供了液相色谱法，氢键合液相色谱法的新模式。 本文提供的大环的进一步有用的应用包括通过去除不需要的离子或中性分子进行环境修复，以及除去用于肾透析的磷酸盐。

    Chelate-forming fiber, process for preparing the same, and use thereof
    89.
    发明授权
    Chelate-forming fiber, process for preparing the same, and use thereof 有权
    螯合物形成纤维，其制备方法及其用途

    公开(公告)号：US06200481B1

    公开(公告)日：2001-03-13

    申请号：US09405000

    申请日：1999-09-27

    Applicant: Nobuyoshi Nambu ,  Osamu Ito ,  Nobutake Mihara ,  Koujirou Nagatsuka

    Inventor： Nobuyoshi Nambu ,  Osamu Ito ,  Nobutake Mihara ,  Koujirou Nagatsuka

    IPC: D06M13328

    CPC classification number: B01J45/00 ,  D06M13/148 ,  Y10S210/911

    Abstract: A chelate-forming fiber which has, in a fiber molecule, a group having an amino group and at least two hydroxyl groups bonded to carbon (preferably a group represented by the formula (1) described below), and has a capability of forming a chelate with metalloid elements including boron and germanium and compounds thereof, and which can be easily incinerated and can be prepared in a simple and safe manner at low cost; and a process for preparing the same; and a method for capturing metalloids or compounds thereof using the chelate-forming fiber are disclosed. (wherein G represents a sugar alcohol residue or a polyhydric alcohol residue, and R represents a hydrogen atom, a (lower) alkyl group, or G (G is as defined above and may be a group identical with or different from the above G).)

    Abstract translation: 在纤维分子中具有氨基和至少两个与碳键合的羟基（优选由下述式（1）表示的基团）的基团的螯合形成性纤维，并且具有形成 与包括硼和锗的准金属元素及其化合物螯合，并且可以容易地焚化并且可以以简单和安全的方式以低成本制备; 及其制备方法; 公开了使用螯合形成纤维捕获准金属或其化合物的方法（其中G表示糖醇残基或多元醇残基，R表示氢原子，（低级）烷基或G（G 如上所定义，可以是与上述G相同或不同的基团。）

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