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1.发明授权Detector for the detection of chemical species or photons using a field effect transistor 失效使用场效应晶体管检测化学物质或光子的检测器
公开(公告)号：US5431883A
公开(公告)日：1995-07-11
申请号：US187808
申请日：1994-01-27
Applicant: Andre Barraud
Inventor： Andre Barraud
IPC: G01N27/414 , H01L29/78
CPC classification number: G01N27/414
Abstract: The invention relates to a detector or sensor for the detection of chemical species or photons. This detector uses a field effect transistor having a semiconducting material substrate (1) in which are defined a source (3) and a drain (5), a gate (9) separated from the substrate by an insulating layer, an external energy source for polarizing the drain, source and gate of the transistor, a film (11), which is conductive or which can be rendered conductive and which is sensitive to the chemical species or photons to be detected, and an ammeter for measuring an electric current variation of the transistor. The arrangement of the film (11) between the connections of the gate (9) and the drain (5) makes it possible to modify the polarization voltage of the transistor gate under the effect of the species to be detected, which is represented by a variation of the current between the drain and the source, when the transistor is correctly polarized.
Abstract translation: 本发明涉及用于检测化学物质或光子的检测器或传感器。 该检测器使用具有半导体材料衬底（1）的场效应晶体管，其中限定了源极（3）和漏极（5），通过绝缘层与衬底分离的栅极（9），外部能量源 使晶体管的漏极，源极和栅极偏振，导电或可导电并且对待检测的化学物质或光子敏感的膜（11）和用于测量电流变化的电流计 晶体管。 在栅极（9）和漏极（5）的连接之间的膜（11）的布置使得可以在被检测物质的作用下修改晶体管栅极的极化电压，其由 当晶体管正确极化时，漏极和源极之间的电流变化。
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2.发明授权Process for producing a thin film having at least one monomolecular layer of non-amphiphilic molecules 失效制造具有至少一个非两亲分子单分子层的薄膜的方法
公开(公告)号：US4632800A
公开(公告)日：1986-12-30
申请号：US732279
申请日：1985-05-09
Applicant: Andre Barraud , Annie Ruaudel , Michel Vandevyver
Inventor： Andre Barraud , Annie Ruaudel , Michel Vandevyver
Abstract: Process for producing a film having at least one monomolecular layer of non-amphiphilic molecules.This process comprises the following stages:(a) combining non-amphiphilic molecules A, such as pyridine, with amphiphilic molecules B, such as a zinc porphyrin, in order to form a complex of molecules A and B;(b) forming on the surface of the liquid a monomolecular layer of the thus obtained complex, and(c) transferring the thus formed monomolecular layer to a rigid support.Molecules A and B can form between them a charge transfer complex, e.g. TCNQ-alkyl pyridinium which makes it possible to obtain laminated structures of organic conductors.
Abstract translation: 制造具有至少一个非两亲分子单分子层的膜的方法。 该方法包括以下步骤：（a）将非两性分子A如吡啶与两亲分子B如卟啉锌合并，以形成分子A和B的络合物; （b）在液体的表面上形成由此得到的复合物的单分子层，和（c）将由此形成的单分子层转移到刚性载体上。 分子A和B可以在它们之间形成电荷转移络合物，例如 TCNQ-烷基吡啶鎓，可以获得有机导体的层叠结构。
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3.发明授权Material containing microaggregates of metals, inorganic compounds or organometallic compounds, more particularly usable in heterogeneous catalysis and its production process 失效含有金属微粒子，无机化合物或有机金属化合物的材料，更特别适用于多相催化及其制备方法
公开(公告)号：US4598056A
公开(公告)日：1986-07-01
申请号：US680354
申请日：1984-12-11
Applicant: Andre Barraud , Jean Leloup , Annie Ruaudel
Inventor： Andre Barraud , Jean Leloup , Annie Ruaudel
CPC classification number: B01J37/024 , B01J35/065
Abstract: The material comprises a membrane constituted either by at least one monomolecular layer of amphiphilic molecules, or by amphiphilic molecules adsorbed on a substrate, and microaggregates of the metal, inorganic compound or organometallic compound retained on or in the membrane. It is prepared from a membrane containing a metal ion or a precursor compound of said metal, inorganic compound or organometallic compound, by reacting the ion or precursor compound fixed in the membrane with at least one reagent for forming the metal, inorganic compound or organometallic compound in situ in the membrane. For example, the membrane can be constituted by monomolecular layers of behenic acid, which is then converted into silver behenate by contacting with a silver nitrate solution. Silver microaggregates are then formed in the membrane by reducing the silver behenate by means of hydrazine.
Abstract translation: 该材料包括由两亲分子的至少一个单分子层或吸附在基底上的两亲分子构成的膜，以及保留在膜上或膜中的金属，无机化合物或有机金属化合物的微团聚体。 通过将固定在膜中的离子或前体化合物与形成金属，无机化合物或有机金属化合物的至少一种试剂反应，由含有金属离子或所述金属，无机化合物或有机金属化合物的前体化合物的膜制备 原位在膜中。 例如，膜可以由山嵛酸的单分子层构成，然后通过与硝酸银溶液接触而转化成山嵛酸银。 然后通过用肼还原山嵛酸银，在膜中形成银微团聚体。
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4.发明授权Electrically conducting films comprising at least one monomolecular layer of an organic charge transfer complex 失效包含至少一个有机电荷转移络合物的单分子层的导电膜
公开(公告)号：US4803011A
公开(公告)日：1989-02-07
申请号：US732413
申请日：1985-05-09
Applicant: Andre Barraud , Annie Ruaudel , Michel Vandevyver
Inventor： Andre Barraud , Annie Ruaudel , Michel Vandevyver
IPC: H01B5/14 , B05D1/18 , B05D1/20 , B05D7/04 , B32B7/02 , C08J5/18 , C08J7/04 , H01B1/12 , H01B13/00 , H01L51/30 , H01B1/00
CPC classification number: H01B1/121 , B82Y30/00 , H01L51/0051 , Y10T428/26 , Y10T428/268 , Y10T428/31504
Abstract: Electrically-conducting films comprising at least one monomolecular layer of an organic charge transfer complex and their production process.These films comprise at least one monomolecular layer of an organic charge transfer complex having at least one electron acceptor group and at least one electron donor group, the electron acceptor and/or donor group having at least one hydrocarbon chain with 16 to 30 carbon atoms and the electron acceptor and/or donor groups being organized in such a way that two adjacent groups of the same type, namely electron donors or electron acceptors, can be sufficiently coupled in the plane of the layer to exchange an electron and ensure an electrical conduction in said plane.The charge transfer complex can be an alkyl pyridinium-tetracyanoquinodimethane.
Abstract translation: 包含有机电荷转移络合物的至少一个单分子层的导电膜及其制造方法。 这些膜包含具有至少一个电子受体基团和至少一个电子给体基团的有机电荷转移络合物的至少一个单分子层，该电子受体和/或供体基团具有至少一个具有16至30个碳原子的烃链和 电子受体和/或供体基团以这样的方式组织，使得相同类型的两个相邻基团即电子给体或电子受体可以在层的平面中充分耦合以交换电子并确保电传导 说飞机 电荷转移络合物可以是烷基吡啶鎓 - 四氰基醌二甲烷。
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5.发明授权Device for the formation and deposition on a substrate of monomolecular films 失效用于在单分子膜的基底上形成和沉积的装置
公开(公告)号：US4599969A
公开(公告)日：1986-07-15
申请号：US677012
申请日：1984-11-30
Applicant: Andre Barraud , Jean Lelcuf
Inventor： Andre Barraud , Jean Lelcuf
IPC: B05C9/00 , B05C3/02 , B05C3/09 , B05C3/10 , B05C11/10 , B05C11/11 , B05D1/20 , H01L21/368 , B05C3/00 , B05C11/00 , B05C19/02
Abstract: Tank for depositing a monomolecular film. It comprises a tank having walls and a base and containing a liquid, a barrier defining two areas on the surface of the liquid, means for displacing the barrier on the surface of the liquid, at least one substrate and means for displacing the substrate. The level of the liquid is below the horizontal rim of the tank. The barrier has a break at each of its ends and rests on the edges of the tank. The break defines a narrower portion partly submerged in the liquid. Sealing means are provided between the faces of the narrower portion and the facing walls.
Abstract translation: 用于沉积单分子膜的罐。 它包括具有壁和基部并且容纳液体的槽，限定液体表面上的两个区域的阻挡层，用于移动液体表面上的阻挡层的装置，至少一个基板和用于移动基板的装置。 液体的液位低于罐的水平边缘。 屏障在其每个端部都有一个断裂，并搁置在水箱的边缘上。 断裂定义了部分浸没在液体中的较窄部分。 密封装置设置在较窄部分的表面和相对的壁之间。
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Patent Agency Ranking6.发明授权Device for formation and deposition of monomolecular layers of amphiphilic molecules on a substrate 失效用于在基板上形成和沉积两亲分子的单分子层的装置
公开(公告)号：US4224896A
公开(公告)日：1980-09-30
申请号：US874533
申请日：1978-02-02
Applicant: Andre Barraud , Roger Gras , Michel Vandevyver
Inventor： Andre Barraud , Roger Gras , Michel Vandevyver
Abstract: The monomolecular layer is first formed from a solution of amphiphilic molecules by introduction of the solution on a liquid surface which is divided into at least two compartments by at least one rotatable and partly immersed horizontal member. The solvent is then removed and the horizontal member is driven in rotation so as to apply a predetermined pressure to said layer as this latter is transferred from one compartment to the next, the layer being finally deposited on a substrate.This a division of application Ser. No. 765,063, filed Feb. 2, 1977, now U.S. Pat. No. 4,093,757, issued June 6, 1978.
Abstract translation: 首先通过将溶液引入到通过至少一个可旋转和部分浸没的水平构件至少两个隔室的液体表面上，由两亲分子的溶液形成单分子层。 然后除去溶剂，水平构件被旋转驱动，以便对所述层施加预定的压力，因为后者从一个隔室转移到下一层，该层最后沉积在基底上。
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7.发明授权
公开(公告)号：US4925774A
公开(公告)日：1990-05-15
申请号：US172597
申请日：1988-03-24
Applicant: Andre Barraud , Joel Richard , Michel Vandevyver
Inventor： Andre Barraud , Joel Richard , Michel Vandevyver
CPC classification number: H05K3/02 , H05K1/09 , H05K2201/0329 , H05K2203/107 , H05K2203/1142 , H05K3/027 , Y10S430/146 , Y10S430/168
Abstract: The invention relates to a microlithographic process for producing circuits using organic, conductive films sensitive to electromagnetic radiation and to charged particles.This process for producing electricity conducting zones on a substrate consists of depositing on said substrate a coating of an electricity conducting, organic compound, such as alkyl pyridinium-tetracyanoquinodimethane and then irradiating certain locations (2,3) of the coating by means of charged particles and/or electromagnetic radiation, so that the irradiated locations become insulating and that on the organic compound coating the electricity conducting zones (1) are directly formed at the desired locations.
Abstract translation: 本发明涉及使用对电磁辐射敏感的有机导电膜和带电粒子来制造电路的微光刻工艺。 用于在衬底上产生导电区的该方法包括在所述衬底上沉积导电的有机化合物（例如烷基吡啶鎓 - 四氰基醌二甲烷）的涂层，然后通过带电粒子照射涂层的某些位置（2,3） 和/或电磁辐射，使得照射的位置变得绝缘，并且涂覆导电区（1）的有机化合物在所需位置处直接形成。
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公开(公告)号：US4235958A
公开(公告)日：1980-11-25
申请号：US38072
申请日：1979-05-11
Applicant: Andre Barraud , Jean Messier , Annie Ruaudel
Inventor： Andre Barraud , Jean Messier , Annie Ruaudel
IPC: G03F7/16 , G03C1/00 , G03C1/74 , G03C5/00 , G03F7/004 , G03F7/027 , G03F7/039 , H01L21/027 , G03C1/68
CPC classification number: G03F7/027 , Y10T428/31504
Abstract: Photosensitive film which can be used in microgravure, wherein it comprises at least one organic monomolecular layer having amphiphilic molecules with at least one irradiation polymerizable function and one aliphatic chain with at least 12 carbon atoms, a polymerizable function being located at the hydrophobic end of said molecules.The photosensitive films can be used with particular advantage in the production of microetched objects, such as optical and holographic systems, integrated optical devices and electronic microcircuits.
Abstract translation: 可用于微凹版印刷的感光膜，其中它包含至少一个具有至少一个可照射聚合功能的两亲分子的有机单分子层和至少12个碳原子的一个脂族链，可聚合的功能位于所述 分子。 感光膜可以在生产诸如光学和全息系统，集成光学器件和电子微电路的微蚀刻物体中具有特别的优点。
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9.发明授权Method of forming and depositing monomolecular layers of amphiphilic molecules on a substrate 失效在基材上形成和沉积单亲分子的单分子层的方法
公开(公告)号：US4093757A
公开(公告)日：1978-06-06
申请号：US765063
申请日：1977-02-02
Applicant: Andre Barraud , Roger Gras , Michel Vandevyver
Inventor： Andre Barraud , Roger Gras , Michel Vandevyver
Abstract: The monomolecular layer is first formed from a solution of amphiphilic molecules by introduction of the solution on a liquid surface which is divided into at least two compartments by at least one rotatable and partly immersed horizontal member. The solvent is then removed and the horizontal member is driven in rotation so as to apply a predetermined pressure to said layer as this latter is transferred from one compartment to the next, the layer being finally deposited on a substrate.
Abstract translation: 首先通过将溶液引入到通过至少一个可旋转和部分浸没的水平构件至少两个隔室的液体表面上，由两亲分子的溶液形成单分子层。 然后除去溶剂，水平构件被旋转驱动，以便对所述层施加预定的压力，因为后者从一个隔室转移到下一层，该层最后沉积在基底上。
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10.发明授权Dielectric material having monomolecular layers and capacitors in which said material is employed 失效具有单分子层的电介质材料和使用所述材料的电容器
公开(公告)号：US4017660A
公开(公告)日：1977-04-12
申请号：US617724
申请日：1975-09-29
Applicant: Andre Barraud , Jean Messier
Inventor： Andre Barraud , Jean Messier
CPC classification number: H01B3/20 , H01G4/14 , Y10T428/31678 , Y10T428/31801
Abstract: The dielectric material is constituted by monomolecular layers of an organic substance, the molecules of which have a long aliphatic chain terminating in a hydrophilic group. The substance is selected from the group in which a lateral group is grafted onto the aliphatic chain and is capable of exchanging a hydrogen bond with an identical adjacent molecule.
Abstract translation: 介电材料由有机物质的单分子层构成，其分子具有以亲水基终止的长的脂族链。 该物质选自其中侧基接枝到脂族链上并且能够与相同的相邻分子交换氢键的基团。
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