公开(公告)号：US09662611B2

公开(公告)日：2017-05-30

申请号：US12750001

申请日：2010-03-30

Applicant: Chung-Zong Wan ,  Xiaolai Zheng ,  Suzanne Stiebels ,  Claudia Wendt ,  Torsten Neubauer ,  R. Samuel Boorse

Inventor： Chung-Zong Wan ,  Xiaolai Zheng ,  Suzanne Stiebels ,  Claudia Wendt ,  Torsten Neubauer ,  R. Samuel Boorse

IPC: B01D50/00 ,  B01D47/00 ,  B01D53/94 ,  F01N3/035 ,  F01N3/08 ,  F01N3/20 ,  F01N3/10 ,  F01N13/02

CPC classification number: B01D53/9431 ,  B01D53/58 ,  B01D53/92 ,  B01D53/9418 ,  B01D53/9422 ,  B01D53/9472 ,  B01D53/9477 ,  B01D2251/2062 ,  B01D2255/102 ,  B01D2255/2042 ,  B01D2255/2045 ,  B01D2255/206 ,  B01D2255/2063 ,  B01D2255/2066 ,  B01D2255/2068 ,  B01D2255/20753 ,  B01D2255/20761 ,  B01D2255/2092 ,  B01D2255/50 ,  B01D2255/9022 ,  B01D2255/91 ,  B01D2255/9155 ,  B01D2255/9205 ,  B01D2258/012 ,  F01N3/02 ,  F01N3/021 ,  F01N3/035 ,  F01N3/0807 ,  F01N3/0814 ,  F01N3/0821 ,  F01N3/0842 ,  F01N3/10 ,  F01N3/103 ,  F01N3/206 ,  F01N3/2066 ,  F01N3/2073 ,  F01N13/02 ,  F01N2510/063 ,  F01N2510/0682 ,  Y02T10/24

Abstract: Provided are emissions treatment systems for an exhaust stream having an ammonia-generating component, such as a NOx storage reduction (NSR) catalyst or a lean NOx trap (LNT) catalyst, and an SCR catalyst disposed downstream of the ammonia-generating catalyst. The SCR catalyst can be a molecular sieve having the CHA crystal structure, for example SSZ-13 or SAPO-34, which can be ion-exchanged with copper. The LNT can be layered, having an undercoat washcoat layer comprising a support material, at least one precious metal, and at least one NOx sorbent selected from the group consisting of alkaline earth elements, rare earth elements, and combinations thereof and a top washcoat layer comprising a support material, at least one precious metal, and ceria in particulate form, the top washcoat layer being substantially free of alkaline earth components. The emissions treatment system is advantageously used for the treatment of exhaust streams from diesel engines and lean burn gasoline engines.

公开(公告)号：US08329607B2

公开(公告)日：2012-12-11

申请号：US12687597

申请日：2010-01-14

Applicant: M. Shahjahan Kazi ,  Michel Deeba ,  Torsten Neubauer ,  Alfred Helmut Punke ,  Torsten Wolfgang Mueller-Stach ,  Gerd Grubert ,  Stanley A. Roth ,  Jeffrey Barmont Hoke ,  Shlang Sung ,  Yuejin Li ,  Xinyi Wei ,  Chung-Zong Wan

Inventor： M. Shahjahan Kazi ,  Michel Deeba ,  Torsten Neubauer ,  Alfred Helmut Punke ,  Torsten Wolfgang Mueller-Stach ,  Gerd Grubert ,  Stanley A. Roth ,  Jeffrey Barmont Hoke ,  Shlang Sung ,  Yuejin Li ,  Xinyi Wei ,  Chung-Zong Wan

IPC: B01J29/06 ,  B01J21/00 ,  B01J29/00 ,  B01J23/00 ,  B01J23/42 ,  B01J23/44 ,  B01J8/02 ,  B01D53/56 ,  B01D53/94 ,  B01D50/00 ,  B01D53/34 ,  C01B21/00 ,  C01B23/00 ,  C01B25/00 ,  C01B31/00 ,  C01B33/00 ,  C01B35/00 ,  C01G28/00 ,  C01G30/00

CPC classification number: B01D53/944 ,  B01D2255/1021 ,  B01D2255/1023 ,  B01D2255/206 ,  B01D2255/20707 ,  B01D2255/20715 ,  B01D2255/2092 ,  B01D2255/502 ,  B01D2255/504 ,  B01D2255/9025 ,  B01D2255/912 ,  B01D2255/9205 ,  B01J23/44 ,  B01J29/40 ,  B01J29/44 ,  B01J29/7007 ,  B01J29/7415 ,  B01J35/002 ,  B01J35/023 ,  B01J35/04 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1061 ,  B01J37/0242 ,  B01J37/0244 ,  B01J37/0246

Abstract: Provided are diesel exhaust components where palladium is segregated from a molecular sieve, specifically a zeolite, in a catalytic material. In the catalytic material, therefore, there are at least two layers: a palladium-containing layer that is substantially free of a molecular sieve and a hydrocarbon trap layer that comprises at least one molecular sieve and is substantially free of palladium. The palladium is provided on a high surface area, porous refractory metal oxide support. The catalytic material can further comprise a platinum component, where a minor amount of the platinum component is in the hydrocarbon trap layer, and a majority amount of the platinum component is in the palladium-containing layer. Systems and methods of using the same are also provided.

Abstract translation: 提供了在催化材料中钯与分子筛特别是沸石分离的柴油机排气组分。 因此，在催化材料中，至少有两层：基本上不含分子筛的含钯层和包含至少一个分子筛并且基本上不含钯的烃捕集层。 钯提供在高表面积上，多孔难熔金属氧化物载体。 催化材料还可以包含铂组分，其中少量的铂组分位于烃阱层中，并且大部分量的铂组分在含钯层中。 还提供了使用它们的系统和方法。

公开(公告)号：US20110305614A1

公开(公告)日：2011-12-15

申请号：US13082907

申请日：2011-04-08

Applicant: Susanne Stiebels ,  Claudia Wendt ,  Torsten Neubauer ,  Martin Dieterle ,  Jaya L. Mohanan

Inventor： Susanne Stiebels ,  Claudia Wendt ,  Torsten Neubauer ,  Martin Dieterle ,  Jaya L. Mohanan

IPC: B01D53/94 ,  F01N3/10 ,  F01N3/035 ,  B01J29/80

CPC classification number: B01J29/80 ,  B01D53/8628 ,  B01D53/9418 ,  B01D53/9463 ,  B01D53/9468 ,  B01D53/9472 ,  B01D53/9477 ,  B01D2255/20738 ,  B01D2255/20761 ,  B01D2255/50 ,  B01D2255/504 ,  B01D2255/902 ,  B01D2255/9022 ,  B01D2258/012 ,  B01J29/46 ,  B01J29/763 ,  B01J37/0246

Abstract: Described is a catalyst, preferably for use in selective catalytic reduction (SCR), said catalyst comprising one or more zeolites of the MFI structure type, and one or more zeolites of the CHA structure type, wherein at least part of the one or more zeolites of the MFI structure type contain iron (Fe), and wherein at least part of the one or more zeolites of the CHA structure type contain copper (Cu). An exhaust gas treatment system is described, comprising said catalyst as well as a process for the treatment of a gas stream comprising NOx using said catalyst as well.

Abstract translation: 描述了优选用于选择性催化还原（SCR）的催化剂，所述催化剂包含一种或多种MFI结构型沸石和一种或多种CHA结构型沸石，其中至少部分一种或多种沸石 的MFI结构类型含有铁（Fe），并且其中CHA结构型的一种或多种沸石的至少一部分含有铜（Cu）。 描述了一种废气处理系统，其包括所述催化剂以及用于使用所述催化剂处理包含NOx的气流的方法。

公开(公告)号：US20100186375A1

公开(公告)日：2010-07-29

申请号：US12687597

申请日：2010-01-14

Applicant: M. Shahjahan Kazi ,  Michel Deeba ,  Torsten Neubauer ,  Alfred Helmut Punke ,  Torsten Wolfgang Mueller-Stach ,  Gerd Grubert ,  Stanley A. Roth ,  Jeffrey Barmont Hoke ,  Shiang Sung ,  Yuejin Li ,  Xinyi Wei ,  Chung-Zong Wan

Inventor： M. Shahjahan Kazi ,  Michel Deeba ,  Torsten Neubauer ,  Alfred Helmut Punke ,  Torsten Wolfgang Mueller-Stach ,  Gerd Grubert ,  Stanley A. Roth ,  Jeffrey Barmont Hoke ,  Shiang Sung ,  Yuejin Li ,  Xinyi Wei ,  Chung-Zong Wan

IPC: F01N3/20 ,  B01J29/068 ,  B01D53/94 ,  F01N3/10

CPC classification number: B01D53/944 ,  B01D2255/1021 ,  B01D2255/1023 ,  B01D2255/206 ,  B01D2255/20707 ,  B01D2255/20715 ,  B01D2255/2092 ,  B01D2255/502 ,  B01D2255/504 ,  B01D2255/9025 ,  B01D2255/912 ,  B01D2255/9205 ,  B01J23/44 ,  B01J29/40 ,  B01J29/44 ,  B01J29/7007 ,  B01J29/7415 ,  B01J35/002 ,  B01J35/023 ,  B01J35/04 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1061 ,  B01J37/0242 ,  B01J37/0244 ,  B01J37/0246

Abstract: Provided are diesel exhaust components where palladium is segregated from a molecular sieve, specifically a zeolite, in a catalytic material. In the catalytic material, therefore, there are at least two layers: a palladium-containing layer that is substantially free of a molecular sieve and a hydrocarbon trap layer that comprises at least one molecular sieve and is substantially free of palladium. The palladium is provided on a high surface area, porous refractory metal oxide support. The catalytic material can further comprise a platinum component, where a minor amount of the platinum component is in the hydrocarbon trap layer, and a majority amount of the platinum component is in the palladium-containing layer. Systems and methods of using the same are also provided.

Abstract translation: 提供了在催化材料中钯与分子筛特别是沸石分离的柴油机排气组分。 因此，在催化材料中，至少有两层：基本上不含分子筛的含钯层和包含至少一个分子筛并且基本上不含钯的烃捕集层。 钯提供在高表面积上，多孔难熔金属氧化物载体。 催化材料还可以包含铂组分，其中少量的铂组分位于烃阱层中，并且大部分量的铂组分在含钯层中。 还提供了使用它们的系统和方法。

公开(公告)号：US20100180582A1

公开(公告)日：2010-07-22

申请号：US12686827

申请日：2010-01-13

Applicant: Torsten Wolfgang Mueller-Stach ,  Torsten Neubauer ,  Alfred Helmut Punke ,  Gerd Grubert ,  Attilio Siani ,  Corinna Freitag

Inventor： Torsten Wolfgang Mueller-Stach ,  Torsten Neubauer ,  Alfred Helmut Punke ,  Gerd Grubert ,  Attilio Siani ,  Corinna Freitag

IPC: F01N3/035 ,  B01J29/068 ,  B01D53/94

CPC classification number: B01D53/944 ,  B01D2255/1021 ,  B01D2255/1023 ,  B01D2255/502 ,  B01D2255/9025 ,  B01D2255/912 ,  B01D2255/9205 ,  B01D2255/9207 ,  B01D2258/012 ,  B01J23/44 ,  B01J29/7415 ,  B01J35/0006 ,  B01J37/0244 ,  B01J37/0246 ,  F01N2510/0682

Abstract: Provided is a diesel oxidation catalyst for the treatment of exhaust gas emissions from a diesel engine and a method for treating a diesel exhaust gas stream, the method comprising providing a diesel oxidation catalyst and contacting said diesel exhaust gas stream with said diesel oxidation catalyst for the treatment of exhaust gas emissions. More particularly, the present invention is directed to a catalyst structure comprising three distinct layers; in which layer comprises a precious metal component such as palladium is located between two hydrocarbon storage layers comprising a molecular sieve such as a zeolite.

Abstract translation: 提供了一种用于处理来自柴油发动机的废气排放物的柴油氧化催化剂和用于处理柴油机废气流的方法，所述方法包括提供柴油机氧化催化剂并将所述柴油机废气流与所述柴油机氧化催化剂接触，用于 处理废气排放。 更具体地，本发明涉及包含三个不同层的催化剂结构; 其中包含贵金属组分如钯的层位于包含分子筛如沸石的两个烃储存层之间。

公开(公告)号：US09079162B2

公开(公告)日：2015-07-14

申请号：US13082697

申请日：2011-04-08

Applicant: Susanne Stiebels ,  Claudia Wendt ,  Torsten Neubauer ,  Edith Schneider ,  Ryuji Ando ,  Takashi Hihara ,  Yasuharu Kanno ,  Makoto Nagata

Inventor： Susanne Stiebels ,  Claudia Wendt ,  Torsten Neubauer ,  Edith Schneider ,  Ryuji Ando ,  Takashi Hihara ,  Yasuharu Kanno ,  Makoto Nagata

IPC: B01J29/04 ,  B01J29/06 ,  B01J29/18 ,  C01G1/00 ,  C01B33/36 ,  B01J29/80 ,  B01D53/94 ,  B01J37/02 ,  B01J29/46 ,  B01J29/76

CPC classification number: B01J29/80 ,  B01D53/9418 ,  B01D2251/2062 ,  B01D2251/2067 ,  B01D2251/208 ,  B01D2255/20738 ,  B01D2255/50 ,  B01D2255/502 ,  B01D2258/012 ,  B01J29/46 ,  B01J29/7615 ,  B01J37/0246

Abstract: Disclosed is a catalyst, preferably for use in selective catalytic reduction (SCR), said catalyst comprising one or more zeolites of the MFI structure type, and one or more zeolites of the BEA structure type, wherein at least part of the one or more zeolites of the MFI structure type and at least part of the one or more zeolites of the BEA structure type respectively contain iron (Fe). Furthermore, an exhaust gas treatment system is described, comprising said catalyst as well as a process for the treatment of a gas stream comprising NOx using said catalyst as well.

Abstract translation: 公开了优选用于选择性催化还原（SCR）的催化剂，所述催化剂包含一种或多种MFI结构型沸石和一种或多种BEA结构型沸石，其中至少部分一种或多种沸石 的MFI结构类型和BEA结构类型的一种或多种沸石的至少一部分分别含有铁（Fe）。 此外，描述了包括所述催化剂的废气处理系统以及用于使用所述催化剂处理包含NOx的气流的方法。

公开(公告)号：US20080219906A1

公开(公告)日：2008-09-11

申请号：US11971515

申请日：2008-01-09

Applicant: Shau-Lin F. Chen ,  Knut Wassermann ,  Stephan Siemund ,  Tian Luo ,  Torsten Neubauer ,  Jin Sakakibara ,  Harold Rabinowitz

Inventor： Shau-Lin F. Chen ,  Knut Wassermann ,  Stephan Siemund ,  Tian Luo ,  Torsten Neubauer ,  Jin Sakakibara ,  Harold Rabinowitz

IPC: B01J23/40 ,  B01J23/42 ,  B01J23/00 ,  B01J21/00 ,  B01D53/94

CPC classification number: B01J37/0244 ,  B01D53/945 ,  B01D2255/1021 ,  B01D2255/1023 ,  B01D2255/1025 ,  B01D2255/2092 ,  B01D2255/502 ,  B01D2255/9027 ,  B01D2255/908 ,  B01J23/40 ,  B01J23/63 ,  Y02T10/22

Abstract: A multilayered, three-way conversion catalyst having the capability of simultaneously catalyzing the oxidation of hydrocarbons and carbon monoxide and the reduction of nitrogen oxides is disclosed. Provided is a catalytic material of at least four layers in conjunction with a carrier, where each of the layers includes a support, at least three layers comprise a precious metal component, and at least one layer comprises an oxygen storage component (OSC). The catalytic material can further comprise a fifth layer, where at least four layers comprise a precious metal component, at least one layer comprises an oxygen storage component, and at least one layer is substantially free of an oxygen storage component.

Abstract translation: 公开了具有同时催化烃和一氧化碳氧化和氮氧化物还原能力的多层三元转化催化剂。 提供了与载体结合至少四层的催化材料，其中每个层包括载体，至少三层包含贵金属组分，并且至少一层包含储氧组分（OSC）。 催化材料还可包括第五层，其中至少四层包含贵金属组分，至少一层包含储氧组分，至少一层基本上不含储氧组分。

公开(公告)号：US20150174564A1

公开(公告)日：2015-06-25

申请号：US14384517

申请日：2012-04-05

Applicant: Torsten W. Müller-Stach ,  Alfred H. Punke ,  Gerd Grubert ,  Marcus Hilgendorff ,  Helke Doering ,  Torsten Neubauer ,  Xiaolai Zheng ,  Chung-Zong Wan ,  Wen-Mei Xue ,  Patrick Burk

Inventor： Torsten W. Müller-Stach ,  Alfred H. Punke ,  Gerd Grubert ,  Marcus Hilgendorff ,  Helke Doering ,  Torsten Neubauer ,  Xiaolai Zheng ,  Chung-Zong Wan ,  Wen-Mei Xue ,  Patrick Burk

IPC: B01J29/76 ,  B01J23/44 ,  B01D53/94 ,  B01J29/44 ,  B01J21/04

CPC classification number: B01J29/7676 ,  B01D53/944 ,  B01D53/9477 ,  B01D2255/1021 ,  B01D2255/1023 ,  B01D2255/2042 ,  B01D2255/2047 ,  B01D2255/2063 ,  B01D2255/50 ,  B01D2255/502 ,  B01D2255/504 ,  B01D2255/9022 ,  B01D2255/9025 ,  B01D2255/912 ,  B01D2258/012 ,  B01J21/04 ,  B01J23/44 ,  B01J29/0354 ,  B01J29/44 ,  B01J29/7615 ,  B01J37/0244 ,  B01J37/0246 ,  B01J2229/64 ,  F01N3/035 ,  F01N3/0814 ,  F01N3/0842 ,  F01N3/103 ,  F01N3/2066 ,  F01N13/009 ,  F01N2370/04 ,  F01N2510/0684 ,  Y02A50/2341 ,  Y02T10/24

Abstract: A diesel oxidation catalyst for the treatment of exhaust gas emissions, such as the oxidation of unburned hydrocarbons (HC), and carbon monoxide (CO) and the reduction of nitrogen oxides (NOx) is described. More particularly, the present invention is directed to a washcoat composition comprising high silica to alumina zeolite and platinum and palladium such that the zeolite minimizes negative interactions of these platinum group metals with the zeolite.

Abstract translation: 描述了用于处理废气排放的柴油氧化催化剂，例如未燃烧的烃（HC）和一氧化碳（CO）的氧化和氮氧化物（NOx）的还原。 更具体地说，本发明涉及包含高二氧化硅 - 氧化铝沸石和铂和钯的修补基面涂料组合物，使得沸石使这些铂族金属与沸石的负相互作用最小化。

公开(公告)号：US08758695B2

公开(公告)日：2014-06-24

申请号：US12826952

申请日：2010-06-30

Applicant: Torsten Neubauer ,  Marcus Hilgendorff ,  Stephan Siemund ,  Alfred H. Punke ,  Gerd Grubert

Inventor： Torsten Neubauer ,  Marcus Hilgendorff ,  Stephan Siemund ,  Alfred H. Punke ,  Gerd Grubert

IPC: B01D50/00

CPC classification number: B01D53/944 ,  B01D53/9454 ,  B01J23/63 ,  B01J29/123 ,  B01J29/126 ,  B01J29/44 ,  B01J29/7415 ,  B01J29/7469 ,  B01J29/85 ,  B01J37/0242 ,  B01J37/0244 ,  B01J37/0248 ,  F01N3/035 ,  F01N2510/06 ,  Y02T10/22

Abstract: The present invention relates to a treatment system for a gasoline engine exhaust gas stream comprising a particulate filter, said particulate filter comprising: a particulate filter substrate, an inlet layer disposed on the exhaust gas inlet surface of the filter substrate, and an outlet layer disposed on the exhaust gas outlet surface of the filter substrate, wherein the inlet layer comprises Rh and/or Pd, and the outlet layer comprises Rh and/or a zeolite.

Abstract translation: 本发明涉及一种用于汽油发动机废气流的处理系统，其包括颗粒过滤器，所述颗粒过滤器包括：颗粒过滤器基材，设置在过滤器基材的废气入口表面上的入口层和设置在出口层 在过滤器基板的排气出口表面上，其中入口层包括Rh和/或Pd，出口层包括Rh和/或沸石。

公开(公告)号：US20120288427A1

公开(公告)日：2012-11-15

申请号：US13469560

申请日：2012-05-11

Applicant: Gerd Grubert ,  Alfred Punke ,  Torsten Neubauer ,  Ruediger Wolff ,  Stanley Roth ,  Yuejin Li ,  Torsten Müller-Stach ,  Marcus Hilgendorff

Inventor： Gerd Grubert ,  Alfred Punke ,  Torsten Neubauer ,  Ruediger Wolff ,  Stanley Roth ,  Yuejin Li ,  Torsten Müller-Stach ,  Marcus Hilgendorff

IPC: B01D53/94 ,  F01N3/035 ,  B05D7/22

CPC classification number: F01N3/106 ,  B01D53/944 ,  B01D53/9477 ,  B01D2255/1021 ,  B01D2255/1023 ,  B01D2255/2063 ,  B01D2255/2065 ,  B01D2255/2066 ,  B01D2255/20715 ,  B01D2255/407 ,  B01D2255/9022 ,  B01D2255/9032 ,  B01D2255/9035 ,  B01D2255/9155 ,  F01N3/035 ,  F01N3/0842 ,  F01N3/2066 ,  F01N13/009 ,  F01N2510/0682 ,  F01N2510/0684

Abstract: Disclosed is a catalyzed soot filter with layered design wherein the first coating of the filter comprises an oxidation catalyst comprising platinum (Pt) and optionally palladium (Pd), wherein the second coating of the filter comprises an oxidation catalyst comprising Pd and optionally Pt, wherein the Pt concentration in the second coating is lower than the Pt concentration in the first coating, and wherein the weight ratio of Pt:Pd in the second coating is in the range of from 1:1 to 0:1; and wherein the first coating and the second coating are present on the wall flow substrate at a coating loading ratio in the range of from 0.25 to 3, calculated as ratio of the loading of the first coating (in g/inch3 (g/(2.54 cm)3)): loading of the second coating (in g/inch3 (g/(2.54 cm)3)).

Abstract translation: 公开了一种具有分层设计的催化烟灰过滤器，其中过滤器的第一涂层包括包含铂（Pt）和任选的钯（Pd）的氧化催化剂，其中过滤器的第二涂层包含包含Pd和任选的Pt的氧化催化剂，其中 第二涂层中的Pt浓度低于第一涂层中的Pt浓度，其中第二涂层中Pt：Pd的重量比在1:1至0:1的范围内; 并且其中所述第一涂层和所述第二涂层以基于所述第一涂层的负载比（以g / inch 3（g /（3 / g）（2.54）计）的0.25至3的涂层负载比率存在于所述壁流动基材上 cm）3））：第二涂层的负载（g / inch 3（g /（2.54cm）3）））。