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公开(公告)号：US20190134617A1
公开(公告)日：2019-05-09
申请号：US16124268
申请日：2018-09-07
Applicant: BASF CORPORATION
Inventor： Wenyong Lin , Jaya Mohanan , Xinsheng Liu , John Hochmuth
IPC: B01J29/76 , B01J37/02 , B01D53/94 , F01N3/20 , B01J29/70 , F01N3/28 , F01N3/10 , B01J35/04 , B01J37/08
Abstract: The present disclosure generally provides catalysts, catalyst articles and catalyst systems including such catalyst articles. In particular, the catalyst composition includes a metal ion-exchanged molecular sieve ion-exchanged with at least one additional metal, which reduces the number of metal centers often present in metal promoted zeolite catalysts. Methods of making and using the catalyst composition are also provided, as well as emission treatment systems including a catalyst article coated with the catalyst composition. The catalyst article present in such emission treatment systems is useful to catalyze the reduction of nitrogen oxides in gas exhaust in the presence of a reductant while minimizing the amount of dinitrogen oxide emission.
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公开(公告)号：US10252217B2
公开(公告)日：2019-04-09
申请号：US14722881
申请日：2015-05-27
Applicant: BASF Corporation
Inventor： Qinglin Zhang , Ye Liu , Pascaline Harrison Tran , Xinsheng Liu , Michelle Casper , Michael P. Galligan , John R. Adomaitis , Shau-Lin F. Chen , Weiliang Feng
IPC: B01D53/94 , B01J21/04 , B01J23/10 , B01J23/42 , B01J23/44 , B01J23/46 , B01J23/89 , B01J35/00 , B01J35/04 , B01J37/02 , B01J37/03 , B01J37/08 , B01J23/889
Abstract: Aspects of the invention pertain to catalytic articles and methods of making catalytic articles comprising a first catalytic coating comprising a platinum group metal, wherein the first catalytic coating is substantially free of Cu, Ni, Fe, Mn, V, Co, Ga, Mo, Mg, Cr and Zn; a second catalytic coating comprising a non-PGM metal, wherein the second catalytic coating is substantially free of any platinum group metal; and one or more substrates, wherein the first catalytic coating is separated from the second catalytic coating, optionally with a barrier layer.
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公开(公告)号：US20140255262A1
公开(公告)日：2014-09-11
申请号：US13786870
申请日：2013-03-06
Applicant: BASF CORPORATION
Inventor： Xinsheng Liu , Esra Cinar , Chunjuan Zhang , Pascaline Harrison Tran
IPC: B01J23/46
CPC classification number: B01D53/9459 , B01D53/9477 , B01D2255/102 , B01D2255/1023 , B01D2255/1025 , B01D2255/2092 , B01D2255/908 , B01D2255/915 , B01D2255/9202 , B01D2255/9205 , B01J23/44 , B01J23/464 , B01J23/83 , B01J35/04 , B01J35/1052 , B01J35/1076 , B01J37/0018 , B01J37/0219 , B01J37/0246 , B01J37/0248 , B01J37/08 , Y10T428/249979 , Y10T428/25
Abstract: Catalyst washcoats with improved porosity and methods for making the washcoats are provided. The process comprises incorporation of an oil-in-water macroemulsion into the catalyst slurry prior to washcoating the carrier substrate, and calcining the washcoated carrier substrate to remove the oil-in-water macroemulsion. Also provided are catalyst articles comprising the washcoat and methods for abatement of exhaust gas emissions.
Abstract translation: 提供具有改善的孔隙率的催化剂洗面漆和制备洗衣布的方法。 该方法包括在洗涤涂覆载体基底之前将油包水宏乳剂掺入催化剂浆液中，并煅烧涂有涂层的载体基底以除去水包油中的乳液。 还提供了包含修补基面涂层的催化剂制品和用于减少废气排放的方法。
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4.发明申请Base Metal Catalyst Composition and Methods of Treating Exhaust From a Motorcycle 有权基础金属催化剂组合物和从摩托车处理排气的方法公开(公告)号：US20130323145A1
公开(公告)日：2013-12-05
申请号：US13867184
申请日：2013-04-22
Applicant: BASF CORPORATION , HONDA MOTOR CO., LTD.
Inventor： Pascaline Harrison Tran , Xinsheng Liu , Ye Liu , Michael P. Galligan , Qinglin Zhang , Hiroyuki Horimura , Akiko Iwasa
IPC: B01D53/94
CPC classification number: B01D53/944 , B01D53/945 , B01D2255/2065 , B01J23/002 , B01J23/8892 , B01J35/023 , B01J35/04 , B01J37/0201 , B01J37/0215 , B01J37/038 , B01J2523/00 , Y02T10/22 , B01J2523/17 , B01J2523/3712 , B01J2523/72
Abstract: Aspects of the invention relate to a method of treating a gas stream generated by a motorcycle, the method comprising: contacting a gas stream containing hydrocarbons, carbon monoxide and nitrogen oxides and generated by a motorcycle under both rich and lean engine operating conditions with a base metal catalyst composition, thereby removing at least a part of the hydrocarbons, carbon monoxide and nitrogen oxides in gas stream. The base metal catalyst composition comprises a support including at least 10% by weight of reducible ceria, and about 3 to about 7 wt % MnO and about 8 to about 22 wt % CuO on the reducible ceria support. The base metal catalyst composition is effective to promote a steam reforming reaction of hydrocarbons and a water gas shift reaction to provide H2 as a reductant to abate NOx.
Abstract translation: 本发明的方面涉及一种处理由摩托车产生的气流的方法，所述方法包括：使含有碳氢化合物，一氧化碳和氮氧化物的气流与丰田和稀有发动机运行条件下的摩托车相接触， 金属催化剂组合物，从而除去气流中的至少一部分烃，一氧化碳和氮氧化物。 贱金属催化剂组合物包括在可还原的二氧化铈载体上包含至少10重量％的可还原二氧化铈和约3至约7重量％的MnO和约8至约22重量％的CuO的载体。 贱金属催化剂组合物有效促进烃的水蒸气重整反应和水煤气变换反应，以提供H2作为还原剂以减少NOx。
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公开(公告)号：US11110446B2
公开(公告)日：2021-09-07
申请号：US16918532
申请日：2020-07-01
Applicant: BASF Corporation
Inventor： Xinzhu Liu , Michael Galligan , Ye Liu , Young Gin Kim , Milena Kudziela , Xinsheng Liu , Pascaline Tran
Abstract: Catalytic articles comprising a substrate having a catalytic coating thereon, the catalytic coating comprising a catalytic layer having a thickness and an inner surface proximate to the substrate and an outer surface distal to the substrate; where the catalytic layer comprises a noble metal component on support particles and where the concentration of the noble metal component towards the outer surface is greater than the concentration towards the inner surface are highly effective towards treating exhaust gas streams of internal combustion engines. The articles are prepared via a method comprising providing a first mixture comprising micron-scaled support particles and applying the first mixture to a substrate to form a micro-particle layer; providing a second mixture comprising nano-scaled support particles and a noble metal component having an initial pH and applying the second mixture to the micro-particle layer and calcining the substrate.
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Patent Agency Ranking
公开(公告)号：US09868088B2
公开(公告)日：2018-01-16
申请号：US15388944
申请日：2016-12-22
Applicant: BASF Corporation
Inventor： Xinsheng Liu , Esra Cinar , Chunjuan Zhang , Pascaline Harrison Tran
IPC: B01D53/94 , B01J23/00 , B01J23/40 , B01J23/56 , B01J35/04 , B01J35/10 , B01J23/46 , B01J37/08 , B01J37/02 , B01J37/00 , B01J23/83 , B01J23/44
CPC classification number: B01D53/9459 , B01D53/9477 , B01D2255/102 , B01D2255/1023 , B01D2255/1025 , B01D2255/2092 , B01D2255/908 , B01D2255/915 , B01D2255/9202 , B01D2255/9205 , B01J23/44 , B01J23/464 , B01J23/83 , B01J35/04 , B01J35/1052 , B01J35/1076 , B01J37/0018 , B01J37/0219 , B01J37/0246 , B01J37/0248 , B01J37/08 , Y10T428/249979 , Y10T428/25
Abstract: Catalyst washcoats with improved porosity and methods for making the washcoats are provided. The process comprises incorporation of an oil-in-water macroemulsion into the catalyst slurry prior to washcoating the carrier substrate, and calcining the washcoated carrier substrate to remove the oil-in-water macroemulsion. Also provided are catalyst articles comprising the washcoat and methods for abatement of exhaust gas emissions.
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公开(公告)号：US11077432B2
公开(公告)日：2021-08-03
申请号：US16124268
申请日：2018-09-07
Applicant: BASF CORPORATION
Inventor： Wenyong Lin , Jaya Lakshmi , Xinsheng Liu , John Hochmuth
IPC: B01J29/06 , B01J29/76 , B01D53/94 , F01N3/20 , B01J29/50 , B01J29/52 , B01J29/72 , B01J29/54 , B01J29/56 , B01J29/58 , B01J29/70 , B01J29/78 , B01J29/74 , B01J37/02 , B01J35/00 , B01J35/04 , B01J37/08 , F01N3/10 , F01N3/28
Abstract: The present disclosure generally provides catalysts, catalyst articles and catalyst systems including such catalyst articles. In particular, the catalyst composition includes a metal ion-exchanged molecular sieve ion-exchanged with at least one additional metal, which reduces the number of metal centers often present in metal promoted zeolite catalysts. Methods of making and using the catalyst composition are also provided, as well as emission treatment systems including a catalyst article coated with the catalyst composition. The catalyst article present in such emission treatment systems is useful to catalyze the reduction of nitrogen oxides in gas exhaust in the presence of a reductant while minimizing the amount of dinitrogen oxide emission.
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公开(公告)号：US20200330971A1
公开(公告)日：2020-10-22
申请号：US16918532
申请日：2020-07-01
Applicant: BASF Corporation
Inventor： Xinzhu Liu , Michael Galligan , Ye Liu , Young Gin Kim , Milena Kudziela , Xinsheng Liu , Pascaline Tran
IPC: B01J33/00 , B01J29/068 , B01J35/00 , F01N3/28
Abstract: Catalytic articles comprising a substrate having a catalytic coating thereon, the catalytic coating comprising a catalytic layer having a thickness and an inner surface proximate to the substrate and an outer surface distal to the substrate; where the catalytic layer comprises a noble metal component on support particles and where the concentration of the noble metal component towards the outer surface is greater than the concentration towards the inner surface are highly effective towards treating exhaust gas streams of internal combustion engines. The articles are prepared via a method comprising providing a first mixture comprising micron-scaled support particles and applying the first mixture to a substrate to form a micro-particle layer; providing a second mixture comprising nano-scaled support particles and a noble metal component having an initial pH and applying the second mixture to the micro-particle layer and calcining the substrate.
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9.发明申请公开(公告)号：US20170304805A1
公开(公告)日：2017-10-26
申请号：US15511271
申请日：2015-10-07
Applicant: BASF CORPORATION
Inventor： Xiaoming Xu , Xinsheng Liu
CPC classification number: B01J23/464 , B01F17/0007 , B01J21/04 , B01J23/40 , B01J23/42 , B01J23/44 , B01J23/48 , B01J35/0006 , B01J35/0013 , B01J35/023 , B01J37/0072 , B01J37/0215 , B01J37/04 , B01J37/16
Abstract: The present invention relates to colloidal dispersions comprising a plurality of precious group nanoparticles, wherein about 90% or more of the precious group metal is in fully reduced form; a dispersion medium comprising a polar solvent; a water-soluble polymer suspension stabilizing agent; and a reducing agent, wherein the nanoparticle concentration is at least about 2 wt. % of the colloidal dispersion, wherein the nanoparticles have an average particle size of about 1 to about 6 nm and at least 95% of the nanoparticles have a particle size within this range; and further wherein the colloidal dispersion is substantially free of halides, alkali metals, alkaline earth metals and sulfur compounds. Methods of preparing, further processing, and using such colloidal dispersions are also provided herein.
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公开(公告)号：US09561495B2
公开(公告)日：2017-02-07
申请号：US13786870
申请日：2013-03-06
Applicant: BASF Corporation
Inventor： Xinsheng Liu , Esra Cinar , Chunjuan Zhang , Pascaline Harrison Tran
IPC: B01J29/00 , B01J29/06 , B01J21/00 , B01J21/04 , B01J23/00 , B01J23/02 , B01J23/08 , B01J23/10 , B01J23/40 , B01J23/42 , B01J23/44 , B01J23/56 , B01J23/46 , B01J37/08 , B01J37/02 , B01J35/04 , B01J35/10 , B01J37/00 , B01D53/94
CPC classification number: B01D53/9459 , B01D53/9477 , B01D2255/102 , B01D2255/1023 , B01D2255/1025 , B01D2255/2092 , B01D2255/908 , B01D2255/915 , B01D2255/9202 , B01D2255/9205 , B01J23/44 , B01J23/464 , B01J23/83 , B01J35/04 , B01J35/1052 , B01J35/1076 , B01J37/0018 , B01J37/0219 , B01J37/0246 , B01J37/0248 , B01J37/08 , Y10T428/249979 , Y10T428/25
Abstract: Catalyst washcoats with improved porosity and methods for making the washcoats are provided. The process comprises incorporation of an oil-in-water macroemulsion into the catalyst slurry prior to washcoating the carrier substrate, and calcining the washcoated carrier substrate to remove the oil-in-water macroemulsion. Also provided are catalyst articles comprising the washcoat and methods for abatement of exhaust gas emissions.
Abstract translation: 提供具有改善的孔隙率的催化剂洗面漆和制备洗衣布的方法。 该方法包括在洗涤涂覆载体基底之前将油包水宏乳剂掺入催化剂浆液中，并煅烧涂有涂层的载体基底以除去水包油中的乳液。 还提供了包含修补基面涂层的催化剂制品和用于减少废气排放的方法。
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