公开(公告)号：US20160023193A1

公开(公告)日：2016-01-28

申请号：US14872458

申请日：2015-10-01

Applicant: BASF Corporation

Inventor： Qinglin Zhang ,  Robert J. Farrauto ,  Christopher R. Castellano

IPC: B01J23/89 ,  B01J23/63 ,  C01B3/32 ,  B01J37/08 ,  B01J37/04 ,  B01J37/00 ,  B01J23/648 ,  B01J37/02

CPC classification number: B01J23/896 ,  B01J23/58 ,  B01J23/62 ,  B01J23/622 ,  B01J23/63 ,  B01J23/648 ,  B01J23/6482 ,  B01J23/894 ,  B01J23/8946 ,  B01J37/0036 ,  B01J37/0236 ,  B01J37/04 ,  B01J37/08 ,  C01B3/326 ,  C01B2203/0233 ,  C01B2203/066 ,  C01B2203/0805 ,  C01B2203/1041 ,  C01B2203/1064 ,  C01B2203/107 ,  C01B2203/1082 ,  C01B2203/1094 ,  C01B2203/1223 ,  Y02E60/36 ,  Y02P20/52

Abstract: Novel catalysts, substantially free of Cu and Zn, useful for the reformation of methanol and steam into H2 for use in hydrogen fuel cells and their use are described herein.

Abstract translation: 本文描述了可用于将甲醇和蒸汽重整成用于氢燃料电池的H 2中的基本上不含Cu和Zn的新型催化剂及其用途。

公开(公告)号：US10335777B2

公开(公告)日：2019-07-02

申请号：US15557786

申请日：2016-04-08

Applicant: BASF Corporation

Inventor： Xingtao Gao ,  Christopher R. Castellano ,  Brendan Patrick Dowd

IPC: B01J29/40 ,  C01B39/38 ,  C01B39/40 ,  B01J35/08 ,  B01J35/00 ,  B01J35/10 ,  B01J37/00 ,  B01J37/02 ,  B01J21/12 ,  B01J37/08 ,  C07C2/76 ,  B01J35/02

Abstract: Disclosed in certain embodiments are ZSM-5 zeolite microspheres. Disclosed in certain embodiments is a method of forming ZSM-5 zeolite microspheres including: 1) shaping a mixture into microspheres where the mixture includes a silica material and of particulates selected from at least one high-density material with an absolute bulk density of at least 0.3 g/cc, ZSM-5 zeolite crystals, and combinations thereof; 2) calcining the microspheres; and 3) reacting and subsequently heating the microspheres with at least one alkali solution to form ZSM-5 zeolite in-situ on the microspheres, where the ZSM-5 zeolite microspheres contain substantially no clay or calcined clay material.

公开(公告)号：US10213774B2

公开(公告)日：2019-02-26

申请号：US15557786

申请日：2016-04-08

Applicant: BASF Corporation

Inventor： Xingtao Gao ,  Christopher R. Castellano ,  Brendan Patrick Dowd

IPC: B01J29/40 ,  C01B39/38 ,  C01B39/40 ,  B01J35/08 ,  B01J35/00 ,  B01J35/10 ,  B01J37/00 ,  B01J37/02 ,  B01J21/12 ,  B01J37/08 ,  C07C2/76

Abstract: Disclosed in certain embodiments are ZSM-5 zeolite microspheres. Disclosed in certain embodiments is a method of forming ZSM-5 zeolite microspheres including: 1) shaping a mixture into microspheres where the mixture includes a silica material and of particulates selected from at least one high-density material with an absolute bulk density of at least 0.3 g/cc, ZSM-5 zeolite crystals, and combinations thereof; 2) calcining the microspheres; and 3) reacting and subsequently heating the microspheres with at least one alkali solution to form ZSM-5 zeolite in-situ on the microspheres, where the ZSM-5 zeolite microspheres contain substantially no clay or calcined clay material.

公开(公告)号：US10786807B2

公开(公告)日：2020-09-29

申请号：US16250720

申请日：2019-01-17

Applicant: BASF Corporation

Inventor： Xingtao Gao ,  Christopher R. Castellano ,  Brendan Patrick Dowd

IPC: C01B39/38 ,  C01B39/40 ,  B01J29/40 ,  B01J35/08 ,  B01J35/00 ,  B01J35/10 ,  B01J37/00 ,  B01J37/02 ,  B01J21/12 ,  B01J37/08 ,  C07C2/76 ,  B01J35/02

Abstract: Disclosed in certain embodiments are ZSM-5 zeolite microspheres. The ZSM-5 zeolite microspheres may contain substantially no clay or calcined clay material. The ZSM-5 zeolite microspheres may have a ZSM-5 zeolite content of at least 70 wt. %. Disclosed in certain embodiments is a method of forming ZSM-5 zeolite microspheres including treating microspheres with at least one alkali solution.

公开(公告)号：US20190151831A1

公开(公告)日：2019-05-23

申请号：US16250720

申请日：2019-01-17

Applicant: BASF Corporation

Inventor： Xingtao Gao ,  Christopher R. Castellano ,  Brendan Patrick Dowd

IPC: B01J29/40 ,  B01J37/02 ,  B01J35/00 ,  B01J35/08 ,  B01J35/10 ,  C07C2/76 ,  C01B39/40 ,  C01B39/38 ,  B01J37/08 ,  B01J21/12 ,  B01J37/00

Abstract: Disclosed in certain embodiments are ZSM-5 zeolite microspheres. Disclosed in certain embodiments is a method of forming ZSM-5 zeolite microspheres including: 1) shaping a mixture into microspheres where the mixture includes a silica material and of particulates selected from at least one high-density material with an absolute bulk density of at least 0.3 g/cc, ZSM-5 zeolite crystals, and combinations thereof; 2) calcining the microspheres; and 3) reacting and subsequently heating the microspheres with at least one alkali solution to form ZSM-5 zeolite in-situ on the microspheres, where the ZSM-5 zeolite microspheres contain substantially no clay or calcined clay material.

公开(公告)号：US20180071723A1

公开(公告)日：2018-03-15

申请号：US15557786

申请日：2016-04-08

Applicant: BASF Corporation

Inventor： Xingtao Gao ,  Christopher R. Castellano ,  Brendan Patrick Dowd

IPC: B01J29/40 ,  B01J21/12 ,  B01J35/00 ,  B01J35/08 ,  B01J37/00 ,  B01J37/08 ,  B01J37/02 ,  C07C2/76

CPC classification number: B01J29/40 ,  B01J21/12 ,  B01J35/0006 ,  B01J35/002 ,  B01J35/0026 ,  B01J35/023 ,  B01J35/08 ,  B01J35/1019 ,  B01J37/0018 ,  B01J37/0045 ,  B01J37/0072 ,  B01J37/0203 ,  B01J37/0221 ,  B01J37/08 ,  B01J2229/60 ,  B01J2229/62 ,  C01B39/38 ,  C01B39/40 ,  C01P2004/32 ,  C01P2006/21 ,  C07C2/76 ,  C07C2521/12 ,  C07C2529/40

Abstract: Disclosed in certain embodiments are ZSM-5 zeolite microspheres. Disclosed in certain embodiments is a method of forming ZSM-5 zeolite microspheres including: 1) shaping a mixture into microspheres where the mixture includes a silica material and of particulates selected from at least one high-density material with an absolute bulk density of at least 0.3 g/cc, ZSM-5 zeolite crystals, and combinations thereof; 2) calcining the microspheres; and 3) reacting and subsequently heating the microspheres with at least one alkali solution to form ZSM-5 zeolite in-situ on the microspheres, where the ZSM-5 zeolite microspheres contain substantially no clay or calcined clay material.