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    A MIDDLE-PRESSURE POLYMERIZATION PROCESS FOR LIQUID ETHYLENE COPOLYMERS
    1.
    发明申请
    A MIDDLE-PRESSURE POLYMERIZATION PROCESS FOR LIQUID ETHYLENE COPOLYMERS 有权

    公开(公告)号：US20220177799A1

    公开(公告)日：2022-06-09

    申请号：US17600797

    申请日：2020-03-23

    Applicant: BASF SE

    Inventor： Ivette GARCIA CASTRO ,  Wolfgang GRABARSE ,  Jan STRITTMATTER ,  Rene KOSCHABEK ,  Robert RUPANER

    IPC: C10M107/28 ,  C08F210/02 ,  C08F220/18

    Abstract: The present invention relates to a middle-pressure polymerization process for the preparation of a liquid ethylene copolymer which comprises in polymerized form 20 to 60 wt % of ethylene; and at least 20 wt % of an acrylate, which is selected from C1-C22 alkyl (meth)acrylate, where a monomer mix comprising the ethylene and the acrylate is polymerized at a pressure of 50 to 400 bar and in the presence of at least 2 wt % of a chain transfer agent. The invention further relates to a liquid ethylene copolymer obtainable by the polymerization process; and to a lubricant comprising the liquid ethylene copolymer obtainable by the polymerization process; and to a method for reducing friction between moving surfaces comprising the step of contacting the surfaces with the lubricant or with the ethylene copolymer.

    USE OF QUATERNIZED ALKYL AMINES AS ADDITIVE IN FUELS AND LUBRICANTS
    3.
    发明申请
    USE OF QUATERNIZED ALKYL AMINES AS ADDITIVE IN FUELS AND LUBRICANTS 审中-公开

    公开(公告)号：US20160251588A1

    公开(公告)日：2016-09-01

    申请号：US15055851

    申请日：2016-02-29

    Applicant: BASF SE

    Inventor： Markus HANSCH ,  Harald BOEHNKE ,  Ludwig VOELKEL ,  Wolfgang GRABARSE ,  Jan STRITTMATTER

    IPC: C10L10/06 ,  C10L10/18 ,  C10L1/222

    Abstract: The present invention relates to the use of quaternized alkylamine nitrogen compounds as a fuel additive and lubricant additive, such as, more particularly, as a detergent additive; for reduction or prevention of deposits in the injection systems of direct injection diesel engines, especially in common rail injection systems, for reduction of the fuel consumption of direct injection diesel engines, especially of diesel engines with common rail injection systems, and for minimization of power loss in direct injection diesel engines, especially in diesel engines with common rail injection systems; and as an additive for gasoline fuels, especially for operation of DISI engines.

    COPOLYMER WITH HIGH CHEMICAL HOMOGENEITY AND USE THEREOF FOR IMPROVING THE COLD FLOW PROPERTIES OF FUEL OILS
    4.
    发明申请
    COPOLYMER WITH HIGH CHEMICAL HOMOGENEITY AND USE THEREOF FOR IMPROVING THE COLD FLOW PROPERTIES OF FUEL OILS 审中-公开
    具有高化学均匀性的共聚物及其用于改善燃油的冷流特性

    公开(公告)号：US20160200844A1

    公开(公告)日：2016-07-14

    申请号：US15077196

    申请日：2016-03-22

    Applicant: BASF SE

    Inventor： Frank-Olaf MAEHLING ,  Jan STRITTMATTER ,  Irene TROETSCH-SCHALLER ,  Ivette GARCIA-CASTRO ,  Michael SCHROERS ,  Uwe REBHOLZ

    IPC: C08F210/02 ,  C08F220/18

    CPC classification number: C08F210/02 ,  C08F8/14 ,  C08F220/06 ,  C08F220/18 ,  C10L1/1963 ,  C10L1/1973 ,  C10L10/14 ,  C10L10/16

    Abstract: A copolymer with high chemical homogeneity, consisting of (A) 50 to 30% by weight of ethylene, (B) 50 to 70% by weight of C4- to C24-hydrocarbyl ester of (meth)acrylic acid, (C) 0 to 5% by weight of (meth)acrylic acid and (D) 0 to 10% by weight of copolymerizable monomers, obtainable by polymerizing a mixture of 80 to 60% by weight of ethylene, 20 to 40% by weight of (meth)acrylic acid and 0 to 10% by weight of copolymerizable monomers in a backmixing, continuous polymerization apparatus, and subsequently polymer-analogously esterifying the resulting copolymer with C4- to C24-hydrocarbinols. The inventive copolymer is suitable for improving the cold flow properties of fuel oils, for lowering the lower mixing temperature of cold flow improver additives into fuel oils, and for improving the filterability of fuel oils comprising cold flow improver additives.

    Abstract translation: 具有高化学均匀性的共聚物，由（A）50〜30重量％的乙烯，（B）50〜70重量％的（甲基）丙烯酸的C 4〜C 24烃基酯，（C）0〜 5重量％的（甲基）丙烯酸和（D）0至10重量％的可共聚单体，可通过将80至60重量％的乙烯，20至40重量％的（甲基）丙烯酸酯 酸和0至10重量％的可共聚单体，在后混合，连续聚合装置中，随后用C4-至C24-烃基聚合物类似地酯化所得共聚物。 本发明的共聚物适用于改善燃料油的冷流性能，用于将冷流改进剂添加剂降低到燃料油中的较低混合温度，以及用于改善包含冷流改进剂添加剂的燃料油的过滤性。

    USE OF SUBSTITUTED UREAS OR URETHANES FOR FURTHER IMPROVEMENT OF THE COLD FLOW PROPERTIES OF MINERAL OILS AND CRUDE OILS
    6.
    发明申请
    USE OF SUBSTITUTED UREAS OR URETHANES FOR FURTHER IMPROVEMENT OF THE COLD FLOW PROPERTIES OF MINERAL OILS AND CRUDE OILS 审中-公开
    替代矿产或替代品的使用，进一步改善矿物油和原油的冷流特性

    公开(公告)号：US20130232858A1

    公开(公告)日：2013-09-12

    申请号：US13781929

    申请日：2013-03-01

    Applicant: BASF SE

    Inventor： Jan STRITTMATTER ,  Karl HAEBERLE ,  Wolfgang GRABARSE ,  Ivette GARCIA CASTRO ,  Markus HANSCH ,  Irene TROETSCH-SCHALLER ,  Stephan SCHENK ,  Michael SCHROERS ,  Bernhard LANGE

    IPC: C10L1/222

    CPC classification number: C10L1/2227 ,  C10L1/224 ,  C10L10/14 ,  C10L2270/026

    Abstract: The use of substituted monoureas, diureas, polyureas, monourethanes, bisurethanes or polyurethanes of the formula R1X—CO—NR3R4 in which X is R2N or O and R1 to R4 are each independently hydrogen, alkyl radicals, alkenyl radicals, cycloalkyl radicals, aryl radicals or arylalkyl radicals, where at least one variable must comprise 4 carbon atoms and where the urea or urethane functionality may be replicated via bridging members, for further improvement of the cold flow properties of mineral oils and crude oils which already comprise further organic compounds suitable for dispersion or for promoting dispersion of paraffin crystals which precipitate under cold conditions, and organic compounds which improve the cold flow characteristics of mineral oils and crude oils.

    Abstract translation: 使用其中X为R2N或O和R1至R4的式R1X-CO-NR3R4的取代的单脲，脲，聚脲，单氨基甲酸酯，双氨酯或聚氨酯各自独立地为氢，烷基，烯基，环烷基，芳基 或芳基烷基，其中至少一个变量必须包含4个碳原子，并且其中尿素或氨基甲酸酯官能度可以通过桥连构件复制，以进一步改进矿物油和原油的冷流性质，其已经包含适合于 分散或促进在冷条件下沉淀的石蜡晶体的分散，以及改善矿物油和原油的冷流特性的有机化合物。

    LUBRICANTS WITH A TERPOLYMER MADE OF DIESTER, OLEFIN AND ACRYLATE
    8.
    发明申请
    LUBRICANTS WITH A TERPOLYMER MADE OF DIESTER, OLEFIN AND ACRYLATE 有权

    公开(公告)号：US20210348079A1

    公开(公告)日：2021-11-11

    申请号：US17286222

    申请日：2019-10-08

    Applicant: BASF SE

    Inventor： Ivette GARCIA CASTRO ,  Wolfgang GRABARSE ,  Jan STRITTMATTER ,  Markus SCHERER ,  Karolin MONZ ,  Rene KOSCHABEK

    IPC: C10M107/28 ,  C10M107/10 ,  C08F210/14 ,  C08F220/18 ,  C08F222/14

    Abstract: Lubricants with a terpolymer made of diester, olefin and acrylate The invention relates to a lubricant comprising a terpolymer which comprises in polymerized forma diester selected from di(C4-C22 alkyl)ester of maleic acid, fumaric acid, 2-methylmaleic acid, 2,3-dimethylmaleic acid, 2-methylfumaric acid, 2,3-dimethylfumaric acid, or mixtures thereof, an olefin selected from C6-C40 alky-1-ene, and an acrylate selected from C4-C40 alkyl (meth)acrylate. The invention further relates to the terpolymer, a process for preparing the terpolymer comprising the step of polymerizing the diester, the olefin, and the acrylate; and to a method for reducing friction between moving surfaces comprising the step of contacting the surfaces with the lubricant or with the terpolymer.

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