公开(公告)号：US12180314B2

公开(公告)日：2024-12-31

申请号：US17419270

申请日：2019-12-27

Applicant: DOW GLOBAL TECHNOLOGIES LLC

Inventor： Jeffrey C. Munro ,  Colin Li Pi Shan ,  Johnathan E. DeLorbe ,  Juan C. Tuberquia ,  Lixin Sun ,  Endre Szuromi ,  Edmund M. Carnahan

IPC: C08F210/16 ,  C08F2/38 ,  C08F210/06 ,  C08K3/22 ,  C08K5/00 ,  C08K5/09 ,  C08K5/14

Abstract: The present disclosure relates to unsaturated polyolefins and processes for preparing the same. The present disclosure further relates to curable formulations comprising the unsaturated polyolefins that show improved crosslinking.

公开(公告)号：US20240173945A1

公开(公告)日：2024-05-30

申请号：US18283945

申请日：2021-04-09

Applicant: Dow Global Technologies LLC

Inventor： Yunfeng Yang ,  Xuejun Liu ,  Lisa S. Madenjian ,  Stacy L. Pesek ,  Jinliang Yan ,  Jeffrey C. Munro

IPC: B32B27/06 ,  B32B5/02 ,  B32B5/18 ,  B32B5/24 ,  B32B27/32

CPC classification number: B32B27/065 ,  B32B5/02 ,  B32B5/18 ,  B32B5/245 ,  B32B27/32 ,  B32B2262/0253 ,  B32B2262/0276 ,  B32B2266/025 ,  B32B2270/00 ,  B32B2307/30 ,  B32B2307/536 ,  B32B2307/546 ,  B32B2307/72

Abstract: The present disclosure provides an article. In an embodiment, the article includes (A) a top layer composed of a composition composed of (i) from 51 wt % to 90 wt % of a propylene-based polymer, and (ii) from 10 wt % to 49 wt % of an ethylene/octene multi-block copolymer having hard segments and soft segments. The ethylene/octene multi-block copolymer has a soft segment melt temperature (SS-Tm) less than 2° C. The article also includes (B) a bottom layer composed of a textile.

公开(公告)号：US20230074326A1

公开(公告)日：2023-03-09

申请号：US17788903

申请日：2020-12-23

Applicant: Dow Global Technologies LLC

Inventor： Stacy L. Pesek ,  Jeffrey C. Munro ,  Zhe Zhou

IPC: C08F297/08

Abstract: The present disclosure provides a process. In an embodiment, the process includes contacting ethylene and butene under polymerization conditions at a temperature greater than 125C with a catalyst system. The catalyst system includes (i) a first polymerization catalyst having the structure of Formula (III), (ii) a second polymerization catalyst having the structure of Formula (I), and (iii) a chain shuttling agent. The process includes forming an ethylene/butene multi-block copolymer having LCB/1000C greater than or equal to 0.06. The present disclosure provides the resultant composition produced by the process. In an embodiment, the composition includes an ethylene/butene multi-block copolymer having LCB/1000C greater than or equal to 0.06.

公开(公告)号：US20220411658A1

公开(公告)日：2022-12-29

申请号：US17756668

申请日：2020-12-11

Applicant: Dow Global Technologies LLC

Inventor： Paul J. Brigandi ,  Jeffrey M. Cogen ,  Jeffrey C. Munro ,  Colin Li Pi Shan

IPC: C09D123/08 ,  C09D123/06 ,  H01B3/44

Abstract: A crosslinkable polyolefin composition comprising an ethylene/alpha-olefin copolymer elastomer having a melt index from 0.6 to 6.2 grams per 10 minutes, a crosslinking effective amount of an alkenyl-functional monocyclic organosiloxane, and from 0.29 to 0.44 wt % of an organic peroxide; products made therefrom; methods of making and using same; and articles containing same.

公开(公告)号：US11236241B2

公开(公告)日：2022-02-01

申请号：US16643378

申请日：2018-09-07

Applicant: Dow Global Technologies LLC

Inventor： Jeffrey C. Munro ,  Jihean Lee ,  Morgan M. Hughes

IPC: C08L23/12 ,  C09D7/65 ,  C09D5/03

Abstract: A composition comprising the following: A) coated polymer particles, and wherein the polymer particles are formed from a first composition comprising an ethylene-based polymer that comprises the following properties: a density from 0.854 to 0.860 g/cc, and a melt index (I2) from 4.0 to 15.0 g/10 min; and wherein the polymer particles comprise a coating on at least a portion of the total surface of the polymer particles, and wherein the coating is formed from a powder composition comprising at least one inorganic powder, and at least one organic powder selected from a metal stearate and/or a polymer powder, and wherein the weight ratio of the total amount of the inorganic powder to the total amount of the organic powder is from 3.0 to 50.0; B) optionally, a propylene-based polymer.

公开(公告)号：US11155658B2

公开(公告)日：2021-10-26

申请号：US16318568

申请日：2017-07-25

Applicant: Dow Global Technologies LLC

Inventor： Edmund M. Carnahan ,  Philip P. Fontaine ,  Carl N. Iverson ,  Jeffrey C. Munro ,  David M. Pearson ,  Kim Walton

IPC: C08F210/16 ,  C08L23/08 ,  C08L23/16 ,  C08F4/64 ,  C08F4/659 ,  C08F4/6592 ,  C08L23/12 ,  C08F210/14 ,  C08F2/01

Abstract: Embodiments of the present disclosure are directed to multimodal elastomers produced by olefin polymerization with a mixed catalyst system, specifically, a constrained geometry catalyst and a biphenyl phenol catalyst. The multimodal elastomers may be incorporated as impact modifiers in thermoplastic olefins.

公开(公告)号：US20210277166A1

公开(公告)日：2021-09-09

申请号：US16321567

申请日：2017-07-19

Applicant: Beverly Walton ,  Dow Global Technologies LLC

Inventor： Endre Szuromi ,  Justin M. Virgill ,  Robert F. Wendel ,  Jeffrey C. Munro ,  Gary R. Marchand ,  Edmund M. Carnahan

IPC: C08F297/08

Abstract: Semi-crystalline, thermoplastic polyolefin block copolymers comprising: (A) A first polyolefin A block comprising isotactic poly(1-butene) (iPB); (B) A polyolefin B block comprising an ethylene and/or alpha-olefin/1-butene copolymer or terpolymer; and (C) A second polyolefin A block comprising isotactic poly(1-butene) (iPB); the A and B blocks bonded to one another to form a block copolymer in which the first and second polyolefin A blocks are joined to and separated by the polyolefin B block. In one embodiment the polyolefin block copolymer is a BAB block copolymer.

公开(公告)号：US20200339789A1

公开(公告)日：2020-10-29

申请号：US16764890

申请日：2018-11-29

Applicant: Dow Global Technologies LLC ,  Rohm and Haas Company

Inventor： Liang Chen ,  Robert S. Moglia ,  Carlos A. Cruz ,  Ralph C. Even ,  Jeffrey C. Munro ,  Jeffrey M. Cogen

IPC: C08L23/08 ,  C08L23/06 ,  C08F255/08 ,  C08K5/14

Abstract: Provided is a method of making a polymeric composition comprising (a) providing a dispersion of initial polyolefin particles in an aqueous medium, wherein the initial polyolefin particles comprise (i) one or more hydrocarbon polyolefin, (ii) one or more non-hydrocarbon polyolefin, and (iii) one or more crosslinking agent; (b) contacting the initial polyolefin particles with a peroxide initiator to form crosslinked polyolefin particles.

公开(公告)号：US10167360B2

公开(公告)日：2019-01-01

申请号：US15111178

申请日：2014-12-15

Applicant: Dow Global Technologies LLC ,  Regents of the University of Minnesota

Inventor： Henry Martinez ,  Marc A. Hillmyer ,  Jeffrey C. Munro ,  Kim L. Walton ,  Morgan M. Hughes

IPC: C08G61/08

Abstract: A process to produce an ionomer comprising reacting alkyl-cis-cyclooctene and cis-cyclooctene in a mole ratio from 1:0 to 0:1, in the presence of a difunctional chain transfer agent under ring opening metathesis polymerization conditions to form an unsaturated polyolefin reactive telechelic pre-polymer; hydrogenating the unsaturated polyolefin reactive telechelic pre-polymer to produce a hydrogenated polyolefin reactive telechelic pre-polymer; reacting the hydrogenated polyolefin reactive telechelic pre-polymer with at least one compound according to the formula aMx+b(R)y, wherein M is a metal, x is a charge of M, R is an alkyl, aryl, oxide, or fatty acid, y is a charge of R, a and b are integers of at least 1, and ax+by=0, to form an ionomer is provided. Further provided are ionomers produced thereby.

公开(公告)号：US20170121478A1

公开(公告)日：2017-05-04

申请号：US15319577

申请日：2014-06-23

Applicant: Dow Global Technologies LLC

Inventor： Tao T. Han ,  Jeffrey C. Munro ,  Lisa S. Madenjian ,  Hong Yang

IPC: C08J7/04 ,  B05D7/00 ,  B05D1/02 ,  B05D3/02 ,  C09D109/06 ,  C09D133/00

CPC classification number: C08J7/042 ,  B05D1/02 ,  B05D3/0272 ,  B05D7/544 ,  C08J2323/12 ,  C08J2353/00 ,  C08J2409/06 ,  C08J2423/12 ,  C08J2433/00 ,  C08J2453/00 ,  C08L23/12 ,  C08L53/00 ,  C09D109/06 ,  C09D133/00 ,  C08L23/16 ,  C08L23/08

Abstract: A painted article includes a primer layer between a substrate and a paint layer, of which the substrate is the product of a substrate forming composition including an olefin block copolymer and a polypropylene polymer having a density from 0.89 g/cm3 and 0.92 g/cm3. The substrate is free of (1) phthalate-based plasticizer, (2) halogen-containing polymer, and (3) leachable, small polymeric units derived from styrene monomer.