Fuel for jet, gas turbine, rocket and diesel engines
    1.
    发明授权
    Fuel for jet, gas turbine, rocket and diesel engines 失效
    用于喷气,燃气轮机,火箭和柴油发动机的燃料

    公开(公告)号:US07683224B2

    公开(公告)日:2010-03-23

    申请号:US10902729

    申请日:2004-07-29

    CPC classification number: C10L1/08 C10L1/04

    Abstract: A fuel or fuel blendstock for jet, gas turbine, rocket, and diesel engines, particularly jet, rocket, and diesel engines that utilizes components of conventional petroleum not currently utilized for jet, gas turbine, rocket, and diesel fuels, such as benzene, linear, and lightly branched alkanes, that may be alkylated with aromatic moieties to make monoaromatics for use in jet and diesel fuels. Additionally, a fuel having such monoaromatics having multiple desired properties such as higher flash point, low pour point, increased density, better lubricity, aerobic degradability, reduction in toxicity, and additionally can deliver benefits in blendstocks.

    Abstract translation: 用于喷气式,燃气轮机,火箭和柴油发动机的燃料或燃料混合物,特别是使用目前未用于喷气式,燃气轮机,火箭和柴油燃料例如苯的常规石油的喷射,火箭和柴油发动机, 线性和轻支化的烷烃,其可以用芳族部分烷基化以制备用于喷气和柴油燃料的单芳烃。 此外,具有这样的具有多个所需性质如闪点较高,低倾点,增加的密度,更好的润滑性,好氧降解性,降低毒性的单一芳族化合物的燃料,并且还可以在共混物料中提供益处。

    Processes for making surfactants via adsorptive separation and products thereof
    2.
    发明授权
    Processes for making surfactants via adsorptive separation and products thereof 有权
    通过吸附分离制备表面活性剂的方法及其制品

    公开(公告)号:US07202205B1

    公开(公告)日:2007-04-10

    申请号:US09786078

    申请日:1999-09-01

    CPC classification number: C11D1/22 C11D1/146 C11D1/29

    Abstract: Processes for making particularly branched, especially monomethyl-branched or nongeminal dimethyl-branched surfactants used in cleaning products; preferred processes comprising particular combinations of two or more adsorptive separation steps and, more preferably, particular OXO and/or alkylation steps; products of such processes, including certain modified primary OXO alcohols and/or alkylbenzenes, modified primary OXO alcohol-derived alkoxylated alcohols, alkylsulfates and/or alkoxysulfates; alkylbenzensulfonate surfactants, and consumer cleaning products, especially laundry detergents, containing them. Preferred processes herein more specifically use specific, unconventional sequences of sorptive separation steps to secure certain branched hydrocarbon fractions which are used in further process steps to make olefins useful in OXO processes or as alkylating agents for arenes or for other useful surfactant-making purposes. Surprisingly, such fractions can even be derived from effluents from current linear alkylbenzene manufacture.

    Abstract translation: 用于制造特别是支链的,特别是用于清洁产品中的单甲基支链或非农业二甲基支链表面活性剂的方法; 优选的方法包括两个或更多个吸附分离步骤的特定组合,更优选地,特定的OXO和/或烷基化步骤; 这些方法的产物,包括某些改性的初级OXO醇和/或烷基苯,改性的初级OXO醇衍生的烷氧基化醇,烷基硫酸盐和/或烷氧基硫酸盐; 烷基苯磺酸盐表面活性剂和消费者清洁产品,特别是含有它们的衣物洗涤剂。 本文优选的方法更具体地使用吸附分离步骤的特定的非常规序列来确定某些支链烃馏分,其用于进一步的方法步骤以制备在OXO方法中有用的烯烃或作为芳烃的烷基化剂或用于其它有用的表面活性剂制备目的。 令人惊讶的是,这些馏分甚至可以从目前的直链烷基苯生产的流出物得到。

    Oligomeric hydrophobic dispersants and laundry detergent compositions comprising oligomeric dispersants
    4.
    发明授权
    Oligomeric hydrophobic dispersants and laundry detergent compositions comprising oligomeric dispersants 失效
    低聚疏水性分散剂和包含低聚分散剂的衣物洗涤剂组合物

    公开(公告)号:US06861400B2

    公开(公告)日:2005-03-01

    申请号:US10208940

    申请日:2002-07-31

    Abstract: The present invention relates to novel hydrophobic soil dispersants having the formula: wherein A units are arylene units, one of which is phenyl, anthryl, or phenanthryl; each R is independently hydrogen, linear or branched C1-C4 alkyl, —O(R3O)mR4, and mixtures thereof; R3 is C2-C4 linear or branched alkylene, R4 is hydrogen, C1-C4 alkyl, phenyl, phenyl sulphonate, —CH2CH(SO3M)CH2OH, —CH2CH(OH)CH2SO3M, —(CH2)eSO3M, —(CH2)fCO2M, —(CH2)eCH(SO3M)-CH2SO3M, —(CH2)eCH(SO2M)-CH2SO3M, —(CH2)fPO3M, —PO3M, or mixtures thereof; M is hydrogen or a water-soluble cation, the index f is an integer from 1 to 6, the index e is an integer from 0 to 6, m is an integer from 0 to 25; R1 is a sulphonate group; R2 is an amino group; [CAP] is a chain capping unit selected from i) hydrogen; ii) an aryl unit having the formula: iii) an aryl unit having the formula: iv) an aryl unit having the formula: v) an aryl unit having the formula: vi) and mixtures thereof; R5 is hydrogen, —CH2OH, —CH2OSO3M, —CH3, and mixtures thereof; the index n has an average value of from 8 to 25; the index p is 0 or 1; the index q is 0 or 1; the index t is 0 or 1

    Abstract translation: 本发明涉及具有下式的新型疏水性土壤分散剂:其中A单元是亚芳基单元,其中一个是苯基,蒽基或菲基; 每个R独立地为氢,直链或支链C 1 -C 4烷基,-O(R 3 O)m R 4及其混合物; R 3是C 2 -C 4直链或支链亚烷基,R 4是氢,C 1 -C 4烷基,苯基,苯基磺酸酯,-CH 2 CH(SO 3 M)CH 2 OH,-CH 2 CH(OH)CH 2 SO 3 M, - (CH 2)e SO 3 M, - (CH2)fCO2M, - (CH2)eCH(SO3M)-CH2SO3M, - (CH2)eCH(SO2M)-CH2SO3M, - (CH2)fPO3M,-PO3M或其混合物; M为氢或水溶性阳离子,指数f为1〜6的整数,指数e为0〜6的整数,m为0〜25的整数。 R 1是磺酸酯基; R 2是氨基; [CAP]是从i)氢中选择的链封接单元; ii)具有下式的芳基单元:iii)具有下式的芳基单元:iv)具有下式的芳基单元:v)具有下式的vi的芳基单元:vi )及其混合物; R 5为氢,-CH 2 OH,-CH 2 OSO 3 M,-CH 3及其混合物; 索引n的平均值为8到25; 指数p为0或1; 指数q是0或1; 指数t为0或1

    Cleaning products comprising improved alkylarylsulfonate surfactants prepared via vinylidene olefins and processes for preparation thereof
    5.
    发明授权
    Cleaning products comprising improved alkylarylsulfonate surfactants prepared via vinylidene olefins and processes for preparation thereof 失效
    清洁产品,包括通过亚乙烯基烯烃制备的改进的烷基芳基磺酸盐表面活性剂及其制备方法

    公开(公告)号:US06566319B1

    公开(公告)日:2003-05-20

    申请号:US09478906

    申请日:2000-01-07

    CPC classification number: C07C303/08 C07C303/06 C11D1/22 C11D11/04 C07C309/31

    Abstract: Cleaning compositions, especially laundry detergents and the like, comprising (i) modified alkylarylsulfonate surfactants, e.g., modified alkylbenzenesulfonates, which are the product of particular processes and (ii) cleaning adjuncts such as enzymes and bleaches. Processes for making the cleaning products, including processes comprising vinylidene olefin production, alkylation of arenes, sulfonation and domestic cleaning product formulation. VO production is used to introduce particular limited branching into an alpha-olefinic feedstock which, converted to dimer form, has from about 10 to about 16, preferably from about 12 to about 14 carbon atoms. Preferred processes maximize the amount of vinylidene olefin useful for detergent manufacture, and minimize deep internal olefin production. Further, an alkylation step, preferably having an internal isomer selectivity of from 0 to no more than about 40 is used, in which the VO monoalkylates arenes such as benzene, in presence of an alkylation catalyst preferably comprising an at least partially crystalline, porous zeolite-containing solid, the zeolite being at least partially acidic and having intermediate pore size. Preferred alkylation catalysts include at least partially dealuminized acidic mordenites.

    Abstract translation: 清洁组合物,特别是衣物洗涤剂等,其包含(i)改性的烷基芳基磺酸盐表面活性剂,例如改性烷基苯磺酸盐,其是特定方法的产物和(ii)清洁助剂如酶和漂白剂。 用于制造清洁产品的方法,包括包含亚乙烯基烯烃生产,芳烃烷基化,磺化和家用清洁产品配方的方法。 VO生产用于将特定有限的支化物引入α-烯烃原料中,其转化为二聚体形式具有约10至约16个,优选约12至约14个碳原子。 优选的方法使用于洗涤剂制造的亚乙烯基烯烃的量最大化,并使内部烯烃的生产最小化。 此外,使用优选具有0至不大于约40的内部异构体选择性的烷基化步骤,其中在烷基化催化剂存在下,优选包含至少部分结晶的多孔沸石的VO单烷基化物芳烃如苯 所述沸石至少部分为酸性且具有中等孔径。 优选的烷基化催化剂包括至少部分脱铝的酸性丝光沸石。

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