公开(公告)号：US20200165537A1

公开(公告)日：2020-05-28

申请号：US16680651

申请日：2019-11-12

Applicant: ExxonMobil Research and Engineering Company

Inventor： Douglas E. Deckman ,  Andrew D. Satterfield ,  Willie A. Givens, Jr.

IPC: C10M169/04 ,  C10M109/00 ,  C10M129/40 ,  C10M129/42 ,  C10M141/00

Abstract: Provided is a lubricating oil composition and method of using such a composition that provides for improved high temperature deposit resistance. The composition includes a lubricating oil base stock at from 20 to 95 wt % of the composition, at least one ashless organic friction modifier at from 0.1 to 20 wt % of the composition, and at least one overbased detergent at from 0.1 to 20 wt % of the composition. The remainder of composition includes one or more other lubricating oil additives. The deposit resistance of the lubricating oil composition as measured by TEOST 33C total deposits is at least 20% lower than the deposit resistance for a comparable lubricating oil composition not including the combination of the at least one ashless organic friction modifier and the at least one overbased detergent.

公开(公告)号：US10604720B2

公开(公告)日：2020-03-31

申请号：US16512005

申请日：2019-07-15

Applicant: ExxonMobil Research and Engineering Company

Inventor： Zhisheng Gao ,  Luca Salvi ,  Eugine Choi ,  Matthew W. Boland ,  Andrew E. Taggi ,  Andrew D. Satterfield

IPC: C10M169/04 ,  C10M105/38 ,  C10M133/12 ,  C10M149/22 ,  C10M145/36 ,  C10M137/08 ,  C10M137/10 ,  C10M141/10 ,  C10M157/04 ,  C10M105/36

Abstract: A method for preventing or reducing engine knock or pre-ignition in a high compression spark ignition engine lubricated with a lubricating oil by introducing to a combustion chamber of the engine from 0.1 to 5% by volume of the gasoline used a lubricating oil as a formulated oil, said formulated oil having a composition comprising (i) a major amount of a lubricating oil base stock comprising at least 80% by weight of one branched ester having at least 15% of the total carbons in the form of methyl groups, and (ii) a minor amount of at least one ashless amine phosphate antiwear additive. Also provided is a lubricating engine oil for high compression spark ignition engines including (i) a major amount of a lubricating oil base stock comprising at least 80% by weight formula I below: esterified (per —OH basis) with 25 to 100% isobutyric acid and 0 to 75% 3,5,5-trimethylhexanoic acid, wherein R is a H, methyl, ethyl, isopropyl, or isobutyl, and (ii) a minor amount of at least one amine phosphate ashless antiwear additive.

公开(公告)号：US20200181525A1

公开(公告)日：2020-06-11

申请号：US16708793

申请日：2019-12-10

Applicant: ExxonMobil Research and Engineering Company

Inventor： Douglas E. Deckman ,  Andrew E. Taggi ,  Mark P. Hagemeister ,  Andrew D. Satterfield

IPC: C10M169/02 ,  C10M101/00 ,  C10M105/04 ,  C10M105/32 ,  C10M107/10 ,  C10M119/12

Abstract: Provided is a method for improving oxidation resistance and deposit resistance of a lubricating oil for use in lubricating a mechanical component. The method includes the step of providing the lubricating oil to the mechanical component and measuring the improved oxidation and deposit resistance. The lubricating oil includes a lubricating oil base stock at from 0 to 80 wt %, at least one branched isoparaffin having a mole % of epsilon carbon as measured by C13 NMR of less than or equal to 10% at from 20 to 80 wt %, at least one viscosity modifier at from 5 to 20 wt %, and one or more other lubricating oil additives. The oxidation resistance in the CEC L-109 oxidation resistance test is improved to greater than 310 hours to achieve a 100% viscosity increase and the deposit resistance in the TEOST 33C is improve to total deposits of less than 45 mg as compared to oxidation resistance and deposit resistance achieved using a lubricating oil not containing the at least one branched isoparaffin.

公开(公告)号：US20200024537A1

公开(公告)日：2020-01-23

申请号：US16275958

申请日：2019-02-14

Applicant: ExxonMobil Research and Engineering Company

Inventor： Abhimanyu O. Patil ,  Kyle G. Lewis ,  Satish Bodige ,  Andrew E. Taggi ,  Andrew D. Satterfield

IPC: C10M105/34 ,  C10M105/56 ,  C10M107/02

Abstract: A composition including one or more benzoate monoester compounds represented by the formulae (I), (II), (III), (IV) and (V) as defined herein. The composition has a viscosity (KV100) from about 1 cSt to about 10 cSt at 100° C. as determined by ASTM D445, a viscosity index (VI) from about −100 to about 300 as determined by ASTM D2270, and a Noack volatility of no greater than 50 percent as determined by ASTM D5800. A process for producing the composition, a lubricating oil base stock and lubricating oil containing the composition, and a method for improving one or more of thermal and oxidative stability, solubility and dispersancy of polar additives, deposit control and traction control in a lubricating oil by using as the lubricating oil a formulated oil containing the composition.

公开(公告)号：US20190338213A1

公开(公告)日：2019-11-07

申请号：US16512005

申请日：2019-07-15

Applicant: ExxonMobil Research and Engineering Company

Inventor： Zhisheng Gao ,  Luca Salvi ,  Eugine Choi ,  Matthew W. Boland ,  Andrew E. Taggi ,  Andrew D. Satterfield

IPC: C10M169/04 ,  C10M105/36 ,  C10M105/38 ,  C10M133/12 ,  C10M149/22 ,  C10M145/36 ,  C10M137/08 ,  C10M137/10 ,  C10M141/10 ,  C10M157/04

Abstract: A method for preventing or reducing engine knock or pre-ignition in a high compression spark ignition engine lubricated with a lubricating oil by introducing to a combustion chamber of the engine from 0.1 to 5% by volume of the gasoline used a lubricating oil as a formulated oil, said formulated oil having a composition comprising (i) a major amount of a lubricating oil base stock comprising at least 80% by weight of one branched ester having at least 15% of the total carbons in the form of methyl groups, and (ii) a minor amount of at least one ashless amine phosphate antiwear additive. Also provided is a lubricating engine oil for high compression spark ignition engines including (i) a major amount of a lubricating oil base stock comprising at least 80% by weight formula I below: esterified (per —OH basis) with 25 to 100% isobutyric acid and 0 to 75% 3,5,5-trimethylhexanoic acid, wherein R is a H, methyl, ethyl, isopropyl, or isobutyl, and (ii) a minor amount of at least one amine phosphate ashless antiwear additive.

公开(公告)号：US10443008B2

公开(公告)日：2019-10-15

申请号：US16013230

申请日：2018-06-20

Applicant: ExxonMobil Research and Engineering Company

Inventor： Nabila Brabez ,  Kevin L. Crouthamel ,  John T. Fogarty ,  Andrew D. Satterfield

IPC: C10M107/02 ,  C10M169/04 ,  C10M129/50

Abstract: Provided are marine lubricating oils including from 15 to 95 wt % of a Group III base stock having a kinematic viscosity at 100 deg. C. of 4 to 12 cSt, 0.5 to 55 wt % of cobase stock having a kinematic viscosity at 100 deg. C. of 29 to 1000 cSt, 0.1 to 2.0 wt % of a molydithiocarbamate friction modifier, 0.1 to 2.0 wt % of a zinc dithiocarbamate anti-wear additive, and 2 to 30 wt % of other lubricating oil additives. The cobase stock is selected from the group consisting of a Group I, a Group IV, a Group V and combinations thereof. Also provided are methods of making and using the marine lubricating oils.