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公开(公告)号：US20220314207A9
公开(公告)日：2022-10-06
申请号：US17217782
申请日：2021-03-30
Inventor： Yuriy Román-Leshkov , Randall J. Meyer , Pedro M. Serna Merino , Mark Sullivan , Kimberly Dinh
Abstract: Catalytic compositions and sequential catalytic methods are generally described. in some embodiments, a composition comprises a first catalyst comprising a Cu-modified zeolite, and a second catalyst capable of a coupling reaction between (a) an intermediate resulting from a reaction of a reactant at the first catalyst, and (b) a co-reagent, wherein a rate of diffusion of the co-reagent within one or more cages and/or pores of the first catalyst is lower than a rate of diffusion of the intermediate within the one or more cages and/or pores of the first catalyst.
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公开(公告)号：US10576464B2
公开(公告)日：2020-03-03
申请号：US16021155
申请日：2018-06-28
Applicant: ExxonMobil Research and Engineering Company
Inventor： Allen W. Burton , Eugene Terefenko , Randall J. Meyer , Hilda B. Vroman
Abstract: The disclosure is related to various modified EMM-23 materials, processes, and uses of the same.
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公开(公告)号：US10307747B2
公开(公告)日：2019-06-04
申请号：US15969182
申请日：2018-05-02
Applicant: ExxonMobil Research and Engineering Company
Inventor： Joseph M. Falkowski , Mary S. Abdulkarim , Mobae Afeworki , Randall J. Meyer , Simon C. Weston
Abstract: A novel metal organic framework, EMM-42, is described having the structure of UiO-66 and comprising bisphosphonate linking ligands. EMM-42 has acid activity and is useful as a catalyst in olefin isomerization. Also disclosed is a process of making metal organic frameworks, such as EMM-42, by heterogeneous ligand exchange, in which linking ligands having a first bonding functionality in a host metal organic framework are exchanged with linking ligands having a second different bonding functionality in the framework.
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公开(公告)号：US20220220045A1
公开(公告)日：2022-07-14
申请号：US17643867
申请日：2021-12-13
Applicant: ExxonMobil Research and Engineering Company
Inventor： Mohsen N. Harandi , Randall J. Meyer
Abstract: A method may include: contacting a light paraffin feed comprising ethane, propane, butane, naphtha or combinations thereof with a restrained catalyst in a reactor; converting at least a portion of the light paraffin feed to ethylene, propylene, or combinations thereof with an olefin selectivity of at least 70 wt. % and methane selectivity of less than 15 wt. %; and withdrawing a product stream from the reactor.
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Patent Agency Ranking
公开(公告)号：US20190030518A1
公开(公告)日：2019-01-31
申请号：US16021155
申请日：2018-06-28
Applicant: ExxonMobil Research and Engineering Company
Inventor： Allen W. Burton , Eugene Terefenko , Randall J. Meyer , Hilda B. Vroman
IPC: B01J29/076
CPC classification number: B01J29/076 , C01B39/026 , C01B39/48 , C10G11/05 , C10G47/16
Abstract: The disclosure is related to various modified EMM-23 materials, processes, and uses of the same.
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公开(公告)号：US20180318816A1
公开(公告)日：2018-11-08
申请号：US15969162
申请日：2018-05-02
Applicant: ExxonMobil Research and Engineering Company
Inventor： Joseph M. Falkowski , Mary S. Abdulkarim , Mobae Afeworki , Randall J. Meyer , Simon C. Weston
CPC classification number: B01J31/1691 , B01J20/226 , B01J31/00 , C07C5/2293 , C07C5/2562 , C07C2531/16 , C07C2531/24 , C07F9/3843 , C07F9/3856 , C07F9/425 , C07C11/10
Abstract: A novel metal organic framework, EMM-39, is described having the structure of UiO-66 and comprising bisphosphonate linking ligands. EMM-39 has acid activity and is useful as a catalyst in olefin isomerization. Also disclosed is a process of making metal organic frameworks, such as EMM-39, by heterogeneous ligand exchange, in which linking ligands having a first bonding functionality in a host metal organic framework are exchanged with linking ligands having a second different bonding functionality in the framework.
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公开(公告)号：US20210346875A1
公开(公告)日：2021-11-11
申请号：US17217782
申请日：2021-03-30
Inventor： Yuriy Román-Leshkov , Randall J. Meyer , Pedro M. Serna Merino , Mark Sullivan , Kimberly Dinh
Abstract: Catalytic compositions and sequential catalytic methods are generally described. in some embodiments, a composition comprises a first catalyst comprising a Cu-modified zeolite, and a second catalyst capable of a coupling reaction between (a) an intermediate resulting from a reaction of a reactant at the first catalyst, and (b) a co-reagent, wherein a rate of diffusion of the co-reagent within one or more cages and/or pores of the first catalyst is lower than a rate of diffusion of the intermediate within the one or more cages and/or pores of the first catalyst.
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公开(公告)号：US20210300842A1
公开(公告)日：2021-09-30
申请号：US17177081
申请日：2021-02-16
Applicant: ExxonMobil Research and Engineering Company
Inventor： Brandon J. O'Neill , Joe M. Falkowski , Allen W. Burton , Scott J. Weigel , Randall J. Meyer , Ajit B. Dandekar
Abstract: Zeolitic and molecular organic framework materials as catalysts suitable for generating branched olefins from linear olefins, thereby increasing the octane of a composition comprising the linear olefins. In particular, catalyst may exhibit selectivity for methyl-shift isomerization over cracking, alkylation, and oligomerization.
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公开(公告)号：US20180318817A1
公开(公告)日：2018-11-08
申请号：US15969182
申请日：2018-05-02
Applicant: ExxonMobil Research and Engineering Company
Inventor： Joseph M. Falkowski , Mary S. Abdulkarim , Mobae Afeworki , Randall J. Meyer , Simon C. Weston
CPC classification number: B01J31/1691 , B01J20/226 , B01J31/00 , C07C1/24 , C07C5/2293 , C07C5/2562 , C07C2531/16 , C07C2531/18 , C07C2531/24 , C07F9/3843 , C07F9/3856 , C07F9/425 , C07C11/10 , C07C11/08
Abstract: A novel metal organic framework, EMM-42, is described having the structure of UiO-66 and comprising bisphosphonate linking ligands. EMM-42 has acid activity and is useful as a catalyst in olefin isomerization. Also disclosed is a process of making metal organic frameworks, such as EMM-42, by heterogeneous ligand exchange, in which linking ligands having a first bonding functionality in a host metal organic framework are exchanged with linking ligands having a second different bonding functionality in the framework.
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