公开(公告)号：US20160318004A1

公开(公告)日：2016-11-03

申请号：US15103907

申请日：2014-12-17

Applicant: KING ABDULLAH UNIVERSITY OF SCIENCE AND TECHNOLOGY

Inventor： Lidong LI ,  Dalaver H. ANJUN ,  Lu ZHOU ,  Paco LAVEILLE ,  Jean-Marie BASSET

IPC: B01J23/89 ,  C01B3/40 ,  B01J37/08 ,  B01J37/04 ,  B01J21/04 ,  B01J35/00

CPC classification number: B01J23/892 ,  B01J21/04 ,  B01J35/0006 ,  B01J35/0013 ,  B01J35/002 ,  B01J35/0066 ,  B01J35/008 ,  B01J35/0086 ,  B01J35/023 ,  B01J35/1019 ,  B01J35/1038 ,  B01J37/0207 ,  B01J37/0209 ,  B01J37/0211 ,  B01J37/0244 ,  B01J37/0248 ,  B01J37/04 ,  B01J37/08 ,  B01J37/16 ,  B01J37/18 ,  B82Y30/00 ,  B82Y40/00 ,  C01B3/26 ,  C01B3/40 ,  C01B3/583 ,  C01B2203/0238 ,  C01B2203/0277 ,  C01B2203/044 ,  C01B2203/047 ,  C01B2203/1058 ,  C01B2203/107 ,  C01B2203/1082 ,  C01B2203/1241 ,  C07C5/03 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2521/08 ,  C07C2521/18 ,  C07C2523/42 ,  C07C2523/755 ,  C07C2523/89 ,  Y02P20/52 ,  C07C15/073

Abstract: Embodiments of the present disclosure provide for supported Ni/Pt bimetallic nanoparticles having a Ni core and a Pt layer disposed on the surface of the Ni core, compositions including supported NiPt nanoparticles, methods of making supported NiPt nanoparticles, methods of using supported NiPt nanoparticles, and the like.

Abstract translation: 本公开的实施方案提供了具有Ni芯和设置在Ni芯的表面上的Pt层的负载的Ni / Pt双金属纳米颗粒，包含负载的NiPt纳米颗粒的组合物，制备负载的NiPt纳米颗粒的方法，使用负载的NiPt纳米颗粒的方法， 等等。

公开(公告)号：US20220098034A1

公开(公告)日：2022-03-31

申请号：US17414440

申请日：2019-11-08

Applicant: King Abdullah University of Science and Technology

Inventor： Baraa WERGHI ,  Jean-Marie BASSET ,  Kuo-Wei HUANG ,  Eva PUMP ,  Anissa BENDJERIOUSEDJERARI

IPC: C01B3/26 ,  B01J31/18 ,  B01J31/16 ,  B01J31/14 ,  B01J37/08 ,  B01J37/04 ,  H01M8/0612

Abstract: The invention relates to heterogeneous catalysts comprising an organo-ruthenium complex immobilized to an aluminum-modified inorganic oxide by a chemical bond between a tetra-coordinated aluminum atom on a surface of the aluminum-modified inorganic oxide and an amino or imino nitrogen of the organo-ruthenium complex, methods of preparing the heterogeneous catalysts including immobilizing the organo-ruthenium complex to a tetra-coordinated aluminum atom on a surface of an inorganic oxide by reacting an amino or imino nitrogen of the organo-ruthenium complex and an aluminum-modified inorganic oxide, followed by a defined heat treatment, as well as methods for producing hydrogen from formic acid using the heterogeneous catalysts.

公开(公告)号：US20210163827A1

公开(公告)日：2021-06-03

申请号：US16772947

申请日：2018-12-18

Applicant: King Abdullah University of Science and Technology

Inventor： Jean-Marie BASSET ,  Kuo-Wei HUANG ,  Amol M. HENGNE ,  Linga Reddy ENAKONDA

IPC: C10G2/00 ,  B01J6/00 ,  B01J37/00 ,  B01J21/04 ,  B01J23/745 ,  B01J23/78 ,  B01J35/02

Abstract: Embodiments of the present disclosure describe methods of preparing pre-catalysts that may be activated under methane to form catalysts for the hydrogenation of carbon dioxide to form olefins, among other chemical species. Embodiments of the present disclosure also describe methods of preparing catalysts and pre-catalysts, catalyst and pre-catalyst compositions, and methods of producing one or more chemical species using catalysts.

公开(公告)号：US20190330059A1

公开(公告)日：2019-10-31

申请号：US16312149

申请日：2017-06-24

Applicant: King Abdullah University of Science and Technology

Inventor： Kazuhiro TAKANABE ,  Jean-Marie BASSET ,  Jung-Hyun PARK ,  Akshaya SAMAL ,  Bedour ALSABBAN

IPC: C01B3/40 ,  B01J23/75 ,  B01J23/83 ,  B01J21/02 ,  B01J37/02 ,  B01J37/18 ,  B01J37/08

Abstract: The present invention uses a cobalt catalyst for carbon dioxide reforming of lower alkanes to synthesis gas having a cobalt catalyst on an oxide support where the supported cobalt catalyst has been modified with a boron precursor. The boron-treated cobalt catalyst systems as described herein show significant increases in the conversion of CH4 and CO2 during the dry reforming of methane (DRM) reaction as compared to traditional catalysts. Described herein are supported catalysts and methods of using the catalysts for the dry reforming of methane to synthesis gas, with the supported catalysts in the present invention include a boron-treated cobalt catalyst disposed on an oxide support. Also described herein are processes for preparing the supported catalysts.

公开(公告)号：US20180312403A1

公开(公告)日：2018-11-01

申请号：US15769947

申请日：2016-10-19

Applicant: King Abdullah University of Science and Technology

Inventor： Jean-Marie BASSET ,  Lu ZHOU ,  Youssef SAIH

IPC: C01B32/162 ,  B01J23/745 ,  B01J21/04 ,  B01J21/18 ,  B01J35/00 ,  B01J37/08

CPC classification number: C01B32/162 ,  B01J21/04 ,  B01J21/185 ,  B01J23/745 ,  B01J35/0013 ,  B01J37/084 ,  B82Y30/00 ,  B82Y40/00 ,  C01B2202/36 ,  C01P2004/03

Abstract: Embodiments of the present disclosure provide for methods that can be used to produce carbon nanotubes (hereinafter CNT) having an inner diameter about 5-55 nm, methods of tuning the inner diameter of CNTs (e.g., by adjusting reaction pressure), CNTs having an inner diameter of greater than 20 nm or more, and the like.

公开(公告)号：US20180200702A1

公开(公告)日：2018-07-19

申请号：US15744226

申请日：2016-07-12

Applicant: King Abdullah University of Science and Technology

Inventor： Jean-Marie BASSET ,  Manoja K. SAMANTARAY ,  Raju DEY ,  Edy ABOU-HAMAD ,  Santosh KAVITAKE

IPC: B01J31/12 ,  B01J31/16

CPC classification number: B01J31/121 ,  B01J31/122 ,  B01J31/1625 ,  B01J2231/543

Abstract: Provided herein are bi-metallic catalysts, methods of making, and uses thereof. In some embodiments, the bi-metallic catalyst contains two different metal catalysts that can be used in hydrocarbon metathesis reactions, in some embodiments, the methods of making the bi-metallic catalysts can include two steps utilizing a surface organometallic chemistry approach in which the two different metal catalysts are sequentially grafted onto a support.

公开(公告)号：US20130224106A1

公开(公告)日：2013-08-29

申请号：US13746936

申请日：2013-01-22

Applicant: King Abdullah University of Science and Technology

Inventor： Jean-Marie BASSET ,  Vivek POLSHETTIWAR ,  Mohamed BOUHRARA ,  Youssef SAIH

IPC: C01B3/26 ,  C07C2/76

CPC classification number: C01B3/26 ,  C01B2203/0277 ,  C01B2203/1047 ,  C01B2203/1052 ,  C01B2203/1064 ,  C01B2203/107 ,  C01B2203/1082 ,  C07C2/76 ,  C07C2521/08 ,  C07C2523/46 ,  C07C2523/745 ,  C07C2523/75 ,  C07C9/06

Abstract: A process for the decomposition of methane can be controlled to form ethane or hydrogen with a solid carbon product.

Abstract translation: 可以控制甲烷分解的方法以与固体碳产物形成乙烷或氢气。

公开(公告)号：US20130211137A1

公开(公告)日：2013-08-15

申请号：US13755549

申请日：2013-01-31

Applicant: KING ABDULLAH UNIVERSITY OF SCIENCE AND TECHNOLOGY

Inventor： Jean-Marie BASSET ,  Miao SUN ,  Valerie CAPS ,  Jeremie PELLETIER ,  Edy ABOU-HAMAD

IPC: C07C51/16

CPC classification number: C07C51/16 ,  B01J23/28 ,  B01J23/30 ,  B01J27/188 ,  B01J27/19 ,  B01J35/1014 ,  B01J37/0207 ,  C07C53/08

Abstract: Heteropolyacids (HPAs) can activate methane at ambient temperature (e.g., 20° C.) and atmospheric pressure, and transform methane to acetic acid, in the absence of any noble metal such as Pd). The HPAs can be, for example, those with Keggin structure: H4SiW12O40, H3PW12O40, H4SiMo12O40, or H3PMo12O40, can be when supported on silica.

Abstract translation: 杂多酸（HPAs）可以在环境温度（例如20℃）和大气压下活化甲烷，并且在没有任何贵金属如Pd的情况下将甲烷转化为乙酸。 HPAs可以是例如具有Keggin结构的那些：H4SiW12O40，H3PW12O40，H4SiMo12O40或H3PMo12O40，当负载在二氧化硅上时。