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    WATER-PROCESSABLE SILICONE-CONTAINING PREPOLYMERS AND USES THEREOF
    1.
    发明申请
    WATER-PROCESSABLE SILICONE-CONTAINING PREPOLYMERS AND USES THEREOF 有权
    含水硅油的预处理剂及其用途

    公开(公告)号：US20160033683A1

    公开(公告)日：2016-02-04

    申请号：US14883142

    申请日：2015-10-14

    Applicant: Novartis AG

    Inventor： Jinyu Huang ,  Frank Chang ,  Robert Scott ,  Arturo Norberto Medina ,  Venkat Shankar ,  Selma Kuyu ,  Dawn Alison Smith ,  Daqing Wu

    IPC: G02B1/04 ,  C08J3/075

    CPC classification number: G02B1/043 ,  C08G77/20 ,  C08G77/42 ,  C08G77/442 ,  C08J3/075 ,  C08J2343/04 ,  C08J2383/08 ,  C08L83/10 ,  C08L101/14 ,  C08L83/04

    Abstract: The invention provide a class of water-processable polymerizable prepolymers which comprises (1) siloxane-containing monomeric units derived at least one siloxane containing monomer having one hydrophilic group or chain and/or polysiloxane-containing crosslinking units derived from at least one hydrophilized polysiloxane or chain-extended polysiloxane crosslinker; (2) hydrophilic monomeric units derived from one or more hydrophilic vinylic monomers; and (3) from about 0.05% to about 5% by weight of polymerizable units each having a pendant or terminal, ethylenically-unsaturated group and free of any polysiloxane segment. The prepolymer comprises from about 20% to about 50% by weight of silicone relative to the total weight of the prepolymer and has a high water solubility or dispersibility of at least about 5% by weight in water and suitable for making silicone hydrogel contact lenses.

    Abstract translation: 本发明提供了一类可水加工的可聚合预聚物，其包含（1）衍生自至少一种含有一个含硅氧烷的单体的含硅氧烷的单体单元，所述单体具有一个亲水基团或链和/或含聚硅氧烷的交联单元，其衍生自至少一种亲水化聚硅氧烷或 链延长聚硅氧烷交联剂; （2）衍生自一种或多种亲水乙烯基单体的亲水单体单元; 和（3）约0.05％至约5％重量的各自具有侧基或末端的可聚合单元，烯属不饱和基团并且不含任何聚硅氧烷链段。 预聚物相对于预聚物的总重量包含约20重量％至约50重量％的硅氧烷，并且在水中具有至少约5重量％的高水溶性或分散性，并且适于制备硅酮水凝胶隐形眼镜。

    Amphiphilic polysiloxane prepolymers and uses thereof
    2.
    发明授权
    Amphiphilic polysiloxane prepolymers and uses thereof 有权
    两亲性聚硅氧烷预聚物及其用途

    公开(公告)号：US08987403B2

    公开(公告)日：2015-03-24

    申请号：US14014631

    申请日：2013-08-30

    Applicant: Novartis AG

    Inventor： Frank Chang ,  Robert Scott ,  Jinyu Huang ,  Arturo N. Medina ,  Dawn A. Smith ,  Laura A. Sanders ,  John Dallas Pruitt

    IPC: C08G77/06 ,  C08G77/388 ,  C08G77/458 ,  G02B1/04 ,  C08F290/06

    CPC classification number: G02B1/043 ,  C08F290/068 ,  C08G77/388 ,  C08G77/458 ,  C08G2210/00 ,  C08L2205/02 ,  C08L83/04 ,  C08L51/085 ,  C08L101/14 ,  C08F220/56 ,  C08F220/28

    Abstract: The present invention provides an amphiphilic polysiloxane prepolymer which comprises hydrophilic monomeric units derived from at least one hydrophilic vinylic monomer, polysiloxane crosslinking units derived from at least one polysiloxane crosslinker having at least two terminal ethylenically-unsaturated groups, dangling polysiloxane chains each of which is terminated with one ethylenically unsaturated group, and chain-transfer units derived from a chain transfer agent other than a RAFT agent. A prepolymer of the invention is suitable for making hydrogel contact lenses. The present invention is also related to hydrogel contact lenses made from an amphiphilic polysiloxane prepolymer of the invention and to processes for preparing an amphiphilic polysiloxane prepolymer of the invention and for making silicone hydrogel contact lenses.

    Abstract translation: 本发明提供一种两亲性聚硅氧烷预聚物，其包含衍生自至少一种亲水乙烯基单体的亲水性单体单元，衍生自至少一种具有至少两个末端烯属不饱和基团的聚硅氧烷交联剂的聚硅氧烷交联单元，悬浮聚硅氧烷链各自被终止 具有一个烯键式不饱和基团，以及衍生自除RAFT试剂之外的链转移剂的链转移单元。 本发明的预聚物适用于制备水凝胶隐形眼镜。 本发明还涉及由本发明的两亲聚硅氧烷预聚物制成的水凝胶隐形眼镜以及制备本发明的两亲性聚硅氧烷预聚物和制备硅酮水凝胶隐形眼镜的方法。

    AMPHIPHILIC POLYSILOXANE PREPOLYMERS AND USES THEREOF
    6.
    发明申请
    AMPHIPHILIC POLYSILOXANE PREPOLYMERS AND USES THEREOF 有权
    聚硅氧烷聚合物预聚物及其用途

    公开(公告)号：US20140005430A1

    公开(公告)日：2014-01-02

    申请号：US14014631

    申请日：2013-08-30

    Applicant: Novartis AG

    Inventor： Frank Chang ,  Robert Scott ,  Jinyu Huang ,  Arturo N. Medina ,  Dawn A. Smith ,  Laura A. Sanders ,  John Dallas Pruitt

    IPC: C08G77/388

    CPC classification number: G02B1/043 ,  C08F290/068 ,  C08G77/388 ,  C08G77/458 ,  C08G2210/00 ,  C08L2205/02 ,  C08L83/04 ,  C08L51/085 ,  C08L101/14 ,  C08F220/56 ,  C08F220/28

    Abstract: The present invention provides an amphiphilic polysiloxane prepolymer which comprises hydrophilic monomeric units derived from at least one hydrophilic vinylic monomer, polysiloxane crosslinking units derived from at least one polysiloxane crosslinker having at least two terminal ethylenically-unsaturated groups, dangling polysiloxane chains each of which is terminated with one ethylenically unsaturated group, and chain-transfer units derived from a chain transfer agent other than a RAFT agent. A prepolymer of the invention is suitable for making hydrogel contact lenses. The present invention is also related to hydrogel contact lenses made from an amphiphilic polysiloxane prepolymer of the invention and to processes for preparing an amphiphilic polysiloxane prepolymer of the invention and for making silicone hydrogel contact lenses.

    Abstract translation: 本发明提供一种两亲性聚硅氧烷预聚物，其包含衍生自至少一种亲水乙烯基单体的亲水性单体单元，衍生自至少一种具有至少两个末端烯属不饱和基团的聚硅氧烷交联剂的聚硅氧烷交联单元，悬浮聚硅氧烷链各自被终止 具有一个烯键式不饱和基团，以及衍生自除RAFT试剂之外的链转移剂的链转移单元。 本发明的预聚物适用于制备水凝胶隐形眼镜。 本发明还涉及由本发明的两亲聚硅氧烷预聚物制成的水凝胶隐形眼镜以及制备本发明的两亲性聚硅氧烷预聚物和制备硅酮水凝胶隐形眼镜的方法。

    Production of ophthalmic devices based on photo-induced step growth polymerization
    8.
    发明授权
    Production of ophthalmic devices based on photo-induced step growth polymerization 有权
    基于光诱导步骤生长聚合的眼科装置的生产

    公开(公告)号：US08609745B2

    公开(公告)日：2013-12-17

    申请号：US13711655

    申请日：2012-12-12

    Applicant: Novartis AG

    Inventor： Arturo Norberto Medina ,  Dawn Alison Smith ,  Robert Scott

    IPC: G02B1/04 ,  C08F290/04

    CPC classification number: B29D11/00038 ,  C08F275/00 ,  G02B1/041 ,  G02B1/043 ,  C08L33/08 ,  C08L33/10 ,  C08L23/20

    Abstract: The invention provide a new lens curing method for making hydrogel contact lenses. The new lens curing method is based on actinically-induced step-growth polymerization. The invention also provides hydrogel contact lenses prepared from the method of the invention and fluid compositions for making hydrogel contact lenses based on the new lens curing method. In addition, the invention provide prepolymers capable of undergoing actinically-induced step-growth polymerization to form hydrogel contact lenses.

    Abstract translation: 本发明提供一种用于制造水凝胶隐形眼镜的新型镜片固化方法。 新的透镜固化方法是基于光化诱导的步进增长聚合。 本发明还提供了根据本发明的方法制备的水凝胶隐形眼镜和基于新的镜片固化方法制备水凝胶隐形眼镜的流体组合物。 此外，本发明提供能够进行光化诱导的步进生长聚合以形成水凝胶隐形眼镜的预聚物。

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