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公开(公告)号：US20080265153A1
公开(公告)日：2008-10-30
申请号：US11332782
申请日：2006-01-12
Applicant: Richard N. Zare , Oliver Trapp
Inventor： Richard N. Zare , Oliver Trapp
IPC: B01D59/44
Abstract: The present invention provides a method of coating an electrospray emitter with silver and then gold utilizing wet-coating processes. First, the electrospray emitter is immersed in a silver-containing liquid solution to coat the electrospray emitter in a layer of silver. Next, the silver-coated electrospray emitter is removed from the silver solution and rinsed with water. The silver-coated electrospray emitter is then annealed to stabilize the silver layer. Once the silver layer has been stabilized, the silver-coated electrospray emitter is immersed into a gold-containing liquid solution and a voltage is applied. This voltage serves to electrochemically deposit a gold layer onto the silver layer. The gold- and silver-coated electrospray emitter is then removed from the gold-containing liquid solution and rinsed with water and, preferably, with nitric acid.
Abstract translation: 本发明提供一种使用湿涂层方法用银涂覆电喷雾发射器的方法，然后使用金涂覆电喷雾发射器。 首先，将电喷射发射器浸入含银液体溶液中，以涂覆银层中的电喷发射体。 接下来，将银涂布的电喷雾发射器从银溶液中取出并用水冲洗。 然后将镀银电喷发射体退火以稳定银层。 一旦银层已经稳定，将银涂覆的电喷雾发射器浸入含金液体溶液中并施加电压。 该电压用于在银层上电化学沉积金层。 然后将金和银涂层的电喷雾发射器从含金液体溶液中除去，并用水冲洗，最好用硝酸冲洗。
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公开(公告)号：US07067803B2
公开(公告)日：2006-06-27
申请号：US10683244
申请日：2003-10-09
Applicant: Richard N. Zare , Facundo M. Fernandez , Joel R. Kimmel , Oliver Trapp
Inventor： Richard N. Zare , Facundo M. Fernandez , Joel R. Kimmel , Oliver Trapp
IPC: H01J49/00
CPC classification number: H01J49/061 , H01J49/40
Abstract: By connecting the Bradbury-Nielson gate (BNG) directly to a driver without a transmission line, distortion of the voltage waveform experienced a the BNG are much reduced. Because the magnitude of the modulation defects grows as the applied modulation voltage is increased, Bradbury-Nielson gates with finer wire spacing such as 100 microns, and operating at 10 to 15 V, significantly better signal-to-noise ratios are achieved. HT-TOFMS data were also post processed using an exact knowledge of the modulation defects.
Abstract translation: 通过将Bradbury-Nielson门（BNG）直接连接到没有传输线的驱动器，经历BNG的电压波形的失真大大减少。 由于调制缺陷的幅度随着施加的调制电压的增加而增加，所以Bradbury-Nielson门具有更细的导线间距，例如100微米，并且在10至15V下工作，实现了明显更好的信噪比。 HT-TOFMS数据也使用调制缺陷的确切知识进行后处理。
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Patent Agency Ranking
公开(公告)号：US07446311B1
公开(公告)日：2008-11-04
申请号：US11332782
申请日：2006-01-12
Applicant: Richard N. Zare , Oliver Trapp
Inventor： Richard N. Zare , Oliver Trapp
IPC: B01D59/44
Abstract: The present invention provides a method of coating an electrospray emitter with silver and then gold utilizing wet-coating processes. First, the electrospray emitter is immersed in a silver-containing liquid solution to coat the electrospray emitter in a layer of silver. Next, the silver-coated electrospray emitter is removed from the silver solution and rinsed with water. The silver-coated electrospray emitter is then annealed to stabilize the silver layer. Once the silver layer has been stabilized, the silver-coated electrospray emitter is immersed into a gold-containing liquid solution and a voltage is applied. This voltage serves to electrochemically deposit a gold layer onto the silver layer. The gold- and silver-coated electrospray emitter is then removed from the gold-containing liquid solution and rinsed with water and, preferably, with nitric acid.
Abstract translation: 本发明提供一种使用湿涂层方法用银涂覆电喷雾发射器的方法，然后使用金涂覆电喷雾发射器。 首先，将电喷射发射器浸入含银液体溶液中，以涂覆银层中的电喷发射体。 接下来，将银涂布的电喷雾发射器从银溶液中取出并用水冲洗。 然后将镀银电喷发射体退火以稳定银层。 一旦银层已经稳定，将银涂覆的电喷雾发射器浸入含金液体溶液中并施加电压。 该电压用于在银层上电化学沉积金层。 然后将金和银涂覆的电喷雾发射器从含金液体溶液中除去，并用水冲洗，最好用硝酸冲洗。
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公开(公告)号：US07456391B2
公开(公告)日：2008-11-25
申请号：US11411393
申请日：2006-04-25
Applicant: Richard N. Zare , Facundo M. Fernandez , Joel R. Kimmel , Oliver Trapp
Inventor： Richard N. Zare , Facundo M. Fernandez , Joel R. Kimmel , Oliver Trapp
IPC: B01D59/44
CPC classification number: H01J49/061 , H01J49/40
Abstract: By connecting the Bradbury-Nielson gate (BNG) directly to a driver without a transmission line, distortion of the voltage waveform experienced a the BNG are much reduced. Because the magnitude of the modulation defects grows as the applied modulation voltage is increased, Bradbury-Nielson gates with finer wire spacing such as 100 microns, and operating at 10 to 15 V, significantly better signal-to-noise ratios are achieved. HT-TOFMS data were also post processed using an exact knowledge of the modulation defects.
Abstract translation: 通过将Bradbury-Nielson门（BNG）直接连接到没有传输线的驱动器，经历BNG的电压波形的失真大大减少。 由于调制缺陷的幅度随着施加的调制电压的增加而增加，所以Bradbury-Nielson门具有更细的导线间距，例如100微米，并且在10至15V下工作，实现了明显更好的信噪比。 HT-TOFMS数据也使用调制缺陷的确切知识进行后处理。
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公开(公告)号：US20060192105A1
公开(公告)日：2006-08-31
申请号：US11411393
申请日：2006-04-25
Applicant: Richard Zare , Facundo Fernandez , Joel Kimmel , Oliver Trapp
Inventor： Richard Zare , Facundo Fernandez , Joel Kimmel , Oliver Trapp
CPC classification number: H01J49/061 , H01J49/40
Abstract: By connecting the Bradbury-Nielson gate (BNG) directly to a driver without a transmission line, distortion of the voltage waveform experienced a the BNG are much reduced. Because the magnitude of the modulation defects grows as the applied modulation voltage is increased, Bradbury-Nielson gates with finer wire spacing such as 100 microns, and operating at 10 to 15 V, significantly better signal-to-noise ratios are achieved. HT-TOFMS data were also post processed using an exact knowledge of the modulation defects.
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公开(公告)号：US08297135B2
公开(公告)日：2012-10-30
申请号：US12090687
申请日：2006-10-17
Applicant: Oliver Trapp
Inventor： Oliver Trapp
CPC classification number: G01N30/20 , G01N30/463 , G01N30/8658 , G01N2030/123 , G01N2030/623
Abstract: The invention relates to a method for substance mixtures, particularly complex chemical and/or biochemical substance mixtures. According to said method, a substance mixture that is to be analyzed is fed to a separating device, the substances of the substance mixture that is to be analyzed are separated from each other in the separating device by means of a chemically and/or physically induced conveying process, and the separated substances are detected in an evaluation unit. The invention further relates to methods and devices for producing pulsed substance mixtures, particularly complex chemical and/or biochemical substance mixtures. In order to improve the analysis of substance mixtures especially regarding the duration of the analysis, the throughput, and the resolution, the substance mixture that is to be analyzed is fed to the separating device in pulses having an unique binary sequence.
Abstract translation: 本发明涉及物质混合物，特别是复杂的化学和/或生物化学物质混合物的方法。 根据所述方法，将要分析的物质混合物供给到分离装置中，待分析的物质混合物的物质通过化学和/或物理诱导在分离装置中彼此分离 输送过程，并且在评估单元中检测分离的物质。 本发明还涉及用于生产脉冲物质混合物，特别是复杂的化学和/或生物化学物质混合物的方法和装置。 为了改进对物质混合物的分析，特别是关于分析持续时间，将要分析的物质混合物的产量和分辨率以具有唯一二进制序列的脉冲供给分离装置。
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公开(公告)号：US20080295617A1
公开(公告)日：2008-12-04
申请号：US12090687
申请日：2006-10-17
Applicant: Oliver Trapp
Inventor： Oliver Trapp
CPC classification number: G01N30/20 , G01N30/463 , G01N30/8658 , G01N2030/123 , G01N2030/623
Abstract: The invention relates to a method for substance mixtures, particularly complex chemical and/or biochemical substance mixtures. According to said method, a substance mixture that is to be analyzed is fed to a separating device, the substances of the substance mixture that is to be analyzed are separated from each other in the separating device by means of a chemically and/or physically induced conveying process, and the separated substances are detected in an evaluation unit. The invention further relates to methods and devices for producing pulsed substance mixtures, particularly complex chemical and/or biochemical substance mixtures. In order to improve the analysis of substance mixtures especially regarding the duration of the analysis, the throughput, and the resolution, the substance mixture that is to be analyzed is fed to the separating device in pulses having an unique binary sequence.
Abstract translation: 本发明涉及物质混合物，特别是复杂的化学和/或生物化学物质混合物的方法。 根据所述方法，将要分析的物质混合物供给到分离装置中，待分析的物质混合物的物质通过化学和/或物理诱导在分离装置中彼此分离 输送过程，并且在评估单元中检测分离的物质。 本发明还涉及用于生产脉冲物质混合物，特别是复杂的化学和/或生物化学物质混合物的方法和装置。 为了改进对物质混合物的分析，特别是关于分析持续时间，将要分析的物质混合物的产量和分辨率以具有唯一二进制序列的脉冲供给分离装置。
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