Abstract:
The invention relates to contactors suitable for use, for example, in manufacturing and chemical refinement processes. In an aspect is a hybrid indirect/direct contactor for thermal management of counter-current processes, the contactor comprising a vertical reactor column, an array of interconnected heat transfer tubes within the reactor column, and a plurality of stream path diverters, wherein the tubes and diverters are configured to block all straight-line paths from the top to bottom ends of the reactor column.
Abstract:
Low-cost and energy-efficient C02 and H2S capture is provided obtaining greater than 99.9% capture efficiency from pressurized gas. The acid species are captured in an ammonia solution, which is then regenerated by stripping the absorbed species. The solution can capture as much as 330 grams of C02 and H2S per 1000 gram of water and when regenerated it produces pure pressurized acid gas containing more than 99.7% C02 and H2S. The absorption of the acid species is accomplished in two absorbers in-series, each having multiple stages. More than 95% of the acid species are captured in the first absorber and the balance is captured in the second absorber to below 10 ppm concentration in the outlet gas. The two absorbers operate at temperatures ranging from 20-70 degrees Celsius. The two absorbers and the main stripper of the alkaline solution operate at similar pressures ranging from 5-200 bara.
Abstract:
The invention provides methods for producing a strong, light, sorbent-based storage/dispenser system for gases and fuels. The system comprises a porous monolithic material with an adherent strong impervious skin that is capable of storing a gas under pressure in a safe and usable manner.
Abstract:
Low-cost and energy-efficient CO2 and H2S capture is provided obtaining greater than 99.9% capture efficiency from pressurized gas. The acid species are captured in an ammonia solution, which is then regenerated by stripping the absorbed species. The solution can capture as much as 330 grams of CO2 and H2S per 1000 gram of water and when regenerated it produces pure pressurized acid gas containing more than 99.7% CO2 and H2S. The absorption of the acid species is accomplished in two absorbers in-series, each having multiple stages. More than 95% of the acid species are captured in the first absorber and the balance is captured in the second absorber to below 10 ppm concentration in the outlet gas. The two absorbers operate at temperatures ranging from 20-70 degrees Celsius. The two absorbers and the main stripper of the alkaline solution operate at similar pressures ranging from 5-200 bara.
Abstract:
The invention provides methods for preparing an asymmetric hollow fiber, the asymmetric hollow fibers prepared by such methods, and uses of the asymmetric hollow fibers. One method involves passing a polymeric solution through an outer annular orifice of a tube-in-orifice spinneret, passing a bore fluid though an inner tube of the spinneret, dropping the polymeric solution and bore fluid through an atmosphere over a dropping distance, and quenching the polymeric solution and bore fluid in a bath to form an asymmetric hollow fiber.
Abstract:
The invention provides methods for producing a strong, light, sorbent-based storage/dispenser system for gases and fuels. The system comprises a porous monolithic material with an adherent strong impervious skin that is capable of storing a gas under pressure in a safe and usable manner.
Abstract:
The technical field of the invention is CO2 capture and sequestration, as well as gas separation and purification technologies. In an aspect is a process for capturing purified CO2 from a CO2-containing gas, comprising steps: (a) contacting in an absorber column the CO2-containing gas with an absorption solution comprising water, ammonia, and potassium carbonate, to enable adsorption of CO2, thereby producing a CO2-depleted gas and a CO2-rich solution; and (b) subjecting the CO2-rich solution to desorption conditions in a regeneration column producing a purified CO2 gas stream and a CO2-depleted solution.
Abstract:
The invention relates to contactors suitable for use, for example, in manufacturing and chemical refinement processes. In an aspect is a hybrid indirect/direct contactor for thermal management of counter-current processes, the contactor comprising a vertical reactor column, an array of interconnected heat transfer tubes within the reactor column, and a plurality of stream path diverters, wherein the tubes and diverters are configured to block all straight-line paths from the top to bottom ends of the reactor column.
Abstract:
The technical field of the invention is CO2 capture and sequestration, as well as gas separation and purification technologies. In an aspect is a process for capturing purified CO2 from a CO2-containing gas, comprising steps: (a) contacting in an absorber column the CO2-containing gas with an absorption solution comprising water, ammonia, and potassium carbonate, to enable adsorption of CO2, thereby producing a CO2-depleted gas and a CO2-rich solution; and (b) subjecting the CO2-rich solution to desorption conditions in a regeneration column producing a purified CO2 gas stream and a CO2-depleted solution.
Abstract:
The invention provides methods for preparing an asymmetric hollow fiber, the asymmetric hollow fibers prepared by such methods, and uses of the asymmetric hollow fibers. One method involves passing a polymeric solution through an outer annular orifice of a tube-in-orifice spinneret, passing a bore fluid though an inner tube of the spinneret, dropping the polymeric solution and bore fluid through an atmosphere over a dropping distance, and quenching the polymeric solution and bore fluid in a bath to form an asymmetric hollow fiber.