公开(公告)号：US09688790B2

公开(公告)日：2017-06-27

申请号：US14410248

申请日：2013-06-24

Applicant: SAUDI BASIC INDUSTRIES CORPORATION

Inventor： Mansour Taftaf ,  Martin Alexander Zuideveld ,  Aurora Alexandra Batinas-Geurts ,  Jaiprakash Brijlal Sainani ,  Vimalkumar Mahendrabhai Patel ,  Vladimir Aleksandrovich Zakharov ,  Gennadii Dimitrievich Bukatov ,  Sergei Andreevich Sergeev ,  Nourdin Ghalit

IPC: C08F110/06 ,  C07C233/18 ,  C07C233/69 ,  C07C235/48

CPC classification number: C08F110/06 ,  C07C233/18 ,  C07C233/69 ,  C07C235/48 ,  C07C2101/14 ,  C07C2601/14 ,  C07C2601/16 ,  C08F10/06 ,  C08F2500/04 ,  C08F2500/12 ,  C08F2500/15 ,  C08F4/651 ,  C08F4/6465 ,  C08F4/6565

Abstract: The present invention relates to a catalyst composition comprising the compound represented by the Fischer projection of formula (I) as an internal electron donor, (I) wherein: R1, R2, R3, R4, R5 and R6 are the same or different and are independently selected from a group consisting of hydrogen, straight, branched and cyclic alkyl and aromatic substituted and unsubstituted hydrocarbyl having 1 to 20 carbon atoms; R7 is selected from a group consisting of straight, branched and cyclic alkyl and aromatic substituted and unsubstituted hydrocarbyl having 1 to 20 carbon atoms; and R8 is selected from a group consisting of aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms; N is nitrogen atom; O is oxygen atom; and C is carbon atom. The present invention also relates to a process for preparing said polymerization catalyst composition and to a polymerization catalyst system comprising said catalyst composition, a cocatalyst and optionally an external electron donor. Furthermore, the present invention relates to a polyolefin obtainable by the process according to the present invention and to the use of the compound of formula (I) as in internal electron donor in catalysts for polymerization of olefins.

公开(公告)号：US09587051B2

公开(公告)日：2017-03-07

申请号：US14762500

申请日：2014-01-28

Applicant: Saudi Basic Industries Corporation

Inventor： Mansour Taftaf ,  Jaiprakash Brijlal Sainani ,  Vladimir Aleksandrovich Zakharov ,  Gennadii Dimitrievich Bukatov ,  Vimalkumar Mahendrabhai Patel ,  Sergei Andreevich Sergeev ,  Martin Alexander Zuideveld ,  Aurora Alexandra Batinas-Geurts

IPC: C08F4/654 ,  C08F4/655 ,  C08F4/656 ,  C08F110/06 ,  C07C233/23 ,  C07C233/18 ,  C08F4/649 ,  C08F10/06 ,  C07C233/69

CPC classification number: C08F110/06 ,  C07C233/18 ,  C07C233/23 ,  C07C233/69 ,  C07C2601/14 ,  C08F4/649 ,  C08F4/6546 ,  C08F4/655 ,  C08F10/06 ,  C08F10/00 ,  C08F4/6565 ,  C08F4/651 ,  C08F2500/04 ,  C08F2500/12 ,  C08F2500/24

Abstract: A process for preparing a catalyst component, including: contacting a compound R9zMgX2-z wherein R9 is aromatic, aliphatic or cyclo-aliphatic group containing up to 20 carbon atoms, X is a halide, and z is larger than 0 and smaller than 2, with an alkoxy- or aryloxy-containing silane compound to give a first intermediate reaction product; contacting the first intermediate reaction product with at least one activating compound selected electron donors, compounds of formula M(OR10)v-w(OR11)w, wherein M is Ti, Zr, Hf, Al or Si, and M(OR10)v-w(R11)w wherein M is Si, each R10 and R11, independently, represent an alkyl, alkenyl or aryl group, v is the valency of M, v is 3 or 4, and w is less than v, to give a second intermediate reaction product; and contacting the second intermediate reaction product with a halogen-containing Ti-compound, a monoester as activating agent, and a 1,3-diether as an internal electron donor.

Abstract translation: 一种催化剂组合物，其包含单酯，由式（I）表示的作为内电子给体的化合物，以及任选的另外的选自二酯和二醚的内给电子体，其中：R1，R2，R3，R4，R5和 R6是氢，具有至多20个碳原子的直链，支链和环状烷基，以及具有6至20个碳原子的芳族取代和未取代的烃基，R7是具有至多20个碳原子的直链，支链和环状烷基，芳基取代和未取代的烃基 具有6至20个碳原子，并且R 8是具有6至20个碳原子的芳族取代和未取代的烃基。 还描述了制备聚合催化剂组合物的方法，包含催化剂组合物，助催化剂和任选的外电子给体的聚合催化剂体系; 以及催化剂体系用于烯烃聚合的用途。

公开(公告)号：US09663596B2

公开(公告)日：2017-05-30

申请号：US14762279

申请日：2014-01-28

Applicant: Saudi Basic Industries Corporation

Inventor： Mansour Taftaf ,  Jaiprakash Brijlal Sainani ,  Vladimir Aleksandrovich Zakharov ,  Gennadii Dimitrievich Bukatov ,  Vimalkumar Mahendrabhai Patel ,  Sergei Andreevich Sergeev ,  Martin Alexander Zuideveld ,  Aurora Alexandra Batinas-Geurts

IPC: C08F110/06 ,  C07C233/23 ,  C07C233/18 ,  C07C233/69 ,  C08F4/655 ,  C08F4/649 ,  C08F4/654 ,  C08F10/06

CPC classification number: C08F110/06 ,  C07C233/18 ,  C07C233/23 ,  C07C233/69 ,  C07C2601/14 ,  C08F4/649 ,  C08F4/6546 ,  C08F4/655 ,  C08F10/06 ,  C08F10/00 ,  C08F4/6565 ,  C08F4/651 ,  C08F2500/04 ,  C08F2500/12 ,  C08F2500/24

Abstract: A catalyst composition comprising a monoester, the compound represented by formula (I) as an internal electron donor, and optionally an additional internal electron donor selected from a group consisting of diesters and diethers, wherein: R1, R2, R3, R4, R5 and R6 are hydrogen, straight, branched and cyclic alkyl having at most 20 carbon atoms and aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms, R7 is a straight, branched and cyclic alkyl having at most 20 carbon atoms and aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms, and R8 is an aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms. Also described is a process for preparing the polymerization catalyst composition, a polymerization catalyst system comprising the catalyst composition, a co-catalyst and optionally an external electron donor; and use of the catalyst system for polymerization of olefins.

公开(公告)号：US20150259448A1

公开(公告)日：2015-09-17

申请号：US14410248

申请日：2013-06-24

Applicant: SAUDI BASIC INDUSTRIES CORPORATION

Inventor： Mansour Taftaf ,  Martin Alexander Zuideveld ,  Aurora Alexandra Batinas-Geurts ,  Jaiprakash Brijlal Sainani ,  Vimalkumar Mahendrabhai Patel ,  Vladimir Aleksandrovich Zakharov ,  Gennadii Dimitrievich Bukatov ,  Sergei Andreevich Sergeev ,  Nourdin Ghalit

IPC: C08F110/06 ,  C07C233/18 ,  C07C235/48 ,  C07C233/69

CPC classification number: C08F110/06 ,  C07C233/18 ,  C07C233/69 ,  C07C235/48 ,  C07C2101/14 ,  C07C2601/14 ,  C07C2601/16 ,  C08F10/06 ,  C08F2500/04 ,  C08F2500/12 ,  C08F2500/15 ,  C08F4/651 ,  C08F4/6465 ,  C08F4/6565

Abstract: The present invention relates to a catalyst composition comprising the compound represented by the Fischer projection of formula (I) as an internal electron donor, (I) wherein: R1, R2, R3, R4, R5 and R6 are the same or different and are independently selected from a group consisting of hydrogen, straight, branched and cyclic alkyl and aromatic substituted and unsubstituted hydrocarbyl having 1 to 20 carbon atoms; R7 is selected from a group consisting of straight, branched and cyclic alkyl and aromatic substituted and unsubstituted hydrocarbyl having 1 to 20 carbon atoms; and R8 is selected from a group consisting of aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms; N is nitrogen atom; O is oxygen atom; and C is carbon atom. The present invention also relates to a process for preparing said polymerization catalyst composition and to a polymerization catalyst system comprising said catalyst composition, a cocatalyst and optionally an external electron donor. Furthermore, the present invention relates to a polyolefin obtainable by the process according to the present invention and to the use of the compound of formula (I) as in internal electron donor in catalysts for polymerization of olefins.

Abstract translation: 本发明涉及一种催化剂组合物，其包含由式（I）的费休投影表示的化合物作为内电子给体，（I）其中：R1，R2，R3，R4，R5和R6相同或不同， 独立地选自氢，直链，支链和环状烷基和芳族取代和未取代的具有1至20个碳原子的烃基; R 7选自直链，支链和环状烷基和芳族取代和未取代的具有1至20个碳原子的烃基; 并且R 8选自具有6至20个碳原子的芳族取代和未取代的烃基; N是氮原子; O是氧原子; C是碳原子。 本发明还涉及制备所述聚合催化剂组合物的方法和包含所述催化剂组合物，助催化剂和任选的外电子给体的聚合催化剂体系。 此外，本发明涉及通过本发明的方法获得的聚烯烃以及式（I）化合物在内电子给体中用于烯烃聚合的催化剂中的用途。