公开(公告)号：US12286715B2

公开(公告)日：2025-04-29

申请号：US17470472

申请日：2021-09-09

Applicant: UNIVERSITY OF CENTRAL FLORIDA RESEARCH FOUNDATION, INC.

Inventor： Yang Yang

IPC: B01J21/06 ,  B01J23/00 ,  B01J23/02 ,  B01J35/64 ,  B01J35/66 ,  C23C14/16 ,  C23C14/18 ,  C23C14/30 ,  C23C14/58 ,  C25B1/04 ,  C25B1/55 ,  C25B9/17 ,  C25B11/051 ,  C25B11/091 ,  C25D11/26 ,  H01L31/0224

Abstract: A heterostructured catalyst includes a 2-dimensional (2D) array of titanium including nanocavities that are all directly attached to a substrate. Each of the titanium including nanocavities have a pore with a nanopore size and a wall with a nanowall thickness. The titanium including nanocavities can be titania nanocavities with a metal layer or a metal compound layer on the titania nanocavities including inside the pores, or the titanium including nanocavities can include SrTiO3 or consist of SrTiO3, each with a surface layer of reduced SrTiO3.

公开(公告)号：US20240344770A1

公开(公告)日：2024-10-17

申请号：US18445978

申请日：2024-04-23

Applicant: GREYROCK TECHNOLOGY, LLC

Inventor： Robert Schuetzle ,  Dennis Schuetzle

IPC: F27D3/00 ,  B01J23/755 ,  B01J35/31 ,  B01J35/63 ,  B01J35/64 ,  B01J35/66 ,  B01J37/08 ,  F27D3/16 ,  F27D5/00 ,  F27D9/00 ,  F27D19/00

CPC classification number: F27D3/0033 ,  B01J23/755 ,  B01J35/31 ,  B01J35/63 ,  B01J35/64 ,  B01J35/66 ,  B01J37/08 ,  F27D5/0068 ,  F27D2003/0034 ,  F27D2003/166 ,  F27D2009/0002 ,  F27D2019/0056 ,  F27D2019/0093

Abstract: The present invention describes an improved process for the commercial scale production of high-quality catalyst materials. These improved processes allow for production of catalysts that have very consistent batch to batch property and performance variations. In addition these improved processes allow for minimal production losses (by dramatically reducing the production of fines or small materials as part of the production process). The improved process involves multiple steps and uses calcining ovens that allow for precisely control temperature increases where the catalyst is homogenously heated. The calcining gas is released into a separate heating chamber, which contains the recirculation fan and the heat source. Catalysts that may be produced using this improved process include but are not limited to catlaysts that promote CO hydrogenation, reforming catalysts, Fischer Tropsch Catalysts, Greyrock GreyCat™ catalysts, catalysts that homologate methanol, catalysts that promote hydrogenation of carbon compounds, and other catalysts used in industry.

公开(公告)号：US12023657B2

公开(公告)日：2024-07-02

申请号：US17240703

申请日：2021-04-26

Applicant: Ineos US Chemicals Company

Inventor： Philip Nubel

IPC: B01J29/40 ,  B01J29/42 ,  B01J29/48 ,  B01J35/40 ,  B01J35/61 ,  B01J35/64 ,  B01J35/69 ,  B01J37/08 ,  C01B39/02 ,  C07C5/22 ,  C07C5/27 ,  C07C15/08 ,  B01J29/04 ,  B01J35/66

CPC classification number: B01J29/405 ,  B01J29/40 ,  B01J29/42 ,  B01J29/48 ,  B01J35/40 ,  B01J35/613 ,  B01J35/615 ,  B01J35/643 ,  B01J35/647 ,  B01J35/69 ,  B01J37/08 ,  C01B39/026 ,  C07C5/222 ,  C07C5/2737 ,  C07C5/2775 ,  C07C15/08 ,  B01J29/041 ,  B01J29/042 ,  B01J29/045 ,  B01J35/66 ,  B01J2229/10 ,  B01J2229/16 ,  B01J2229/20 ,  B01J2229/37 ,  B01J2229/38 ,  B01J2229/40 ,  C07C2529/40 ,  C07C2529/48 ,  Y02P20/52 ,  C07C5/2737 ,  C07C15/08 ,  C07C5/2775 ,  C07C15/08

Abstract: A method of making a xylene isomerization catalyst comprises the steps of (i) contacting a ZSM-5 zeolite starting material having a silica to alumina molar ratio of 20 to 50 and having a mesopore surface area in the range of 50 m2/gram to 200 m2/gram in a reactor with a base to provide an intermediate zeolite material; (ii) recovering the intermediate ZSM-5 zeolite material of step (i); (iii) contacting the intermediate zeolite material with an acid to provide an acid treated ZSM-5 zeolite product; (iv) recovering the acid treated ZSM-5 zeolite material; and (v) calcining the acid treated ZSM-5 zeolite material to provide a desilicated ZSM-5 zeolite product having a silica to alumina molar ratio of 20 to 150 and having a mesopore surface area in the range of 100 m2/gram to 400 m2/gram.

公开(公告)号：US12006479B1

公开(公告)日：2024-06-11

申请号：US18066521

申请日：2022-12-15

Applicant: Saudi Arabian Oil Company

Inventor： Guanghui Zhu ,  Maryam M. Al-Taher ,  Qingyuan Hu

IPC: C10G27/04 ,  B01J31/02 ,  B01J35/56 ,  B01J35/66 ,  C10G61/02 ,  C10L1/04 ,  F02M27/02 ,  F02M31/12 ,  F02M31/16

CPC classification number: C10G27/04 ,  B01J31/0271 ,  B01J35/56 ,  B01J35/66 ,  C10G61/02 ,  C10L1/04 ,  F02M27/02 ,  F02M31/12 ,  F02M31/16 ,  C10G2300/307 ,  C10G2300/4068 ,  C10G2300/80 ,  C10G2400/02 ,  C10L2200/0423 ,  C10L2270/02 ,  C10L2290/06 ,  C10L2290/24

Abstract: According to one or more other aspects of the present disclosure, a system for reforming a liquid hydrocarbon fuel includes a mixing zone with a fuel intake fluidly coupled to a liquid hydrocarbon fuel source and an oxygen-containing gas intake fluidly coupled to an oxygen-containing gas source. The mixing zone further includes at least one atomizing nozzle and a fuel distribution zone downstream the at least on atomizing nozzle. The system also includes a catalyst reaction zone downstream the mixing zone, including a monolith block having a plurality of flow channels defined by monolith walls and a reforming catalyst coated onto the monolith walls. The atomizing nozzle generates a plurality of droplets comprising the liquid hydrocarbon fuel suspended in oxygen-containing gas. The fuel distribution zone distributes the plurality of droplets to each of the plurality of flow channels to contact the reforming catalyst including N-hydroxyphthalimide.

公开(公告)号：US20250011278A1

公开(公告)日：2025-01-09

申请号：US18705667

申请日：2022-11-15

Applicant: API CORPORATION

Inventor： Yurie KOBA ,  Hirotsugu TANIIKE ,  Naoyuki WATANABE

IPC: C07C231/10 ,  B01J23/44 ,  B01J35/40 ,  B01J35/56 ,  B01J35/66 ,  C07C231/24

Abstract: A method for producing acetaminophen, the method comprising causing p-nitrophenol to undergo an acetamination reaction to produce the acetaminophen, by passing a solution containing the p-nitrophenol through a column packed with a catalyst while also passing an acetylating agent and hydrogen through the column. The catalyst is a supported metal catalyst in which a metal element is supported on a monolith porous body, and a reaction temperature of the acetamination reaction is 0° C. to 60° C., and a reaction pressure of the acetamination reaction is 0.1 MPa to 1 MPa.

公开(公告)号：US20250002430A1

公开(公告)日：2025-01-02

申请号：US18700708

申请日：2022-10-13

Applicant: CHINA PETROLEUM & CHEMICAL CORPORATION ,  SHANGHAI RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGY, SINOPEC

Inventor： Wei LI ,  Yaxin ZHOU ,  Libin WU ,  Yuemei WANG ,  Min HOU

IPC: C07C13/26 ,  B01J29/70 ,  B01J29/85 ,  B01J35/63 ,  B01J35/66 ,  B01J37/02 ,  B01J37/04 ,  B01J37/12

Abstract: An olefin conversion catalyst and its preparation method and application are disclosed. The catalyst comprises the following components, in parts by mass: a) 50-90 parts of a molecular sieve with a structure of twelve-membered ring and above; b) calculated as oxide, 0.1-10 parts of an added component selected from Group IA metal elements, Group IIA metal elements, or a combination thereof; c) calculated as oxide, 0.1-10 parts of a modifying component selected from silicon, germanium, bismuth, tin, boron, gallium or a combination thereof; and d) 10-49 parts of a support component. When the catalyst is used to convert a small amount of olefins in an aromatic distillate oil, it has the characteristics of high activity and stability, long life and effective utilization of olefins.

公开(公告)号：US20240359167A1

公开(公告)日：2024-10-31

申请号：US18572000

申请日：2021-07-29

Applicant: Toyo Tire Corporation

Inventor： Norihiko Nakamura ,  Noritatsu Tsubaki ,  Guohui Yang

IPC: B01J29/40 ,  B01J35/63 ,  B01J35/66 ,  B01J37/00 ,  B01J37/10 ,  C07C1/24

CPC classification number: B01J29/405 ,  B01J35/633 ,  B01J35/635 ,  B01J35/638 ,  B01J35/695 ,  B01J37/0018 ,  B01J37/10 ,  C07C1/24 ,  C07C2521/06 ,  C07C2521/08 ,  C07C2523/06

Abstract: A catalyst according to an embodiment is a catalyst for synthesizing 1,3 -butadiene from ethanol. The catalyst contains a porous silica support made of crystalline silica, Zn, and Zr, and has a multimodal pore size distribution with a peak pore size (Dmicro) of 2 in or less and a peak pore size (Dmeso+macro) of more than 2 nm.

公开(公告)号：US11994345B2

公开(公告)日：2024-05-28

申请号：US17803671

申请日：2022-10-04

Applicant: GREYROCK TECHNOLOGY, LLC

Inventor： Robert Schuetzle ,  Dennis Schuetzle

IPC: F27D3/00 ,  B01J23/755 ,  B01J35/31 ,  B01J35/63 ,  B01J35/64 ,  B01J35/66 ,  B01J37/08 ,  F27D3/16 ,  F27D5/00 ,  F27D9/00 ,  F27D19/00

CPC classification number: F27D3/0033 ,  B01J23/755 ,  B01J35/31 ,  B01J35/63 ,  B01J35/64 ,  B01J35/66 ,  B01J37/08 ,  F27D5/0068 ,  F27D2003/0034 ,  F27D2003/166 ,  F27D2009/0002 ,  F27D2019/0056 ,  F27D2019/0093

Abstract: The present invention describes an improved process for the commercial scale production of high-quality catalyst materials. These improved processes allow for production of catalysts that have very consistent batch to batch property and performance variations. In addition these improved processes allow for minimal production losses (by dramatically reducing the production of fines or small materials as part of the production process). The improved process involves multiple steps and uses calcining ovens that allow for precisely control temperature increases where the catalyst is homogenously heated. The calcining gas is released into a separate heating chamber, which contains the recirculation fan and the heat source. Catalysts that may be produced using this improved process include but are not limited to catalysts that promote CO hydrogenation, reforming catalysts, Fischer Tropsch Catalysts, Greyrock GreyCat™ catalysts, catalysts that homologate methanol, catalysts that promote hydrogenation of carbon compounds, and other catalysts used in industry.

公开(公告)号：US12152518B2

公开(公告)日：2024-11-26

申请号：US17599540

申请日：2019-03-29

Applicant: HONDA MOTOR CO., LTD.

Inventor： Chiaki Seki ,  Yusuke Imai ,  Atsushi Furukawa ,  Yuichi Matsuo ,  Naohiro Sato

IPC: F01N3/035 ,  B01D46/00 ,  B01D53/94 ,  B01J21/08 ,  B01J23/10 ,  B01J23/46 ,  B01J35/56 ,  B01J35/66 ,  F01N3/02 ,  F01N3/022 ,  F01N3/10 ,  B01D46/24

Abstract: The present invention provides an exhaust purification filter with which pressure loss can be reduced, the filter having high exhaust purification performance and granular-substance-filtering performance. The exhaust purification filter comprises a filter base material having a wall flow structure, and an exhaust purification catalyst supported on a dividing wall of the filter base material, the exhaust purification filter being such that: a median pore diameter (D50) of the filter base material according to a volumetric basis is 15 μm or greater; and the exhaust purification catalyst is unevenly supported on a high-density layer, in which the density of the exhaust purification catalyst is relatively high, and a low-density layer, in which the density of the exhaust purification catalyst is relatively low.

公开(公告)号：US12121881B2

公开(公告)日：2024-10-22

申请号：US17285799

申请日：2019-09-19

Applicant: BASF SE

Inventor： Andrey Karpov ,  Marco Oskar Kennema ,  Nicolas Duyckaerts ,  Christian Walsdorff ,  Christian Bartosch ,  Juergen Zuehlke ,  Miguel Angel Romero Valle

IPC: B01J23/68 ,  B01J21/04 ,  B01J35/40 ,  B01J35/56 ,  B01J35/61 ,  B01J35/63 ,  B01J35/64 ,  B01J35/66 ,  B01J37/02 ,  B01J37/08 ,  C07D301/04

CPC classification number: B01J23/688 ,  B01J21/04 ,  B01J35/40 ,  B01J35/56 ,  B01J35/612 ,  B01J35/633 ,  B01J35/635 ,  B01J35/651 ,  B01J35/653 ,  B01J35/657 ,  B01J35/695 ,  B01J37/0213 ,  B01J37/082 ,  C07D301/04

Abstract: A shaped catalyst body for producing ethylene oxide by gas-phase oxidation of ethylene, comprising silver deposited on a porous refractory support, the shaped catalyst body having a first face side surface, a second face side surface and a circumferential surface, characterized by a content of at least 20 wt.-% of silver, relative to the total weight of the shaped catalyst body; a multilobe structure; a plurality of passageways extending from the first face side surface to the second face side surface, outer passageways being arranged around a central passageway with one outer passageway being assigned to each lobe, wherein neighboring outer passageways are arranged essentially equidistantly to each other and the outer passageways are arranged essentially equidistantly to the central passageway; a minimum wall thickness A between two neighboring passageways in the range of 0.6 to 1.3 mm; a minimum wall thickness B between each outer passageway and the circumferential surface in the range of 1.1 to 1.8 mm; and a BET surface area in the range of 1.6 to 3.0 m2/g. The shaped catalyst bodies allow for a favorable balance between mechanical stability, pressure drop and selectivity. The invention also relates to a process for producing ethylene oxide by gas-phase oxidation of ethylene, comprising reacting ethylene and oxygen in the presence of a shaped catalyst body as defined above. The invention further relates to a process for preparing a shaped catalyst body as above, comprising i) impregnating a refractory support having a BET surface area in the range of 1.4 to 2.5 m2/g with a silver impregnation solution; and ii) subjecting the impregnated refractory support to a calcination process; wherein steps i) and ii) are optionally repeated.