PROCESS FOR GAS-PHASE POLYMERIZATION OF OLEFINS

    公开(公告)号:WO2018177701A1

    公开(公告)日:2018-10-04

    申请号:PCT/EP2018/055537

    申请日:2018-03-07

    Abstract: Process for the preparation of heterophasic propylene copolymer compositions (RAH ECO) comprising a random propylene copolymer (RACO) and an elastomeric propylene copolymer (BlPO), the process being carried out in a reactor having two interconnected polymerization zones, a riser and a down- comer, wherein the growing polymer particles: (a) flow through the first of said polymerization zones, the riser, under fast fluidization conditions in the presence of propylene and of ethylene and/or an alpha-olefin having from 4 to 10 carbon atoms, thus obtaining the random propylene copolymer (RACO); (b) leave the riser and enter the second of said polymerization zones, the downcomer, through which they flow downward in a densified form in the presence of propylene and of ethylene and/or an alpha-olefin having from 4 to 10 carbon atoms, wherein the concentration of ethylene and/or of the alpha-olefin in the downcomer is higher than in the riser, thus obtaining the elastomeric propylene copolymer (Bl PO); (c) leave the downcomer and are reintroduced into the riser, thus establishing a circulation of polymer between the riser and the downcomer.

    PROPYLENE BASED POLYMER COMPOSITION
    4.
    发明申请
    PROPYLENE BASED POLYMER COMPOSITION 审中-公开
    丙烯基聚合物组合物

    公开(公告)号:WO2017097579A1

    公开(公告)日:2017-06-15

    申请号:PCT/EP2016/078417

    申请日:2016-11-22

    Abstract: A propylene polymer composition comprising: a) from 40 wt% to 80 wt% of a propylene 1-hexene copolymer containing from 5.5 to 9.0% by weight, of 1-hexene derived units having a Melt Flow Rate (MFR, measured according to ASTM D 1238, 230°C/2.16 kg, i.e. at 230°C, with a load of 2.16 kg) from 3.5 to 12.0 g/10 min; b) from 20 wt% to 60 wt% of a propylene ethylene copolymer containing from 1.5 wt% to 6.5 wt% of ethylene derived units, a having a Melt Flow Rate (MFR, measured according to ASTM D 1238, 230°C/2.16 kg, i.e. at 230°C, with a load of 2.16 kg) from 3.5 to 12.0 g/10 min.

    Abstract translation: 丙烯聚合物组合物,其包含:a)40重量%至80重量%的含5.5至9.0重量%的1-己烯衍生单元的丙烯1-己烯共聚物,所述单元具有熔体流动 速率(MFR,根据ASTM D 1238,230℃/ 2.16kg,即在230℃,2.16kg的负荷下测量)为3.5-12.0g / 10min; b)20重量%至60重量%的含有1.5重量%至6.5重量%的乙烯衍生单元的丙烯乙烯共聚物,其熔体流动速率(MFR,根据ASTM D 1238,230℃/ 2.16 kg,即在230℃,2.16kg的负载下)为3.5-12.0g / 10min。

    PROPYLENE-BASED POLYMER COMPOSITION
    6.
    发明申请
    PROPYLENE-BASED POLYMER COMPOSITION 审中-公开
    基于丙烯的聚合物组合物

    公开(公告)号:WO2015180916A1

    公开(公告)日:2015-12-03

    申请号:PCT/EP2015/059239

    申请日:2015-04-28

    Abstract: A propylene polymer composition comprising: A) from 81 wt% to 91 wt% of a propylene ethylene copolymer containing from 1.0 wt% to 3.5 wt% of ethylene derived units having a fraction soluble in xylene at 25°C comprised between 10 wt% and 3 wt%; and a melt flow rate ranging from 5 to 50 g/10 min; B) from 9 wt% to 19 wt%, of a copolymer of propylene and ethylene with from 21.0 wt% to 31.0 wt% of ethylene derived units; the sum A) + B) being 100; the composition having an melt flow rate ranging from 20 to 35 g/10 min; the xylene soluble fraction at 25°C ranging from 13.0 wt% to 25.0 wt% and the intrinsic viscosity of the fraction soluble in xylene at 25°C ranging from 0.7 dl/g to 1.9 dl/g.

    Abstract translation: 丙烯聚合物组合物,其包含:A)81重量%至91重量%的含有1.0重量%至3.5重量%的在25℃下可溶于二甲苯的馏分的乙烯衍生单元的丙烯乙烯共聚物包含10重量%至 3重量% 熔体流动速率为5〜50g / 10min; B)为9重量%至19重量%的丙烯与乙烯共聚物与21.0重量%至31.0重量%的乙烯衍生单元; 总和A)+ B)为100; 所述组合物的熔体流动速率为20至35g / 10min; 25℃下的二甲苯可溶成分为13.0重量%〜25.0重量%,25℃下可溶于二甲苯的馏分的特性粘度为0.7dl / g〜1.9dl / g。

    MINERAL FILLED POLYPROPYLENE COMPOSITION
    7.
    发明申请
    MINERAL FILLED POLYPROPYLENE COMPOSITION 审中-公开
    矿物填充聚丙烯组合物

    公开(公告)号:WO2015091372A1

    公开(公告)日:2015-06-25

    申请号:PCT/EP2014/077790

    申请日:2014-12-15

    Abstract: A polypropylene composition for the production of molded articles, such as finished parts for the automotive industry, has melt flow rate (230°C, 2.16 Kg) of at least 25 g /10 min and comprises: (A) 50-95% of a composition having an intrinsic viscosity of the fraction soluble in xylene at 25 °C of 3.0-5.0 dl/g and comprising: (Al) 70-95% of a propylene homopolymer having a Polydispersity Index (PI) of 4.3-10, a fraction insoluble in xylene at 25 °C higher than 90% and a MFR (230°C, 2.16 Kg) of 100- 250 g/10 min; (A2) 5-30% of a copolymer of propylene with 36-44% of ethylene-derived units; (B) optionally up to 45% of a heterophasic propylene polymer, having MFR (230°C, 2.16 Kg) of 10-25 g/10 min, flexural modulus higher than 1400 MPa, and comprising 5-20% of a copolymer rubber component and 80-95% of a matrix propylene polymer component; (C) 2-10% of an ethylene based elastoplastic copolymer; and (D) optionally up to 20% of talc.

    Abstract translation: 用于生产模制品的聚丙烯组合物,例如用于汽车工业的成品,其熔体流动速率(230℃,2.16Kg)为至少25g / 10min,包括:(A)50-95% 在25℃下可溶于二甲苯的馏分的特性粘度为3.0-5.0dl / g的组合物,其组成为:(Al)70-95%的多分散指数(PI)为4.3-10的丙烯均聚物, 在25℃下不溶于二甲苯的馏分高于90%,MFR(230℃,2.16Kg)为100-250g / 10min; (A2)5-30%丙烯与36-44%乙烯衍生单元的共聚物; (B)任选多达45%的多相丙烯聚合物,MFR(230℃,2.16Kg)为10-25g / 10min,弯曲模量高于1400MPa,并且包含5-20%的共聚物橡胶 组分和80-95%的基质丙烯聚合物组分; (C)2-10%的乙烯基弹性共聚物; 和(D)任选地最多20%的滑石。

    PROPYLENE BASED TERPOLYMER FOR CONTAINERS
    9.
    发明申请
    PROPYLENE BASED TERPOLYMER FOR CONTAINERS 审中-公开
    用于容器的基于丙烯的三元共聚物

    公开(公告)号:WO2014195073A1

    公开(公告)日:2014-12-11

    申请号:PCT/EP2014/059198

    申请日:2014-05-06

    CPC classification number: C08F210/06 C08F2500/12 C08F210/16 C08F210/14

    Abstract: A container comprising a propylene, ethylene, 1-hexene terpolymer wherein in the terpolymer: (i) the content of ethylene derived units ranges from 0.5 wt% to 2.0 wt%; (ii) the content of 1-hexene derived units ranges from 1.5 wt% to 5.5 wt%; (iii) the content of ethylene derived units fulfills the following equation (I); C2

    Abstract translation: 一种包含丙烯,乙烯,1-己烯三元共聚物的容器,其中在三元共聚物中:(i)乙烯衍生单元的含量为0.5wt%至2.0wt%; (ii)1-己烯衍生单元的含量为1.5重量%〜5.5重量%。 (iii)乙烯衍生单元的含量满足下式(I); C2

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