Abstract:
A propylene ethylene copolymer having: (i) an ethylene derived units content ranging from 2.0 wt% to 11.0 wt%; (ii) ) the fraction soluble in xylene at 25°C (Xs) ranging from 7.1 wt% to 28.5 wt%; (iii) the intrinsic viscosity of the fraction soluble in xylene at 25°C ranges from 3.2 dl/g to 5.6 dl/g; (iv) the melting point is higher than 140.0 °C and fulfils the following relation (I): Tm>155-1.4xC2 (I) (v) the flexural modulus is higher than 500MPa and fulfils the following relation (II) TM> 1900 - 285xC2+50xXs (II).
Abstract:
Process for the preparation of heterophasic propylene copolymer compositions (RAH ECO) comprising a random propylene copolymer (RACO) and an elastomeric propylene copolymer (BlPO), the process being carried out in a reactor having two interconnected polymerization zones, a riser and a down- comer, wherein the growing polymer particles: (a) flow through the first of said polymerization zones, the riser, under fast fluidization conditions in the presence of propylene and of ethylene and/or an alpha-olefin having from 4 to 10 carbon atoms, thus obtaining the random propylene copolymer (RACO); (b) leave the riser and enter the second of said polymerization zones, the downcomer, through which they flow downward in a densified form in the presence of propylene and of ethylene and/or an alpha-olefin having from 4 to 10 carbon atoms, wherein the concentration of ethylene and/or of the alpha-olefin in the downcomer is higher than in the riser, thus obtaining the elastomeric propylene copolymer (Bl PO); (c) leave the downcomer and are reintroduced into the riser, thus establishing a circulation of polymer between the riser and the downcomer.
Abstract:
Halogenated alcohols used in gas phase polymerization of ethylene in combination with a Ti based catalyst component and aluminum alkyls as co-catalyst allows to efficiently suppress ethane formation and to simultaneously increase the polymerization activity.
Abstract:
A process for the gas-phase polymerization of α-olefms carried out in two interconnected polymerization zones, wherein the growing polymer particles flow through the first of said polymerization zones (riser) under fast fluidization conditions, leave said riser and enter the second of said polymerization zones (downcomer) through which they flow downward in a densified form, the process being characterized in that: (a) the gas mixture present in the riser is totally or partially prevented from entering the downcomer by introducing into the upper part of said downcomer a liquid stream LB having a composition different from the gaseous mixture present in the riser; (b) the ratio R between the flow rate F p of polymer circulated between said downcomer and said riser and the flow rate LB of said liquid being adjusted in a range from 10 to 50.
Abstract:
A process for the preparation of polyolefins carried out in the presence of an antistatic composition comprising: a) a compound of formula R-OH wherein R represents hydrogen or a linear or branched, saturated alkyl group having from 1 to 15 carbon atoms; and b) an oligomeric or polymeric organic compound having one or more terminal hydroxyl groups and a viscosity at 40 °C of at least 20 mm 2 /sec (DIN 51562).
Abstract:
A catalyst system for the (co)polymerization of olefins, comprising (A) a solid catalyst component comprising a titanium compound supported on magnesium dichloride (B) an aluminum alkyl compound and (C) an halogenated organic ester of formula A-COOR in which R is a C 1 C 10 hydrocarbon group and A is a C 1 C 5 saturated or unsaturated hydrocarbon group in which at least one of the hydrogen atoms is replaced by chlorine. Said catalyst systems has improved polymerization activity and reduced ethane generation.
Abstract:
Feeding a supported antistatic compound that does not comprise a transition- metal-based catalyst component to an olefin polymerization reactor allows avoiding the formation of polymer agglomerates in the reactor while at the same time minimizing negative effects on catalyst yield.
Abstract:
A process for the gas-phase polymerization of α-olefÊns CH 2 =CHR, where R is hydrogen or a hydrocarbon radical having 1-12 carbon atoms, carried out in a first and a second interconnected polymerization zones, wherein the growing polymer particles flow through the first of said polymerization zones (riser) under fast fluidization conditions, leave said riser and enter the second of said polymerization zones (downcomer) through which they flow downward in a densified form, leave said downcomer and are reintroduced into said riser, in which process: (a) the gas mixture present in the riser is totally or partially prevented from entering the downcomer, and (b) the gaseous composition inside a portion of the downcomer is maintained substantially similar to the gaseous composition reacting in the riser.
Abstract translation:其中R是氢或具有1-12个碳原子的烃基的α-烯烃CH 2 R 2 = CHR的气相聚合方法是在第一和第二互连聚合区 ,其中生长的聚合物颗粒在快速流化条件下流过第一个所述聚合区(提升管),离开所述提升管并进入其中以致密化形式向下流动的所述聚合区(降液管)中的第二个,离开所述降液管和 重新引入所述提升管中,在该过程中:(a)存在于提升管中的气体混合物完全或部分地被阻止进入降液管,并且(b)降液管的一部分内的气态组合物保持基本上类似于气体 组合物在提升管中反应。
Abstract:
A process for the preparation of ethylene polymers comprising polymerizing ethylene, optionally with one or more α-olefin comonomers, in the presence of: (i) a solid catalyst component comprising titanium, magnesium, halogen and optionally an internal electron-donor compound, (ii) an aluminum alkyl compound, and (iii) an antistatic compound selected among the hydroxyesters with at least two free hydroxyl groups, wherein the weight ratio of aluminum alkyl compound to solid catalyst component is higher than 0.80 and the weight ratio of antistatic compound to aluminum alkyl compound is higher than 0.10.
Abstract:
A process for introducing a catalyst powder based on a titanium compound supported on magnesium halide into a gas-phase olefin polymerization reactor, characterized in that it comprises: (a) storing the catalyst powder under an atmosphere of a liquid C 3 -C 12 alkane; (b) withdrawing from step (a) a measured amount of said catalyst powder by means of a rotary valve; (c) transferring said metered amount of catalyst powder to a catalyst activation section by a continuous pick-up flow of a liquid C 3 -C 12 alkane; (d) contacting the catalyst powder with a liquid phase comprising an organo-aluminum compound and optionally an external donor compound, at a temperature ranging from -20 °C to 60 °C; (e) introducing the activated catalyst powder in one or more gas-phase olefin polymerization reactors, where a gaseous mixture comprising at least one alpha-olefin is subjected to polymerization.