Abstract:
The invention relates to a method for applying integrated pre-treatment layers with a thickness of between 1 and 25 µm to metallic surfaces, especially the surfaces of strip metals, by treatment with a composition containing at least one binding agent, a cross-linking agent, a fine-particle inorganic filler, and a dicarboxylic acid olefin copolymer. The invention also relates to metallic moulded bodies provided with one such integrated pre-treatment layer, and a formulation for carrying out the method.
Abstract:
Disclosed is a method for applying corrosion-resistant layers, especially integrated pretreatment layers or layers for atmospheric corrosion protection, to metallic surfaces. In said method, copolymers are used which contain monomers comprising 20 to 70 percent by weight of nitrogen heterocyles, monomers comprising 10 to 50 percent of acidic groups, 10 to 50 percent by weight of vinyl aromatic monomers, and 0 to 25 percent by weight of other optional monomers as monomeric constitutional units. Also disclosed are copolymers having said composition as well as preparations for applying corrosion-resistant layers.
Abstract:
The present invention relates to a process for applying integrated pretreatment layers having a thickness of 1 to 25 mum to metallic surfaces, particularly the surfaces of coil metals, by treatment with a composition comprising at least one binder, crosslinker, a finely divided inorganic filler, and a dicarboxylic acid-olefin copolymer. It also relates to shaped metallic articles provided with an integrated pretreatment layer of this kind, and to a formulation for implementing the process.
Abstract:
Disclosed is a method for applying corrosion-resistant layers, especially integrated pretreatment layers or layers for atmospheric corrosion protectio n, to metallic surfaces. In said method, copolymers are used which contain monomers comprising 20 to 70 percent by weight of nitrogen heterocyles, monomers comprising 10 to 50 percent of acidic groups, 10 to 50 percent by weight of vinyl aromatic monomers, and 0 to 25 percent by weight of other optional monomers as monomeric constitutional units. Also disclosed are copolymers having said composition as well as preparations for applying corrosion-resistant layers.
Abstract:
The present invention relates to a process for applying integrated pretreatment layers having a thickness of 1 to 25 mum to metallic surfaces, particularly the surfaces of coil metals, by treatment with a composition comprising at least one binder, crosslinker, a finely divided inorganic filler, and a dicarboxylic acid-olefin copolymer. It also relates to shaped metallic articles provided with an integrated pretreatment layer of this kind, and to a formulation for implementing the process.
Abstract:
The present invention relates to a composition for coating metallic surfaces, comprising a binder component; a corrosion inhibitor polymer based on an ethylenically monocarboxylic and dicarboxylic acid and, if appropriate, further ethylenical monomers, a solvent component, and, if appropriate, crosslinkable components, and also pigment/filler components. The invention further relates to processes for its preparation and also to methods of coating a metallic surface using the composition, to coated metallic surfaces thus obtained, and to the use of the composition as a primer, particularly in coil coating or in atmospheric corrosion control. After drying, the applied layer preferably has a thickness of at least 3.1 μm and is therefore thicker than a typical pretreatment layer.
Abstract:
La presente invencion se refiere a un proceso para aplicar capas de pretratamiento integradas que tienen un espesor de 1 a 25 (m sobre superficies metalicas, particularmente superficies de metales en rollo, mediante el tratamiento con una composicion que comprende por lo menos un aglomerante, agente de reticulacion, un rellenador inorganico finamente dividido, y un copolimero de acido dicarboxilico-olefina. Se refiere tambien a articulos metalicos con forma que reciben una capa de pretratamiento integrada de este tipo, y a una formulacion para implementar el proceso.
Abstract:
Method for applying integrated pre-treatment layers with a thickness of 1-25 mu m, comprises applying cross linkable preparation on the metallic surface and thermally- and/or photochemically cross linking the layer, where the preparation contains e.g. corrosion protection agent, which is a copolymer from (a) monoethylenic unsaturated hydrocarbon, (b) 4-8C monoethylenic unsaturated dicarboxylic acid and (c) other ethylenic unsaturated monomers. Method for applying integrated pre-treatment layers with a thickness of 1-25 mu m to metallic surfaces, comprises applying a cross linkable preparation (A) on the metallic surface and thermally- and/or photochemically cross linking the applied layer, where (A) contains at least 20-70 wt.% of at least one thermal and/or photochemical cross linkable binder system, 20-70 wt.% of at least fine particle-inorganic fillers with an average particle size of less than 10 mu m, 0.25-40 wt.% of at least one corrosion protection agent and optionally a solvent, where the corrosion protection agent is at least a copolymer, obtained from (a) 70-30 mol.% of at least a monoethylenic unsaturated hydrocarbon (a1) and/or at least one monomer (monoethylenic unsaturated hydrocarbons modified with functional groups X 1> (a2) and vinylethers (a3)), (b) 30-70 mol.% of at least 4-8C monoethylenic unsaturated dicarboxylic acid, its anhydride and/or derivatives (where the derivatives are esters of dicarboxylic acids with alcohols of formula (HO-R 1>-X 2> n), amides, imides with ammonia and/or amines of formula (HR 2>N-R 1>-X 2> n)) and (c) 0-10 mol.% of other ethylenic unsaturated monomers, which are different from (a) and (b), but are copolymerizable with (a) and (b), where the quantities in each case are referred to the total quantity of all monomer units in the copolymer. R 1>(n+1)-value of 1-40C hydrocarbons, optionally substituted with non-adjacent C-atoms and O and/or N; R 2>H, 1-10C hydrocarbon group or -(R 1>-X 2> n); n : 1-3; and X 2>a functional group. Independent claims are included for: (1) a molded article with a metallic surface, which is coated with an integrated pretreatment layer with a thickness of 1-25 mu m obtained by the above procedure; and (2) a preparation (A) for applying integrated pretreatment layers on metallic surfaces.