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    METHOD FOR PROCESSING A LIQUID HYDROFORMYLATION DISCHARGE
    1.
    发明申请
    METHOD FOR PROCESSING A LIQUID HYDROFORMYLATION DISCHARGE 审中-公开
    一种用于处理液体的羰基化

    公开(公告)号：WO0158844A3

    公开(公告)日：2002-04-04

    申请号：PCT/EP0101582

    申请日：2001-02-13

    Applicant: BASF AG ,  WALCZUCH KARL HEINZ ,  MUELLER ROLF ,  KROKOSZINSKI ROLAND ,  GEISSLER BERNHARD

    Inventor： WALCZUCH KARL-HEINZ ,  MUELLER ROLF ,  KROKOSZINSKI ROLAND ,  GEISSLER BERNHARD

    IPC: C07B61/00 ,  C07C45/50 ,  C07C47/02

    CPC classification number: C07C45/50 ,  C07C47/02

    Abstract: The invention relates to a method for processing a liquid discharge of a continuous hydroformylation that substantially contains aldehydes, high-boiling by-products, a homogeneously dissolved hydroformylation catalyst, non-reacted olefins, low-boiling by-products and dissolved synthesis gases. According to the inventive method a) the liquid hydroformylation discharge is expanded in a first expansion step to a pressure that is 2 to 20 bar below the reactor pressure, while the discharge is separated into a liquid phase and a gaseous phase; and b) expanding the liquid phase obtained in the first expansion step in a second expansion step to a pressure that is lower than the pressure of the first expansion step, while the liquid phase is separated into a liquid phase that substantially contains the high-boiling by-products of the hydroformylation, the homogeneously dissolved hydroformylation catalyst and small quantities of hydroformylation product and non-reacted olefins, and into a gaseous phase that substantially contains the main quantity of the hydroformylation product, non-reacted olefins and low-boiling by-products.

    Abstract translation: 本发明涉及一种用于后处理的液体的处理Austrages的连续加氢甲酰化基本上醛，高沸点的副产物，一均匀溶解加氢甲酰化催化剂，未反应的烯烃，低沸点副产物，并溶解合成气含有，其特征在于，a）在第一减压阶段的液体加氢甲酰化以 被释放的压力，其为2至20巴反应器压力的下方，其特征在于，分离成液相和气相; 和b）在第一减压步骤中获得的液相在第二减压阶段的压力比所述第一膨胀阶段的压力下，其中，分离成液相基本上是高沸点的副产物的加氢甲酰化的，均匀溶解的加氢甲酰化催化剂进行减压 和少量的加氢甲酰化产物和未反应的烯烃的，并包含在气相，其基本上包含加氢甲酰化产物，未反应的烯烃和低沸点副产物的主要量。

    2.
    发明专利
    未知

    公开(公告)号：AT249411T

    公开(公告)日：2003-09-15

    申请号：AT01911637

    申请日：2001-02-13

    Applicant: BASF AG

    Inventor： WALCZUCH KARL-HEINZ ,  MUELLER ROLF ,  KROKOSZINSKI ROLAND ,  GEISSLER BERNHARD

    IPC: C07B61/00 ,  C07C45/50 ,  C07C47/02

    Abstract: A liquid output from a continuous hydroformylation, which comprises essentially aldehydes, high-boiling by-products, a homogeneously dissolved hydroformylation catalyst, unreacted olefins, low-boiling by-products and dissolved synthesis gas, is worked up by a process in which a) the liquid hydroformylation output is depressurized in a first depressurization stage to a pressure which is from 2 to 20 bar below the reactor pressure, resulting in separation into a liquid phase and a gas phase, and b) the liquid phase obtained in the first depressurization stage is depressurized in a second depressurization stage to a pressure which is lower than the pressure of the first depressurization stage, resulting in separation into a liquid phase comprising essentially high-boiling by-products of the hydroformylation, the homogeneously dissolved hydroformylation catalyst and small amounts of hydroformylation product and unreacted olefin and a gas phase comprising essentially the major part of the hydroformylation product, unreacted olefin and low-boiling by-products.

    Method for processing a liquid hydroformylation discharge
    4.
    发明专利
    Method for processing a liquid hydroformylation discharge 未知

    公开(公告)号：AU4061601A

    公开(公告)日：2001-08-20

    申请号：AU4061601

    申请日：2001-02-13

    Applicant: BASF AG

    Inventor： WALCZUCH KARL-HEINZ ,  MULLER ROLF ,  KROKOSZINSKI ROLAND ,  GEISSLER BERNHARD

    IPC: C07B61/00 ,  C07C45/50 ,  C07C47/02

    Abstract: A liquid output from a continuous hydroformylation, which comprises essentially aldehydes, high-boiling by-products, a homogeneously dissolved hydroformylation catalyst, unreacted olefins, low-boiling by-products and dissolved synthesis gas, is worked up by a process in which a) the liquid hydroformylation output is depressurized in a first depressurization stage to a pressure which is from 2 to 20 bar below the reactor pressure, resulting in separation into a liquid phase and a gas phase, and b) the liquid phase obtained in the first depressurization stage is depressurized in a second depressurization stage to a pressure which is lower than the pressure of the first depressurization stage, resulting in separation into a liquid phase comprising essentially high-boiling by-products of the hydroformylation, the homogeneously dissolved hydroformylation catalyst and small amounts of hydroformylation product and unreacted olefin and a gas phase comprising essentially the major part of the hydroformylation product, unreacted olefin and low-boiling by-products.

    6.
    发明专利
    未知

    公开(公告)号：ES2146082T3

    公开(公告)日：2000-07-16

    申请号：ES97904422

    申请日：1997-02-12

    Applicant: BASF AG

    Inventor： GEISSLER BERNHARD ,  KNEUPER HEINZ-JOSEF ,  ROPER MICHAEL ,  PACIELLO ROCCO ,  OPPENLANDER KNUT ,  GUNTHER WOLFGANG

    IPC: B01J31/40 ,  C07C29/16 ,  C07C45/50 ,  C07C45/80 ,  C07F9/38 ,  C08G73/02

    Abstract: A process for the preparation of aldehydes or aldehydes and alcohols by hydroformylation of olefins containing more than 3 carbon atoms, comprising a hydroformylation stage, in which the olefin is hydroformylated under a pressure of form 50 to 1000 bar and at a temperature of from 50° to 180° C. by means of a rhodium catalyst dissolved in a homogenous reaction medium and a catalyst recovery stage comprising extraction of the rhodium catalyst with an aqueous solution of chelating agent, isolation of alcohols and/or aldehyde from the extracted hydroformylation product steam, precarbonylation of the aqueous rhodium-containing extract in the presence of carbon monoxide, synthesis gas as, or a gas mixture containing carbon monoxide under a pressure of from 50 to 1000 bar and at a temperature of from 50° to 180° C., separation of the effluent of the precarbonylation stage into an organic phase containing the major portion of the rhodium and an aqueous phase containing the chelating agent and recycling of the organic phase to the hydroformylation stage, where the rhodium catalyst is extracted from the effluent of the hydroformylation stage using an aqueous solution of a sulfonic acid group-free, water-soluble polymer capable of chelating rhodium.

    PROCEDIMIENTO PARA LA OBTENCION DE PRTODUCTOS DE HODROFORMILACION DE OLEFINAS CON 2 HASTA 8 ATOMOS DE CARBONO.
    8.
    发明专利
    PROCEDIMIENTO PARA LA OBTENCION DE PRTODUCTOS DE HODROFORMILACION DE OLEFINAS CON 2 HASTA 8 ATOMOS DE CARBONO. 未知

    公开(公告)号：ES2254478T3

    公开(公告)日：2006-06-16

    申请号：ES01967099

    申请日：2001-06-27

    Applicant: BASF AG

    Inventor： RICHTER WOLFGANG ,  KROKOSZINSKI ROLAND ,  MULLER ROLF ,  GEISSLER BERNHARD

    IPC: C07B61/00 ,  C07C45/50 ,  C07C47/02

    Abstract: Procedimiento para la obtención de productos de hidroformilación de olefinas con 2 hasta 8 átomos de carbono, en el que a) se alimenta una materia prima hidrocarbonada en una zona de craqueo/deshidrogenación y se somete a un craqueo térmico y/o catalítico y/o a una deshidrogenación obteniéndose un gas de disociación que contiene olefinas, b) se somete al gas de disociación, o fracciones del mismo, a una separación en, al menos, una corriente hidrocarbonada enriquecida en olefina con i átomos de carbono y, al menos, una corriente hidrocarbonada empobrecida en olefina con i átomos de carbono, c) se alimenta la corriente hidrocarbonada, enriquecida en olefina con i átomos de carbono, con monóxido de carbono e hidrógeno en una zona de hidroformilación y se hace reaccionar en presencia de un catalizador para la hidroformilación, d) se separa, a partir de la descarga procedente de la zona de hidroformilación, una corriente constituida esencialmente por olefina con i átomos de carbono no convertida y por hidrocarburo con i átomos de carbono saturado, e) se recila la corriente constituida esencialmente por olefina con i átomos de carbono no convertida y por el hidrocarburo con i átomos de carbono saturado, al menos en parte hasta la etapa b), significando i un número entero desde 2 hasta 8.

    10.
    发明专利
    未知

    公开(公告)号：DE59703863D1

    公开(公告)日：2001-07-26

    申请号：DE59703863

    申请日：1997-01-28

    Applicant: BASF AG

    Inventor： PACIELLO ROCCO ,  KNEUPER HEINZ-JOSEF ,  GEISSLER BERNHARD ,  ROEPER MICHAEL

    IPC: B01J31/22 ,  B01J31/16 ,  B01J31/18 ,  B01J31/40 ,  C07B61/00 ,  C07C27/22 ,  C07C29/16 ,  C07C31/125 ,  C07C45/50 ,  C07C45/80 ,  C07C47/02 ,  C07D213/38 ,  C07D213/74

    Abstract: PCT No. PCT/EP97/00372 Sec. 371 Date Jul. 15, 1998 Sec. 102(e) Date Jul. 15, 1998 PCT Filed Jan. 28, 1997 PCT Pub. No. WO97/28113 PCT Pub. Date Aug. 7, 1997A process for the preparation of aldehydes or aldehydes and alcohols by hydroformylation of olefins containing more than 3 carbon atoms comprising a hydroformylation stage, in which the olefin is hydroformylated under a pressure of from 50 to 1000 bar and at a temperature of from 50 DEG to 180 DEG C. using a rhodium catalyst that is dissolved in a homogeneous reaction medium and by extraction of the rhodium catalyst, in which a) the hydroformylation is carried out in the presence of a rhodium complex, which exhibits, as ligand, a polydentate, organic nitrogen compound that is free from phosphorus and capable of forming complexes with Group VIII metals, which additionally contains at least one tertiary nitrogen radical that is capable of being protonized by a weak acid, b) the effluent of the hydroformylation stage is subjected to extraction with an aqueous solution of a distillable acid optionally following separation or partial separation of aldehydes and alcohols, (c) the aqueous acid extract is subjected to thermal treatment in the presence of an organic solvent or solvent mixture, which is inert under the hydroformylation conditions, with distillation of the aqueous acid, by means of which treatment the complex is deprotonized and transferred to the organic phase, and (d) the organic phase containing the catalyst complex is recycled to the hydroformylation stage.

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