公开(公告)号：AU2003215639A8

公开(公告)日：2003-09-22

申请号：AU2003215639

申请日：2003-03-07

Applicant: BASF AG

Inventor： HULLMANN MICHAEL ,  ISELBORN STEFAN ,  GERLACH TILL ,  FUNKE FRANK ,  RUDLOFF MARTIN ,  MELDER JOHANN-PETER

IPC: C07D295/02 ,  B01J23/70 ,  B01J23/755 ,  B01J23/78 ,  B01J37/03 ,  B01J37/06 ,  C07B61/00 ,  C07C209/16 ,  C07C209/26 ,  C07C209/60 ,  C07C211/03 ,  C07C211/07 ,  C07C213/02 ,  C07C217/08 ,  C07D295/023

Abstract: Disclosed are catalysts, the catalytically active mass of which contains 22 to 40 percent by weight of oxygen-containing compounds of zirconium, calculated as ZrO 2 , 1 to 30 percent by weight of oxygen-containing compounds of copper, calculated as CuO, 15 to 50 percent by weight of oxygen-containing compounds of nickel, calculated as NiO, the molar ratio between nickel and copper being greater than 1, 15 to 50 percent by weight of oxygen-containing compounds of cobalt, calculated as CoO, and less than 1 percent by weight of an alkali metal, calculated as alkali metal oxide, prior to being treated with hydrogen. Also disclosed is a method for the production of amines by reacting primary and secondary alcohols, aldehydes, or ketones with hydrogen and nitrogen compounds selected from the group ammonia, primary and secondary amines, in the presence of said catalysts at an elevated temperature and an elevated pressure.

公开(公告)号：CA2478858A1

公开(公告)日：2003-09-18

申请号：CA2478858

申请日：2003-03-07

Applicant: BASF AG

Inventor： GERLACH TILL ,  FUNKE FRANK ,  ISELBORN STEFAN ,  HUELLMANN MICHAEL ,  MELDER JOHANN-PETER ,  RUDLOFF MARTIN

IPC: C07D295/02 ,  B01J23/70 ,  B01J23/755 ,  B01J23/78 ,  B01J37/03 ,  B01J37/06 ,  C07B61/00 ,  C07C209/16 ,  C07C209/26 ,  C07C209/60 ,  C07C211/03 ,  C07C211/07 ,  C07C213/02 ,  C07C217/08 ,  C07D295/023

Abstract: Disclosed are catalysts, the catalytically active mass of which contains 22 to 40 percent by weight of oxygen-containing compounds of zirconium, calculated as ZrO2, 1 to 30 percent by weight of oxygen-containing compounds of copper, calculated as CuO, 15 to 50 percent by weight of oxygen-containing compounds of nickel, calculated as NiO, the molar ratio between nickel and copper bein g greater than 1, 15 to 50 percent by weight of oxygen-containing compounds of cobalt, calculated as CoO, and less than 1 percent by weight of an alkali metal, calculated as alkali metal oxide, prior to being treated with hydroge n. Also disclosed is a method for the production of amines by reacting primary and secondary alcohols, aldehydes, or ketones with hydrogen and nitrogen compounds selected from the group ammonia, primary and secondary amines, in the presence of said catalysts at an elevated temperature and an elevated pressure.

公开(公告)号：CA2478858C

公开(公告)日：2010-12-14

申请号：CA2478858

申请日：2003-03-07

Applicant: BASF AG

Inventor： GERLACH TILL ,  FUNKE FRANK ,  MELDER JOHANN-PETER ,  ISELBORN STEFAN ,  RUDLOFF MARTIN ,  HUELLMANN MICHAEL

IPC: B01J23/755 ,  C07D295/02 ,  B01J23/70 ,  B01J23/78 ,  B01J37/03 ,  B01J37/06 ,  C07B61/00 ,  C07C209/16 ,  C07C209/26 ,  C07C209/60 ,  C07C211/03 ,  C07C211/07 ,  C07C213/02 ,  C07C217/08 ,  C07D295/023

Abstract: Disclosed are catalysts, the catalytically active mass of which contains 22 to 40 percent by weight of oxygen-containing compounds of zirconium, calculated as ZrO2, 1 to 30 percent by weight of oxygen-containing compounds of copper, calculated as CuO, 15 to 50 percent by weight of oxygen-containing compounds of nickel, calculated as NiO, the molar ratio between nickel and copper being greater than 1, 15 to 50 percent by weight of oxygen-containing compounds of cobalt, calculated as CoO, and less than 1 percent by weight of an alkali metal, calculated as alkali metal oxide, prior to being treated with hydrogen. Also disclosed is a method for the production of amines by reacting primary and secondary alcohols, aldehydes, or ketones with hydrogen and nitrogen compounds selected from the group ammonia, primary and secondary amines, in the presence of said catalysts at an elevated temperature and an elevated pressure.

公开(公告)号：CA2691642A1

公开(公告)日：2008-12-24

申请号：CA2691642

申请日：2008-06-20

Applicant: BASF AG

Inventor： ISELBORN STEFAN ,  GEIER REINER ,  HEPFER BENJAMIN ,  BECHTEL MARCUS ,  WILLE MICHAEL ,  DAISS ANDREAS

IPC: B01J8/00 ,  B01D3/00 ,  B01J8/02 ,  C10G49/00

Abstract: The invention relates to a reactor (R) for performing a three-phase react ion of a fluid phase (1) and a gaseous phase (2) on a packed bed catalyst (F ), the packed bed catalyst (F) being disposed horizontally in the reactor (R ) and the fluid phase (1) and the gaseous phase (2) being fed through the re actor (R) from the bottom to the top, using a mixing and distributing device (MV) across the packed bed catalyst (F), characterized in that the mixing a nd distributing device (MV) comprises a trough distributor (TV) for the flui d phase (1) having trough-shaped channels (K) and drain tubes (A) in the tro ugh-shaped channels (K) for the fluid phase (1), and a distributor floor (B) disposed below and at a distance from the trough distributor (TV) in which vertical spouts (T) are disposed, having one or more openings (P1) for the i nlet of the gaseous phase (2) and one or more openings (P2) disposed below t he openings (P1) for the inlet of the gaseous phase, for the inlet of the fl uid phase (1) into the spouts (T), and the number and size of the openings ( P2) for the inlet of the fluid phase (1) being designed such that the fluid level on the distribution floor (B) is adjusted to be below the openings (P1 ) for the inlet of the gaseous phase (2) and above the openings (P2) for the inlet of the fluid phase (1) for a prescribedinlet flow of fluid.

公开(公告)号：AU2003215639A1

公开(公告)日：2003-09-22

申请号：AU2003215639

申请日：2003-03-07

Applicant: BASF AG

Inventor： FUNKE FRANK ,  MELDER JOHANN-PETER ,  ISELBORN STEFAN ,  RUDLOFF MARTIN ,  HULLMANN MICHAEL ,  GERLACH TILL

IPC: C07D295/02 ,  B01J23/70 ,  B01J23/755 ,  B01J23/78 ,  B01J37/03 ,  B01J37/06 ,  C07B61/00 ,  C07C209/16 ,  C07C209/26 ,  C07C209/60 ,  C07C211/03 ,  C07C211/07 ,  C07C213/02 ,  C07C217/08 ,  C07D295/023 ,  C07C209/00

Abstract: Disclosed are catalysts, the catalytically active mass of which contains 22 to 40 percent by weight of oxygen-containing compounds of zirconium, calculated as ZrO 2 , 1 to 30 percent by weight of oxygen-containing compounds of copper, calculated as CuO, 15 to 50 percent by weight of oxygen-containing compounds of nickel, calculated as NiO, the molar ratio between nickel and copper being greater than 1, 15 to 50 percent by weight of oxygen-containing compounds of cobalt, calculated as CoO, and less than 1 percent by weight of an alkali metal, calculated as alkali metal oxide, prior to being treated with hydrogen. Also disclosed is a method for the production of amines by reacting primary and secondary alcohols, aldehydes, or ketones with hydrogen and nitrogen compounds selected from the group ammonia, primary and secondary amines, in the presence of said catalysts at an elevated temperature and an elevated pressure.

公开(公告)号：DE10211101A1

公开(公告)日：2003-09-25

申请号：DE10211101

申请日：2002-03-14

Applicant: BASF AG

Inventor： FUNKE FRANK ,  MELDER JOHANN-PETER ,  ISELBORN STEFAN ,  RUDLOFF MARTIN ,  HUELLMANN MICHAEL ,  GERLACH TILL

IPC: C07D295/02 ,  B01J23/70 ,  B01J23/755 ,  B01J23/78 ,  B01J37/03 ,  B01J37/06 ,  C07B61/00 ,  C07C209/16 ,  C07C209/26 ,  C07C209/60 ,  C07C211/03 ,  C07C211/07 ,  C07C213/02 ,  C07C217/08 ,  C07D295/023 ,  C07B43/04 ,  C07C209/24 ,  C07C213/00 ,  C08F8/32 ,  C08F10/10

Abstract: Disclosed are catalysts, the catalytically active mass of which contains 22 to 40 percent by weight of oxygen-containing compounds of zirconium, calculated as ZrO 2 , 1 to 30 percent by weight of oxygen-containing compounds of copper, calculated as CuO, 15 to 50 percent by weight of oxygen-containing compounds of nickel, calculated as NiO, the molar ratio between nickel and copper being greater than 1, 15 to 50 percent by weight of oxygen-containing compounds of cobalt, calculated as CoO, and less than 1 percent by weight of an alkali metal, calculated as alkali metal oxide, prior to being treated with hydrogen. Also disclosed is a method for the production of amines by reacting primary and secondary alcohols, aldehydes, or ketones with hydrogen and nitrogen compounds selected from the group ammonia, primary and secondary amines, in the presence of said catalysts at an elevated temperature and an elevated pressure.