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    H-förmige Polyamide
    1.
    发明公开
    H-förmige Polyamide 失效
    H-förmige聚酰胺

    公开(公告)号：EP0850974A1

    公开(公告)日：1998-07-01

    申请号：EP97122686

    申请日：1997-12-22

    Applicant: BASF AG

    Inventor： GLUECK ALEXANDER DR ,  GOETZ WALTER DR ,  GRUTKE STEFAN DR ,  LAUN MARTIN DR ,  WARZELHAN VOLKER DR

    IPC: C08G69/36 ,  C08G69/08 ,  C08G69/14

    CPC classification number: C08G69/36

    Abstract: Polyamide werden aufgebaut aus Lactamen, Aminocarbonsäuren oder deren Gemischen als Grundbausteine (a), 1 bis 50 µmol/g Polyamid an mindestens trifunktionellen Aminen oder Carbonsäuren als Grundbausteine (b), difunktionellen Carbonsäuren oder Aminen als Grundbausteine (c) und monofunktionellen Carbonsäuren oder Aminen als Grundbausteine (d), wobei (c) und (d) Carbonsäuren sind, wenn (b) Amine sind und (c) und (d) Amine sind, wenn (b) Carbonsäuren sind, das Äquivalentverhältnis der funktionellen Gruppen von (b) zu den fünktionellen Gruppen von (c) und (d) zusammen 60:40 bis 40:60 beträgt und das Äquivalentverhältnis der funktionellen Gruppen von (c) zu den funktionellen Gruppen von (d) 15:85 bis 60:40 beträgt.

    Abstract translation: 聚酰胺（I）包含：（A）内酰胺和/或氨基羧酸（B）1-50微摩尔/ g（I）至少三官能胺或羧酸（C）双官能羧酸或胺（D） 单官能羧酸或胺。 当（B）是胺时，（C）和（D）是羧酸，当（B）是羧酸时，（C）和（D）是胺。 （B）与（C）和（D）的当量比为60:40 - 40:60。 （C）与（D）的当量比为15:85〜60:40。 还要求的是：（i）通过在250-300℃和1-40巴下在蒸汽存在下混合（A），（B）和（C）来制备（I）的方法。 （ii）包含（I）（iii）成型体和（II）制成的纤维的成型组合物（II）和（iv）通过（II）的注射成型，挤出或吹塑成型制造模制品的方法， 用于通过纺丝（II）生产纤维。

    2.
    发明专利
    未知

    公开(公告)号：DE19543161A1

    公开(公告)日：1997-05-22

    申请号：DE19543161

    申请日：1995-11-18

    Applicant: BASF AG

    Inventor： FISCH HERBERT DR ,  PIPPER GUNTER ,  RIEGER JENS DR ,  LAUN MARTIN DR ,  WARZELHAN VOLKER DR

    IPC: C08G69/48 ,  C08G69/04 ,  C08G69/28 ,  C08G69/46 ,  C08G69/06

    Abstract: The production of branched polyamides (I) comprises: (i) mixing (A) 10-99.7 wt% molten polyamide prepolymer with a viscosity number (VN) of 40-90 ml/g with (B) 0.3-6 wt% poly- carboxylic acid with 3-10 free COOH groups and (C) 0-80 wt% other additives and processing aids; followed by (ii) solid-phase post- condensation. Also claimed are thermoplastic moulding materials obtained by this process. Preferably after solid-phase post-condensation, the polyamide has a VN of at least 100 ml/g. Component (B) contains 3 or 4 free COOH groups; preferred (B) is benzene-1,3,5- tricarboxylic or -1,2,4,5-tetracarboxylic acid, biphenyl- -3,5,3',5'-tetracarboxylic acid and/or naphthalene-1,3,5,7- tetracarboxylic acid. The amount of (B) used is 0.4-5.8 wt%. Component (A) consists of polyamide (PA) 66, PA 6/6T and/or PA 66/6T.

    7.
    发明专利
    未知

    公开(公告)号：ES2057260T3

    公开(公告)日：1994-10-16

    申请号：ES90109438

    申请日：1990-05-18

    Applicant: BASF AG

    Inventor： SCHMIDT FRANZ DR ,  BUNG RICHARD DR ,  LAUN MARTIN DR ,  LOUIS GERD DR

    IPC: C08F2/22 ,  C08F2/20 ,  C08F20/22 ,  C08F218/16 ,  C08F220/04 ,  C08F220/40 ,  C08F246/00

    Abstract: Highly dilatant copolymer dispersions which contain, as essential components, an emulsion copolymer prepared from 1 to 10% by weight, based on the total amount of monomers employed, of alpha , beta - monoolefinically unsaturated carboxylic acids and other olefinically unsaturated monomers are characterised in that the emulsion copolymer is prepared in the presence of from 5 to 30% by weight, based on the total amount of monomers employed, of an allyl or alkylallyl carboxylate containing 2 or more copolymerisable, olefinic double bonds, or a mixture thereof, where the alkyl radical contains 1 to 4 carbon atoms.

    8.
    发明专利
    未知

    公开(公告)号：DE59006816D1

    公开(公告)日：1994-09-22

    申请号：DE59006816

    申请日：1990-05-18

    Applicant: BASF AG

    Inventor： SCHMIDT FRANZ DR ,  BUNG RICHARD DR ,  LAUN MARTIN DR ,  LOUIS GERD DR

    IPC: C08F2/22 ,  C08F2/20 ,  C08F20/22 ,  C08F218/16 ,  C08F220/04 ,  C08F220/40 ,  C08F246/00

    Abstract: Highly dilatant copolymer dispersions which contain, as essential components, an emulsion copolymer prepared from 1 to 10% by weight, based on the total amount of monomers employed, of alpha , beta - monoolefinically unsaturated carboxylic acids and other olefinically unsaturated monomers are characterised in that the emulsion copolymer is prepared in the presence of from 5 to 30% by weight, based on the total amount of monomers employed, of an allyl or alkylallyl carboxylate containing 2 or more copolymerisable, olefinic double bonds, or a mixture thereof, where the alkyl radical contains 1 to 4 carbon atoms.

    Thermoplastics moulding compsn. - contains polyester of specified viscosity and polyamide of specified viscosity having improved flowability properties
    9.
    发明专利
    Thermoplastics moulding compsn. - contains polyester of specified viscosity and polyamide of specified viscosity having improved flowability properties 未知

    公开(公告)号：DE4133515A1

    公开(公告)日：1993-04-15

    申请号：DE4133515

    申请日：1991-10-10

    Applicant: BASF AG

    Inventor： BRIGHT THERESA ANNE DR ,  GOETZ WALTER DR ,  PLACHETTA CHRISTOPH DR ,  LAUN MARTIN DR

    IPC: C08L67/02

    Abstract: Compsns. (I) contain; (A) 40-99.5 % (all pts.wt.) thermoplastic polyester with viscosity no. (DIN 53 726, 0.5% in 1:1 mixt. of phenol and o-dichlorobenzene at 23 deg.C) (VA) 90-300 ml/g; (B) 0.5-10 % low mol. thermoplastic polyamide with viscosity no. (ISO 307, 0.5% in 96% H2SO4 at 25 deg.C) (VA) 30-100 ml/g, where VA-VB is at least 30; (C) 0-50% fibrous or particulate fillers or their mixts., (D) 0-40% rubber-elastic polymer; (E) 0-30% conventional additives. Pref. VA = 100-200 ml/g. VB = 40-80 ml/g. VA-VB is at least 50. (I) contain 50-99% (A) and 1-5% (B). (A) is PET and/or polybutylene terephthalate (II). (B) is polyhexamethylene adipamide (III) and/or polycaprolactam and/or partly aromatic partly crystalline copolyamide. USE/ADVANTAGE - Prepn. of fibres, films, and moulded articles partic. in the motor vehicle industry. (I) have improved flowability compared with compsns. not contg. (B), independently of amt. and type of (E), reduced cycle time, and improved toughness with greater plastic deformation before final break

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