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    6.
    发明专利
    未知

    公开(公告)号：DE19722569A1

    公开(公告)日：1998-12-03

    申请号：DE19722569

    申请日：1997-05-28

    Applicant: BASF AG

    Inventor： KERSTING MEINOLF DR ,  SCHOENE WERNER DR ,  LANGHAUSER FRANZ DR

    IPC: C08F2/34 ,  C08F4/02 ,  C08F4/642 ,  C08F4/654 ,  C08F4/658 ,  C08F10/00 ,  C08F210/06 ,  C08F210/16 ,  C08F210/02

    Abstract: Random copolymers (I) of propylene with ethylene and 4-10 carbon (C) alk-1-ene(s), with a melting point of 135 degrees C (by differential scanning calorimetry (DSC) method), are obtained by polymerising the monomers from the gas phase, in the absence of a liquid reaction medium, at 50-100 degrees C and 15-40 bar in the presence of a Ziegler-Natta catalyst system containing (a) solid component containing titanium (Ti), a halogenated magnesium (Mg) compound, an electron donor and an inorganic oxide as carrier, (b) an aluminium (Al) compound and (c) another electron donor compound. The novelty is that the ratio of the partial pressures is adjusted to (20-100):1 for propylene and ethylene and (2.5-20):1 for 4-10 C alk-1-ene(s) and ethylene. Also claimed are: (i) the production of (I) in this way; and (ii) films, fibres or mouldings containing (I).

    7.
    发明专利
    未知

    公开(公告)号：DE59502797D1

    公开(公告)日：1998-08-20

    申请号：DE59502797

    申请日：1995-04-07

    Applicant: BASF AG

    Inventor： SEILER ERHARD DR ,  SCHOENE WERNER DR

    IPC: C08J5/16 ,  C08J5/18 ,  C08L23/06 ,  C08L23/08 ,  C08L23/10 ,  C08L23/12 ,  C08L23/14

    Abstract: Moulding materials (I) comprise (A) polymers of propylene and ≤ 20 wt.% other monomers, contg. (B) 0.05-0.4 wt.% mono- or poly-basic carboxylic acid amide(s) with a mol. wt. of 150-600 and (C) 0.1-3.0 wt.% ethylene polymer with ≤ 20 wt.% comonomers, with a density of 0.890-0.945 g/cm and a MFI 190/2.16 of 10-100 g/10 mins.. Also claimed are films and mouldings made from (I), such as injection syringes. Pref. (A) is a polypropylene homopolymer or a copolymer of 90-99.9 wt.% propylene and 0.1-10 wt.% ethylene and/or 4-10C alk-1-ene. (B) is 13-docosenoic acid amide (erucamide) and/or 9-octadecenoic acid amide (oleamide), in amts. of 0.08-0.2 wt.%.

    8.
    发明专利
    未知

    公开(公告)号：DE4413058A1

    公开(公告)日：1995-10-19

    申请号：DE4413058

    申请日：1994-04-15

    Applicant: BASF AG

    Inventor： SEILER ERHARD DR ,  SCHOENE WERNER DR

    IPC: C08J5/16 ,  C08J5/18 ,  C08L23/06 ,  C08L23/08 ,  C08L23/10 ,  C08L23/12 ,  C08L23/14 ,  C08L23/04 ,  C08K5/20 ,  A61M5/178

    Abstract: Moulding materials (I) comprise (A) polymers of propylene and ≤ 20 wt.% other monomers, contg. (B) 0.05-0.4 wt.% mono- or poly-basic carboxylic acid amide(s) with a mol. wt. of 150-600 and (C) 0.1-3.0 wt.% ethylene polymer with ≤ 20 wt.% comonomers, with a density of 0.890-0.945 g/cm and a MFI 190/2.16 of 10-100 g/10 mins.. Also claimed are films and mouldings made from (I), such as injection syringes. Pref. (A) is a polypropylene homopolymer or a copolymer of 90-99.9 wt.% propylene and 0.1-10 wt.% ethylene and/or 4-10C alk-1-ene. (B) is 13-docosenoic acid amide (erucamide) and/or 9-octadecenoic acid amide (oleamide), in amts. of 0.08-0.2 wt.%.

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