公开(公告)号：JP2002249453A

公开(公告)日：2002-09-06

申请号：JP2002034464

申请日：2002-02-12

Applicant: BASF AG

Inventor： ZEHNER PETER ,  NILLES MICHAEL

IPC: B01J10/00 ,  B01J19/00 ,  B01J19/24 ,  C07B61/00 ,  C07C45/50 ,  C07C47/02

Abstract: PROBLEM TO BE SOLVED: To provide a method for hydroformylating an olefin having at least 6 carbon atoms that achieves as high conversion as possible for a given reactor volume. SOLUTION: At least one kind of olefin is introduced along with synthesis gas at the lower end of the first reaction chamber and then the reaction mixture reacted in part is introduced to the lower end of the second reaction chamber out of the upper end of the first reaction chamber and then the hydroformylated olefin is taken out at the upper end of the second reaction chamber, using a vertically long cylindrical reactor of which the internal space is divided by a partition into at least two reaction chambers essentially extended to the longitudinal direction of the reactor.

公开(公告)号：ES2121357T3

公开(公告)日：1998-11-16

申请号：ES95912212

申请日：1995-03-06

Applicant: BASF AG

Inventor： KNEUPER HEINZ-JOSEF ,  ARON MAIK ,  KORGITZSCH FRANK-MICHAEL ,  NILLES MICHAEL ,  HARDER WOLFGANG ,  ROPER MICHAEL

IPC: B01J31/40 ,  C07B61/00 ,  C07C27/22 ,  C07C29/141 ,  B01J23/46 ,  C07C29/16 ,  C07C31/02 ,  C07C45/50 ,  C07C45/80 ,  C07C47/02 ,  C07C51/235 ,  C07C209/00

Abstract: PCT No. PCT/EP95/00825 Sec. 371 Date Sep. 13, 1996 Sec. 102(e) Date Sep. 13, 1996 PCT Filed Mar. 6, 1995 PCT Pub. No. WO95/25080 PCT Pub. Date Sep. 21, 1995An industrial preparation of aldehydes and/or alcohols from olefins of more than 3 carbon atoms by a catalytic hydroformylation of the olefin reactant at a pressure of from 50 to 1000 bar and a temperature of from 50 to 180 DEG C. in the presence of an uncomplexed rhodium catalyst homogeneously dissolved in the reaction medium. The catalytic activity of the rhodium is maintained, first by extracting it from the initially discharged reaction mixture by means of an aqueous solution of a nitrogen-containing complexing agent such as sulfonated or carboxylated pyridines, quinolines or the like. In a recycle of the complexed rhodium to be reused in the hydroformylation reaction, the aqueous rhodium-containing extract is fed to a precarbonylation stage where it subjected to a required precarbonylation in the presence of an essentially water-insoluble organic liquid and in the presence of carbon monoxide, synthesis gas or another gas mixture containing carbon monoxide at from 50 to 1000 bar and from 50 to 180 DEG C. The mixture discharged from this precarbonylation stage is then separated into an organic phase containing the main part of the rhodium and an aqueous phase containing the complexing agent. The resulting rhodium-containing organic phase with the regenerated catalyst is then fed into the hydroformylation stage to complete its recycle.

公开(公告)号：AT385845T

公开(公告)日：2008-03-15

申请号：AT02740529

申请日：2002-04-26

Applicant: BASF AG

Inventor： BENFER REGINA ,  NILLES MICHAEL ,  WEINLE WERNER ,  ZEHNER PETER

IPC: B01D3/00 ,  C07D319/06 ,  B01D3/20 ,  B01J8/04 ,  B01J8/18 ,  B01J8/22 ,  B01J8/34 ,  B01J10/00 ,  B01J19/24 ,  B01J47/00 ,  C07C68/04 ,  C07C69/96

Abstract: A reactor (1) having a vertical longitudinal axis and an inlet (2) for a liquid or liquid/solid feed stream in the upper region of the reactor and an inlet (3) for a gaseous stream in the lower region of the reactor (1), characterized by at least two chambers (4) arranged above one another in the longitudinal direction, where the chambers (4) are separated from one another by liquid-tight bottom plates, each chamber is connected via a liquid overflow (6) to the chamber (4) located immediately underneath and a liquid product stream is taken off via the liquid overflow (6) of the bottommost chamber (4), the gas space (7) above the liquid surface in each chamber (4) is connected to the chamber (4) located immediately above it by one or more guide tubes (8) which opens (each open) into a gas distributor (9) provided with openings for exit of gas below the liquid surface, and each chamber is provided with at least one guide plate (12) which is arranged vertically around each siphon like gas distributor (9) and whose upper end is below the liquid surface and whose lower end is above the liquid-tight bottom plate (5) of the chamber (4) and which divides each chamber (4) into one or more spaces into which gas flows (13) and one or more spaces into which gas does not flow (14), is used for gas/liquid or gas/liquid/solid reactions.

公开(公告)号：DE50204499D1

公开(公告)日：2006-02-23

申请号：DE50204499

申请日：2002-02-12

Applicant: BASF AG

Inventor： ZEHNER PETER ,  NILLES MICHAEL

IPC: B01J10/00 ,  B01J19/00 ,  B01J19/24 ,  C07B61/00 ,  C07C45/50 ,  C07C47/02

Abstract: Continuous, homogeneously-catalyzed hydroformylation of ≥ 6C olefins is such that (a) a vertical cylindrical reactor is used which is divided into ≥ 2 zones stretching lengthwise; (b) olefin, together with synthesis gas, is fed in at the lower end of the first zone; (c) partly converted reaction mixture is fed from the upper end to the lower end of the next zone. Continuous, homogeneously-catalyzed hydroformylation of ≥ 6C olefins is such that (a) a vertical cylindrical reactor is used which is divided into ≥ 2 zones stretching lengthwise; (b) olefin, together with synthesis gas, is fed in at the lower end of the first zone; (c) partly converted reaction mixture is fed from the upper end to the lower end of the next zone; and (d) the hydroformylated olefin is led off at the upper end of the last zone. An Independent claim is also included for a vertical cylindrical reactor (1) subdivided lengthwise and having recycling devices (6) acting from the upper end of reaction zones to their lower ends.

公开(公告)号：DE59503268D1

公开(公告)日：1998-09-24

申请号：DE59503268

申请日：1995-03-06

Applicant: BASF AG

Inventor： KNEUPER HEINZ-JOSEF ,  ARON MAIK ,  KORGITZSCH FRANK-MICHAEL ,  NILLES MICHAEL ,  HARDER WOLFGANG ,  ROEPER MICHAEL ,  PACIELLO ROCCO

IPC: B01J31/40 ,  C07B61/00 ,  C07C27/22 ,  C07C29/141 ,  B01J23/46 ,  C07C29/16 ,  C07C31/02 ,  C07C45/50 ,  C07C45/80 ,  C07C47/02 ,  C07C51/235 ,  C07C209/00

Abstract: PCT No. PCT/EP95/00825 Sec. 371 Date Sep. 13, 1996 Sec. 102(e) Date Sep. 13, 1996 PCT Filed Mar. 6, 1995 PCT Pub. No. WO95/25080 PCT Pub. Date Sep. 21, 1995An industrial preparation of aldehydes and/or alcohols from olefins of more than 3 carbon atoms by a catalytic hydroformylation of the olefin reactant at a pressure of from 50 to 1000 bar and a temperature of from 50 to 180 DEG C. in the presence of an uncomplexed rhodium catalyst homogeneously dissolved in the reaction medium. The catalytic activity of the rhodium is maintained, first by extracting it from the initially discharged reaction mixture by means of an aqueous solution of a nitrogen-containing complexing agent such as sulfonated or carboxylated pyridines, quinolines or the like. In a recycle of the complexed rhodium to be reused in the hydroformylation reaction, the aqueous rhodium-containing extract is fed to a precarbonylation stage where it subjected to a required precarbonylation in the presence of an essentially water-insoluble organic liquid and in the presence of carbon monoxide, synthesis gas or another gas mixture containing carbon monoxide at from 50 to 1000 bar and from 50 to 180 DEG C. The mixture discharged from this precarbonylation stage is then separated into an organic phase containing the main part of the rhodium and an aqueous phase containing the complexing agent. The resulting rhodium-containing organic phase with the regenerated catalyst is then fed into the hydroformylation stage to complete its recycle.

公开(公告)号：DE10106482A1

公开(公告)日：2002-08-14

申请号：DE10106482

申请日：2001-02-13

Applicant: BASF AG

Inventor： ZEHNER PETER ,  NILLES MICHAEL

IPC: B01J10/00 ,  B01J19/00 ,  B01J19/24 ,  C07B61/00 ,  C07C45/50 ,  C07C47/02 ,  B01J12/00

Abstract: Continuous, homogeneously-catalyzed hydroformylation of ≥ 6C olefins is such that (a) a vertical cylindrical reactor is used which is divided into ≥ 2 zones stretching lengthwise; (b) olefin, together with synthesis gas, is fed in at the lower end of the first zone; (c) partly converted reaction mixture is fed from the upper end to the lower end of the next zone. Continuous, homogeneously-catalyzed hydroformylation of ≥ 6C olefins is such that (a) a vertical cylindrical reactor is used which is divided into ≥ 2 zones stretching lengthwise; (b) olefin, together with synthesis gas, is fed in at the lower end of the first zone; (c) partly converted reaction mixture is fed from the upper end to the lower end of the next zone; and (d) the hydroformylated olefin is led off at the upper end of the last zone. An Independent claim is also included for a vertical cylindrical reactor (1) subdivided lengthwise and having recycling devices (6) acting from the upper end of reaction zones to their lower ends.

公开(公告)号：AU1948795A

公开(公告)日：1995-10-03

申请号：AU1948795

申请日：1995-03-06

Applicant: BASF AG

Inventor： KNEUPER HEINZ-JOSEF ,  ARON MAIK ,  KORGITZSCH FRANK-MICHAEL ,  NILLES MICHAEL ,  HARDER WOLFGANG ,  ROPER MICHAEL ,  PACIELLO ROCCO

IPC: B01J23/46 ,  B01J31/40 ,  C07B61/00 ,  C07C27/22 ,  C07C29/141 ,  C07C29/16 ,  C07C31/02 ,  C07C45/50 ,  C07C45/80 ,  C07C47/02 ,  C07C51/235 ,  C07C209/00

Abstract: PCT No. PCT/EP95/00825 Sec. 371 Date Sep. 13, 1996 Sec. 102(e) Date Sep. 13, 1996 PCT Filed Mar. 6, 1995 PCT Pub. No. WO95/25080 PCT Pub. Date Sep. 21, 1995An industrial preparation of aldehydes and/or alcohols from olefins of more than 3 carbon atoms by a catalytic hydroformylation of the olefin reactant at a pressure of from 50 to 1000 bar and a temperature of from 50 to 180 DEG C. in the presence of an uncomplexed rhodium catalyst homogeneously dissolved in the reaction medium. The catalytic activity of the rhodium is maintained, first by extracting it from the initially discharged reaction mixture by means of an aqueous solution of a nitrogen-containing complexing agent such as sulfonated or carboxylated pyridines, quinolines or the like. In a recycle of the complexed rhodium to be reused in the hydroformylation reaction, the aqueous rhodium-containing extract is fed to a precarbonylation stage where it subjected to a required precarbonylation in the presence of an essentially water-insoluble organic liquid and in the presence of carbon monoxide, synthesis gas or another gas mixture containing carbon monoxide at from 50 to 1000 bar and from 50 to 180 DEG C. The mixture discharged from this precarbonylation stage is then separated into an organic phase containing the main part of the rhodium and an aqueous phase containing the complexing agent. The resulting rhodium-containing organic phase with the regenerated catalyst is then fed into the hydroformylation stage to complete its recycle.

公开(公告)号：DE50211675D1

公开(公告)日：2008-03-27

申请号：DE50211675

申请日：2002-04-26

Applicant: BASF AG

Inventor： BENFER REGINA ,  NILLES MICHAEL ,  WEINLE WERNER ,  ZEHNER PETER

IPC: B01D3/00 ,  C07D319/06 ,  B01D3/20 ,  B01J8/04 ,  B01J8/18 ,  B01J8/22 ,  B01J8/34 ,  B01J10/00 ,  B01J19/24 ,  B01J47/00 ,  C07C68/04 ,  C07C69/96

Abstract: A reactor (1) having a vertical longitudinal axis and an inlet (2) for a liquid or liquid/solid feed stream in the upper region of the reactor and an inlet (3) for a gaseous stream in the lower region of the reactor (1), characterized by at least two chambers (4) arranged above one another in the longitudinal direction, where the chambers (4) are separated from one another by liquid-tight bottom plates, each chamber is connected via a liquid overflow (6) to the chamber (4) located immediately underneath and a liquid product stream is taken off via the liquid overflow (6) of the bottommost chamber (4), the gas space (7) above the liquid surface in each chamber (4) is connected to the chamber (4) located immediately above it by one or more guide tubes (8) which opens (each open) into a gas distributor (9) provided with openings for exit of gas below the liquid surface, and each chamber is provided with at least one guide plate (12) which is arranged vertically around each siphon like gas distributor (9) and whose upper end is below the liquid surface and whose lower end is above the liquid-tight bottom plate (5) of the chamber (4) and which divides each chamber (4) into one or more spaces into which gas flows (13) and one or more spaces into which gas does not flow (14), is used for gas/liquid or gas/liquid/solid reactions.

公开(公告)号：DE10120801A1

公开(公告)日：2002-11-07

申请号：DE10120801

申请日：2001-04-27

Applicant: BASF AG

Inventor： BENFER REGINA ,  NILLES MICHAEL ,  WEINLE WERNER ,  ZEHNER PETER

IPC: C07D319/06 ,  B01D3/00 ,  B01D3/20 ,  B01J8/04 ,  B01J8/18 ,  B01J8/22 ,  B01J8/34 ,  B01J10/00 ,  B01J19/24 ,  B01J47/00 ,  C07C68/04 ,  C07C69/96 ,  B01J19/00

Abstract: The invention relates to a reactor (1) for gas/liquid or gas/liquid/solid reactions comprising a vertical longitudinal axis, a feed inlet (2) for a liquid or liquid/solid educt stream in the upper area of the reactor and for a gaseous steam (3) in the lower area of the reactor (1). The reactor also comprises at least two chambers (4) that are arranged one above the other in the longitudinal direction, whereby the chambers (4) are separated from one another by liquid-tight bottoms. Each chamber is connected to the chamber (4) located directly underneath by a liquid overflow (6), and a liquid product stream is withdrawn via the liquid overflow (6) of the lowermost chamber (4). The gas space (7) above the liquid level in each chamber (4) is connected to the chamber (4) directly located thereabove by one or more gas feed pipes (8) each of which discharging into a gas distributor (9) with openings for discharging gas underneath the liquid level. The reactor also comprises at least one baffle plate (12), which is vertically arranged around each gas distributor (9) and whose upper end terminates underneath the liquid level and whose lower end terminates above the liquid-tight bottom (5) of the chamber (4). In addition, the baffle plate divides each chamber (4) into one or more gassed (13) spaces and into one or more ungassed (14) spaces.

公开(公告)号：DE59902306D1

公开(公告)日：2002-09-12

申请号：DE59902306

申请日：1999-11-23

Applicant: BASF AG

Inventor： BERG STEFAN ,  ZEHNER PETER ,  BENFER REGINA ,  MUELLER JOERN ,  NILLES MICHAEL ,  SCHULZ RALF ,  STUETZER DIETER

IPC: B01J8/22 ,  B01J10/00 ,  B01J19/00 ,  B01J19/24 ,  B01J19/26 ,  C07B61/00 ,  C07C45/72 ,  C07C51/235 ,  C07C53/122

Abstract: A reactor (1) of high cylindrical construction for continuously carrying out gas-liquid, liquid-liquid or gas-liquid-solid reactions, provided with a downward-directed jet nozzle (2) via which the starting materials and the reaction mixture are fed in and which is located in the upper region of the reactor, and provided with an offtake (3), preferably in the lower region of the reactor, via which the reaction mixture is conveyed via an external circuit back to the jet nozzle (2) by means of a pump (P), wherein a guide tube (4) which extends essentially over the total length of the reactor (1) with the exception of the reactor ends and has a cross-sectional area in the range from one tenth to one half of the cross-sectional area of the reactor (1) is located concentrically in the reactor (1), and the jet nozzle (2) is located above the upper end of the guide tube (4), preferably at a distance of from one eighth of the guide tube diameter to one guide tube diameter, or projects into the guide tube (4) to a depth up to a plurality of guide tube diameters is proposed. A heat exchanger, in particular a heat exchanger having heat exchange tubes (6), preferably running parallel to the guide tube, welded in between plates (5), is integrated into the annular space.