公开(公告)号：JPH11349517A

公开(公告)日：1999-12-21

申请号：JP9491399

申请日：1999-04-01

Applicant: BASF AG

Inventor： BROECKER FRANZ JOSEF DR ,  KAIBEL GERD DR ,  AQUILA WERNER ,  FUCHS HARTWIG ,  WEGNER GUENTER DR ,  STROEZEL MANFRED

IPC: B01J23/44 ,  B01J8/20 ,  B01J8/22 ,  B01J19/24 ,  B01J23/46 ,  C07B61/00 ,  C07C45/62 ,  C07C47/21 ,  C07C49/04

Abstract: PROBLEM TO BE SOLVED: To carry out the hydrogenation of especially citral to citronellal at a low cost by an economical process having improved space-time yield and reduced investment cost by hydrogenating an α,β-unsaturated carbonyl compound in liquid phase under specific condition. SOLUTION: A compound of formula II is produced by the hydrogenation of an α,β-unsaturated carbonyl compound of formula I (R1 is H or an organic group; R2 to R4 are each H or a 1-4C alkyl) with hydrogen in the presence of powdery palladium and/or rhodium and an organic group while performing the regeneration of the product and the circulation of hydrogen gas in a bubble packed column reactor. The packing material in the bubble column reactor preferably has a hydraulic diameter of 0.5-20 mm and a surface roughness of 0.1 to 10 times the average particle diameter of the powdery catalyst particles at the opening or the channel wall part of the packing material and is made of a metallic material, a plastic material, etc.

公开(公告)号：DE59500893D1

公开(公告)日：1997-12-04

申请号：DE59500893

申请日：1995-06-30

Applicant: BASF AG

Inventor： DOBLER WALTER DR ,  KRAUSE WOLFGANG DR ,  PAUST JOACHIM DR ,  WOERZ OTTO DR ,  RHEUDE UDO DR ,  BURST WOLFRAM ,  DAEUWEL GUENTER ,  BERTRAM ARMIN ,  SCHULZ BERNHARD DR ,  WEGNER GUENTER DR ,  MUENSTER PETER DR ,  ERNST HANSGEORG DR ,  KOCHNER ARNO ,  ETZRODT HEINZ DR

IPC: C07C51/16 ,  C07C403/00 ,  C07C403/20

公开(公告)号：AT77086T

公开(公告)日：1992-06-15

申请号：AT90103616

申请日：1990-02-24

Applicant: BASF AG

Inventor： KARBACH STEFAN DR ,  SEELE RAINER DR ,  WEGNER GUENTER DR ,  SMUDA HUBERT DR ,  BIRECKOVEN BERND DR ,  LORENZ GISELA DR ,  AMMERMANN EBERHARD DR

IPC: C07D405/06 ,  A01N43/50 ,  A01N43/653 ,  C07D405/14 ,  C07D521/00

公开(公告)号：DK0947493T3

公开(公告)日：2002-12-30

申请号：DK99105126

申请日：1999-03-26

Applicant: BASF AG

Inventor： BROECKER FRANZ JOSEF DR ,  KAIBEL GERD DR ,  AQUILA WERNER DR ,  FUCHS HARTWIG ,  WEGNER GUENTER DR ,  STROEZEL MANFRED

IPC: B01J23/44 ,  B01J8/20 ,  B01J8/22 ,  B01J19/24 ,  B01J23/46 ,  C07B61/00 ,  C07C45/62 ,  C07C47/21 ,  C07C49/04

Abstract: Production of saturated carbonyl compounds (I) by selective liquid-phase hydrogenation of alpha , beta -unsaturated carbonyl compounds (II) is carried out in a packed bubble column with the product recycled and by circulating hydrogen gas. Production of saturated carbonyl compounds of formula R1-CH(R2)-CH(R3)-C(R4)=O (I) by selective liquid-phase hydrogenation of alpha , beta -unsaturated carbonyl compounds of formula R1-C(R2)=C(R3)-C(R4)=O (II) in the presence of a particulate palladium and/or rhodium catalyst and a base is carried out in a packed bubble column with the product recycled and by circulating hydrogen gas. R1 = H or an organic group; R2-R4 = H or 1-4C alkyl.

公开(公告)号：DE59000151D1

公开(公告)日：1992-07-16

申请号：DE59000151

申请日：1990-02-24

Applicant: BASF AG

Inventor： KARBACH STEFAN DR ,  SEELE RAINER DR ,  WEGNER GUENTER DR ,  SMUDA HUBERT DR ,  BIRECKOVEN BERND DR ,  LORENZ GISELA DR ,  AMMERMANN EBERHARD DR

IPC: C07D405/06 ,  A01N43/50 ,  A01N43/653 ,  C07D405/14 ,  C07D521/00

Abstract: Trifluoromethylphenylazolylmethyloxiranes of the general formula I in which R represents hydrogen, halogen, nitro, phenyl, phenoxy, alkyl, alkoxy, haloalkyl or haloalkoxy, and, moreover, R together with the phenyl ring can also form a naphthyl radical which is unsubstituted or substituted, n represents an integer from 1 to 5, R represents ortho- or para-trifluoromethyl, X represents CH or N, and their acid addition salts and metal salts which are tolerated by plants, and fungicides containing these compounds.

公开(公告)号：DE3907729A1

公开(公告)日：1990-09-13

申请号：DE3907729

申请日：1989-03-10

Applicant: BASF AG

Inventor： KARBACH STEFAN DR ,  SEELE RAINER DR ,  WEGNER GUENTER DR ,  SMUDA HUBERT DR ,  BIRECKOVEN BERND DR ,  LORENZ GISELA DR ,  AMMERMANN EBERHARD DR

IPC: C07D405/06 ,  A01N43/50 ,  A01N43/653 ,  C07D405/14 ,  C07D521/00

Abstract: Trifluoromethylphenylazolylmethyloxiranes of the general formula I in which R represents hydrogen, halogen, nitro, phenyl, phenoxy, alkyl, alkoxy, haloalkyl or haloalkoxy, and, moreover, R together with the phenyl ring can also form a naphthyl radical which is unsubstituted or substituted, n represents an integer from 1 to 5, R represents ortho- or para-trifluoromethyl, X represents CH or N, and their acid addition salts and metal salts which are tolerated by plants, and fungicides containing these compounds.

公开(公告)号：AT226930T

公开(公告)日：2002-11-15

申请号：AT99105126

申请日：1999-03-26

Applicant: BASF AG

Inventor： BROECKER FRANZ JOSEF DR ,  KAIBEL GERD DR ,  AQUILA WERNER DR ,  FUCHS HARTWIG ,  WEGNER GUENTER DR ,  STROEZEL MANFRED

IPC: B01J23/44 ,  B01J8/20 ,  B01J8/22 ,  B01J19/24 ,  B01J23/46 ,  C07B61/00 ,  C07C45/62 ,  C07C47/21 ,  C07C49/04

Abstract: Production of saturated carbonyl compounds (I) by selective liquid-phase hydrogenation of alpha , beta -unsaturated carbonyl compounds (II) is carried out in a packed bubble column with the product recycled and by circulating hydrogen gas. Production of saturated carbonyl compounds of formula R1-CH(R2)-CH(R3)-C(R4)=O (I) by selective liquid-phase hydrogenation of alpha , beta -unsaturated carbonyl compounds of formula R1-C(R2)=C(R3)-C(R4)=O (II) in the presence of a particulate palladium and/or rhodium catalyst and a base is carried out in a packed bubble column with the product recycled and by circulating hydrogen gas. R1 = H or an organic group; R2-R4 = H or 1-4C alkyl.

公开(公告)号：DE4424294A1

公开(公告)日：1996-01-11

申请号：DE4424294

申请日：1994-07-09

Applicant: BASF AG

Inventor： DOBLER WALTER DR ,  KRAUSE WOLFGANG DR ,  PAUST JOACHIM DR ,  WOERZ OTTO DR ,  RHEUDE UDO DR ,  BURST WOLFRAM ,  DAEUWEL GUENTER ,  BERTRAM ARMIN ,  SCHULZ BERNHARD DR ,  WEGNER GUENTER DR

IPC: A23L5/40 ,  C07B41/04 ,  C07B41/08 ,  C07C45/72 ,  C07C67/347 ,  C07C291/04 ,  C07C403/14 ,  C07C403/20 ,  C07D207/46 ,  C07D211/94 ,  C07D263/04 ,  C07D521/00 ,  C09B23/01

Abstract: Prodn. of polyenecarbonyl cpds. (I) having high all-E content, and their acetals and ketals, comprises reacting a carbonyl cpd. (II) with a dialkyl phosphonate in a Horner-Emmons reaction or with a CH-acidic cpd. in an aldol condensation in the presence of 0.3-10 mol.% (based on (II)) of a component (B) comprising a) oxygen or nitrogen monoxide (opt. mixed with an inert gas); b) the stable 2,2-diphenyl-1-picrylhydrazyl radical or a hydrogen peroxide-urea adduct; c) quinone, a quinone deriv. or coenzyme Q10 hydroquinone; and/or d) a stable radical of formula (I) or (II). R1, R2 = 1-4C alkyl; or R1+R2 = ethylene, propylene, vinylene or propenylene (all opt. substd. by alkyl, aryl, OH, alkoxy, silyloxy, oxo, NH2, SH, alkylthio, CN, COOH, carbamoyl, heteroaryl or alkylcarbonyloxy); R3-R5 = as R1, R2.

公开(公告)号：DE59009812D1

公开(公告)日：1995-11-30

申请号：DE59009812

申请日：1990-08-22

Applicant: BASF AG

Inventor： KOBER REINER DR ,  SEELE RAINER DR ,  ZIERKE THOMAS DR ,  ISAK HEINZ DR ,  KARBACH STEFAN DR ,  WEGNER GUENTER DR

IPC: C07B49/00 ,  C07F3/02 ,  C07F7/08

Abstract: Preparation of ether solutions of arylmethylmagnesium halides… Ar-CH2-Mg-Hal I… (Aryl = unsubstituted or substituted aryl; Hal = Cl, Br) by the Grignard process from arylmethyl halides II… Ar-CH2-Hal II… with magnesium in an ether as a solvent, by using III… tert-butyl-O-R III… (R = C1-C3-alkyl) for this purpose.

公开(公告)号：DK0386557T3

公开(公告)日：1992-07-27

申请号：DK90103616

申请日：1990-02-24

Applicant: BASF AG

Inventor： AMMERMANN EBERHARD DR ,  LORENZ GISELA DR ,  KARBACH STEFAN DR ,  SMUDA HUBERT DR ,  SEELE RAINER DR ,  WEGNER GUENTER DR ,  BIRECKOVEN BERND DR

IPC: C07D405/06 ,  A01N43/50 ,  A01N43/653 ,  C07D405/14 ,  C07D521/00

Abstract: Trifluoromethylphenylazolylmethyloxiranes of the general formula I in which R represents hydrogen, halogen, nitro, phenyl, phenoxy, alkyl, alkoxy, haloalkyl or haloalkoxy, and, moreover, R together with the phenyl ring can also form a naphthyl radical which is unsubstituted or substituted, n represents an integer from 1 to 5, R represents ortho- or para-trifluoromethyl, X represents CH or N, and their acid addition salts and metal salts which are tolerated by plants, and fungicides containing these compounds.