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公开(公告)号：DE10315094A1
公开(公告)日：2004-10-14
申请号：DE10315094
申请日：2003-04-02
Applicant: BASF AG
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公开(公告)号：DE102005019880A1
公开(公告)日：2006-11-09
申请号：DE102005019880
申请日：2005-04-28
Applicant: BASF AG
Inventor： DOETZ FLORIAN , NORD SIMON , WEIS HORST , ROESCH JOACHIM
Abstract: The invention relates to a method for producing polyfluoroanthenes containing repeat units of general formula (I), said method consisting of the following steps: a) a monomer fluoroanthene derivative of formula IIa is produced; b) optionally the monomer fluoroanthene derivative of formula IIa is converted into another monomer fluoroanthene derivative of formula IIb; and c) the monomer fluoroanthene derivative of formula IIa or IIb is polymerised, optionally together with at least one other comonomer. The invention also relates to polyfluoroanthenes that can be produced according to the inventive method, films, a light-emitting layer containing or consisting of at least one inventive polyfluoroanthene, OLEDs containing at least one inventive polyfluoroanthene, OLEDs containing an inventive light-emitting layer, a device containing an inventive OLED, and the use of the inventive polyfluoroanthene emitter substances in OLEDs.
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公开(公告)号：DE10211648A1
公开(公告)日：2003-09-25
申请号：DE10211648
申请日：2002-03-15
Applicant: BASF AG
Inventor： SCHWALM REINHOLD , HEISCHKEL YVONNE , WEIS HORST
Abstract: Polymers with fluoranthene-based repeat units are new. Polymers containing repeat units of formula (I) are new. a = 0-3; R1-R3 = H, 1-20C alkyl, (optionally with one or more Si, N, P, O or S atoms), 6-30C (preferably 6-14C) aryl, 4-14C heteroaryl with at least one S or N atom, -N(6-14C aryl)2 or the group Y1; Y1 = vinyl, (E)- or (Z)-phenylethenyl, (meth)acryloyl, methyl styryl, vinyloxy, glycidyl, phenylethynyl or the group -Phe-O-Y2; Phe = 1,4-phenylene; Y2 = vinyl, (E)- or (Z)-phenyl-ethenyl, (meth)acryloyl, methyl styryl, vinyloxy or glycidyl, optionally with one or more groups Y1 or Y2 crosslinked together. Independent claims are also included for: (1) a method (M1) for the production of (I) from monomers of formula (II) by reaction in the presence of nickel or palladium compounds (2) monomers of formula (II) with a halogen or esterified sulfonate group on ring C (preferably at position 8 of the fluoranthene system) and a boron-containing group (c) (see below) on ring B (preferably at position 3) (i.e. monomers III) (3) a method for the preparation of (III) from the corresponding compounds with halogen or sulfonate groups, by metalation with at least 2 or at least 4 equivalents of a strong organometallic base followed by reaction with 1 or 2 equivs. of boron compounds of formula (V) (4) a method (M2) for the production of (I) by the photochemical or thermal polymerisation of monomers of formula (II) with no X1 or X2 groups (i.e. monomers VI) (5) films containing or consisting of (I) (6) organic electro luminescent diodes based on (I). X1, X2 = (a) halogen, (b) esterified sulfonate, or (c) boron-containing groups of formula -B(O-(C(R6)2)n)-O-), using either one monomer of formula (II) in which X1 is a group (a) or (b) and X2 is (c), or at least two different monomers (II), one of which has two (a) and two (b) groups, or one of each, and the other monomer has two groups (c), with (a + b) and (c) in a mol ratio of (0.8:1)-(1.2:1) ; R6 = H or 1-20C alkyl; n = 2-10; X5 = 1-6C alkoxy.
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Patent Agency Ranking
公开(公告)号：DE19831865A1
公开(公告)日：2000-01-20
申请号：DE19831865
申请日：1998-07-16
Applicant: BASF AG
Inventor： AUWETER HELMUT , BOHN HERIBERT , HORN DIETER , KRAEMER KLAUS , PAUST JOACHIM , WEIS HORST
IPC: A23K1/16 , A23L1/275 , A23L5/41 , A23L5/44 , A61K8/31 , A61K8/35 , A61K8/46 , A61K8/49 , A61K8/60 , A61K31/395 , A61K31/52 , A61Q19/00 , C07C403/00 , C07C403/24 , C07D339/04 , C09B61/00 , C09B67/42 , A23L1/30
Abstract: The use of organosulfur compounds is claimed for bathochromic shifting of the UV/visible absorption spectrum of carotinoids. Independent claims are included for: (A) complexes comprising one or more organosulfur compounds and one or more carotinoids, and (B) preparation of carotinoid formulations, which comprises dispersion of an organosulfur/carotinoid mixture in water or a protective colloid solution, followed by drying of the dispersion.
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公开(公告)号：DE102004039982A1
公开(公告)日：2006-02-23
申请号：DE102004039982
申请日：2004-08-12
Applicant: BASF AG
Inventor： WEIS HORST , KNOLL KONRAD , STEININGER HELMUT , GUSEV ANDRE , ISMAN GABRIEL , BENEVOLENSKI OLEG , SCHMITT WINFRIED , SCHLOEGL SABINE , RIEDEL HERMANN
Abstract: Method for microstructure-based modeling of mechanical characteristics of block copolymer comprises: generating one or more hypothetical morphologies (a) and forming cross link between discriminate finite elements (b); producing several domains and with the laid (a) each domain consists of one or more (b); and simulating deformation of the cross link of (b). Method for microstructure-based modeling of mechanical characteristics of block copolymer (exhibiting several phases, intermediate phase and a composite morphology from several domains) comprises: generating one or more hypothetical morphologies (a) and forming cross link between discriminate finite elements (b); producing several domains and with the laid (a) each domain consists of one or more (b); and simulating deformation of the cross link of (b). Independent claims are also included for: (1) a computer program with program code comprising the automatic execution of the above method during execution of the program on a computer or on a computer system; and (2) a computer program product with program code (stored on a computer-readable data carrier) comprising carrying out the above process when the computer program comes on a computer for execution.
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公开(公告)号：DE10234005A1
公开(公告)日：2004-02-05
申请号：DE10234005
申请日：2002-07-25
Applicant: BASF AG
Inventor： CHOWDHRY MUBARIK MAHMOOD , SCHMID MARKUS , PREISHUBER-PFUEGL PETER , SAVA XAVIER , WEIS HORST , MECKING STEFAN , BAUERS FLORIAN M
IPC: C08F2/22 , C08F2/24 , C08F10/02 , C08F110/02 , C08F210/16 , C08F4/42 , C08F10/00
Abstract: A method for the emulsion polymerization of one or more olefins by reacting a ligand of general formulae Ia and Ib or a mixture of at least two ligands Ia or Ib, wherein R respectively represents one or several of the following radicals; hydrogen, halogen, nitrile, C1-C12-alkyl groups, C1-C12-alkoxy groups, C7-C13-aralkyl groups, C6-C14-aryl groups, and wherein identical or different compounds of general formulae Ia and Ib can, optionally, be concatenated by one or several bridges, with a phosphine compound PR3′ and a metal compound of general formula M(L2)2 or M(L2)2 (L1)z, wherein the variables are defined as follows: M is a transition metal of groups 7-10 in the periodic system of the elements; L1 represents phosphanes (R5)xPH3-x or amines (R5)xNH3-x with identical or different radicals R5, ether (R5)2O, H2O, alkohols (R5)OH, pyridine, pyridine derivatives of formula C5H5-x(R5)xN, CO, C1-C12-alkylnitriles, C6-C14-arylnitriles or ethylenically unsaturated double bond systems, wherein x is a whole number ranging from 0-3, L2 represents halogenide ions R6xNH3-x, wherein x is a whole number ranging from 0 3 and R6 represents C1-C12-alkyl, and C1-C6-alkylane ions, allylane ions, benzylane ions or arylane ions, wherein L1 and L2 can be concatenated with each other by one or several covalent bonds, z is a number ranging from 0 4. The invention also relates to the immediate use of the reaction product in the polymerization or copolymerization of olefins in water or in a solvent mixture containing at least 50 vol. % water in the presence of an emulsifier and, optionally, in the presence of an activator.
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公开(公告)号：DE10229977A1
公开(公告)日：2004-01-22
申请号：DE10229977
申请日：2002-07-03
Applicant: BASF AG
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公开(公告)号：DE102004043497A1
公开(公告)日：2006-03-09
申请号：DE102004043497
申请日：2004-09-06
Applicant: BASF AG
Inventor： DOETZ FLORIAN , NORD SIMON , WEIS HORST , ROESCH JOACHIM
Abstract: The present invention relates to a process for preparing polynaphthalene derivatives comprising repeating units of the general formula Ia and/or Ib where R 1 , R 2 , R 1' , R 2' are as defined in the description. The present invention further relates to polynaphthalene derivatives which can be prepared by the process of the invention, films comprising or consisting of at least one polynaphthalene derivative according to the invention, organic light-emitting diodes (OLEDs) comprising at least one polynaphthalene derivative according to the invention, a light-emitting layer comprising or consisting of at least one polynaphthalene derivative according to the invention, an OLED comprising the light-emitting layer of the invention, devices comprising an OLED according to the invention and the use of the polynaphthalene derivatives of the invention as emitter substances in OLEDs.
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