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    ELECTROCHEMICAL METHOD FOR PRODUCING DIPHENYLPHOSPHINE OXIDE, DIPHENYLPHOSPHINE OR PHOSPHINE AND THEIR DERIVATIVES
    1.
    发明申请
    ELECTROCHEMICAL METHOD FOR PRODUCING DIPHENYLPHOSPHINE OXIDE, DIPHENYLPHOSPHINE OR PHOSPHINE AND THEIR DERIVATIVES 审中-公开
    电化学过程用于生产二苯基膦，DIPHENYLPHOPHIN磷化氢及其衍生物

    公开(公告)号：WO2005031040A3

    公开(公告)日：2005-11-24

    申请号：PCT/EP2004010420

    申请日：2004-09-17

    Applicant: BASF AG ,  GRIESBACH ULRICH ,  WEISKOPF VERENA ,  MAASE MATTHIAS

    Inventor： GRIESBACH ULRICH ,  WEISKOPF VERENA ,  MAASE MATTHIAS

    IPC: C25B3/04

    CPC classification number: C25B3/04

    Abstract: The invention relates to a method for producing diphenylphosphine oxide (DPPO) or its nucleus-substituted derivatives, diphenylphosphine (DPP) or its nucleus-substituted derivatives or phosphine (PP) or its nucleus-substituted derivatives, starting from triphenylphosphine oxide (TPPO) or the corresponding nucleus-substituted derivatives, or in the case of the production of DPP and PP, starting from triphenylphosphine (TPP) or the corresponding nucleus-substituted derivatives or DPPO. According to said method, the starting products are reduced electrochemically in the presence of ammonia or an amine.

    Abstract translation: 一种用于制备二苯基氧化膦或它的环上取代的衍生物（DPPO），二苯基膦或其环上取代的衍生物（DPP）或膦或其环上取代的衍生物（PP）过程中，从三苯基膦氧化物或相应的环上取代的衍生物（TPPO）或在DPP的制剂的情况下开始 和PP还从三苯基膦或相应的环取代的衍生物（TPP）或DPPO，其被电化学还原，起始产品中氨或胺的存在下开始。

    New phosphorous chelate compounds are useful as catalysts for asymmetrical synthesis (preferably as chiral components for the production of pharmaceuticals, plant protecting agents, cosmetics or flavor materials)
    3.
    发明专利
    New phosphorous chelate compounds are useful as catalysts for asymmetrical synthesis (preferably as chiral components for the production of pharmaceuticals, plant protecting agents, cosmetics or flavor materials) 未知

    公开(公告)号：DE102005061642A1

    公开(公告)日：2006-07-06

    申请号：DE102005061642

    申请日：2005-12-22

    Applicant: BASF AG

    Inventor： VOLLAND MARTIN ,  PAPP RAINER ,  HETTCHE FRANK ,  JAEKEL CHRISTOPH ,  WEISKOPF VERENA ,  PACIELLO ROCCO ,  SPRINGMANN STEFFEN

    IPC: C07F9/547 ,  B01J31/24 ,  C07C29/16 ,  C07C31/125

    Abstract: Phosphorous chelate compounds (I) are new. Phosphorous chelate compounds (I) of formula (R1>-P(R2>)-(X)a-Y1>-(O)b-P-((O)c-Rgamma )-(O)d-Rdelta ) are new. either R1>, R2>5-7 membered heterocyclic groups that are bonded over N atom to P atom; or PR1>R2>5-7 membered heterocycle additionally contains optionally substituted N atom and a further under oxygen and optionally substituted N atoms that are bonded directly to P atom; either Rgamma , Rdelta : akyl, cycloalkyl, heterocycloalkyl, aryl or hetaryl (all substituted with 1-5 of cycloalkyl, heterocycloalkyl, aryl, hetaryl, alkoxy, cycloalkoxy, heterocycloalkoxy, aryloxy, hetaryloxy, hydroxy, thiol, polyalkylenoxide, polyalkylenimine, COOH, carboxylate, SO3H, sulfonate, NE1>E2>, NE1>E2>E3>X-, halo, NO2, acyl or CN); or PRgamma Rdelta , ORgamma Rdelta : 5-8 membered heterocycle optionally annealed with 1-3 of cycloalkyl, heterocycloalkyl, aryl or hetaryl, where the heterocycle and optionally the annealed groups are substituted with 1-4 of alkyl, cycloalkyl, heterocycloalkyl, aryl, hetaryl, hydroxy, thiol, polyalkyleneoxide, polyalkylenimine, alkoxy, halo, COOH, carboxylate, SO3H, sulfonate, NE4>E5>, NE4>E5>E6>+>X->, NO2, alkoxycarbonyl, acyl or CN; E4>, E5>, E6>H, alkyl, cycloalkyl or aryl; X : O, S, SiReRf or NRg; Re, Rf, Rg : H, alkyl, cycloalkyl, heterocycloalkyl, aryl or hetaryl; X->anion; Y1>bivalent carbon containing bridge atoms; and a-d : 0-1 (where at least one of b, c or d is 1). Independent claims are also included for: (1) catalyst comprising at least one complex with a transition metal, as ligands of (I); (2) preparation of chiral compounds comprising reacting prochiral compounds containing at least ethylenic unsaturated double bond, with a substrate in the presence of a chiral catalyst; (3) a method for hydroformylation of compounds containing at least ethylenic unsaturated double bond comprising reacting with carbon monoxide and hydrogen in the presence of hydroformylating catalyst; (4) preparation of 2-propylheptanol comprising subjecting butene or butene containing C4-hydrocarbon mixture of hydroformylation to obtain n-valeraldehyde containing hydroformylating products, optionally isolating hydroformylating products under n-valeraldehyde enriched groups, subjecting the obtained hydroformylating products and n-valeraldehyde enriched groups to aldol condensation, hydrogenating the products of aldol condensation, catalytically with hydrogen to alcohols and optionally subjecting the hydrogenation products to isolate 2-propylheptanol enriched groups; and (5) a method of hydroformylation of alpha -olefine and olefine with inner double bonds containing a composition, comprising reacting with carbon monoxide and hydrogen in the presence of hydroformylating catalyst in two-stage reaction system (where the first step comprises feeding an inlet containing olefin, carbon monoxide and hydrogen and converting partly catalytically; feeding and converting the discharge from the above step; and feeding the discharge from the second step with a stream obtained from non-reacted olefine and saturated hydrocarbons).

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