Abstract:
The invention relates to spiro compounds of the formula (I) and monolithic materials produced therefrom by double ring-opening polymerization, made of a porous metal or semi-metal oxide framework, and suitable for use as a catalyst support or as a support for active agents.
Abstract:
The invention relates to an aqueous composition containing (a) polymers having primary amino groups and/or amidine groups with a total content of said groups of =1.5 meq/g polymer and (b) 0.01 - 50 mol-% 1,4-cyclohexandion (b) based on the total amount of primary amino groups and amidine groups of the polymers. The aqueous composition has a pH-value =6. The invention also relates to the use thereof as a solidifying agent and to a method for producing paper and cardboard, to the use of the aqueous composition and to the thus produced paper and cardboard.
Abstract:
The present invention relates to a method for separating substance mixtures by means of a non-porous polymer film, comprising (a) at least one inorganic or metal-organic phase, and (b) at least one organic polymer phase, wherein the polymer film can be obtained by polymerizing at least one monomer comprising at least one first polymerizable monomer segment A1, comprising at least one metal or semi-metal M, and at least one second polymerizable organic monomer segment A2, connected to the polymerizable monomer segment A1 by means of a covalent chemical bond, under polymerization conditions, under which both the polymerizable monomer segment A1 and the polymerizable organic monomer segment A2 polymerize while breaking the covalent chemical bond between A1 and A2. The present invention further relates to the use of the above polymer films for permeating, gas separating, or pervaporating.
Abstract:
The invention relates to a method for producing a nanocomposite material composed of a) at least one inorganic or organometallic phase, and b) an organic polymer phase. Said method includes the polymerization of at least one monomer M which comprises at least one first polymerizable monomer unit A containing a metal or semimetal M, and at least one second polymerizable organic monomer unit B that is linked to polymerizable unit A via a covalent chemical bond, in polymerization conditions in which both polymerizable monomer unit A and polymerizable unit B polymerize while the bond between A and B is broken. The monomers M to be polymerized comprise a first monomer M1 and at least one second monomer M2 which differs from monomer M1 in at least one of monomer units A or B (embodiment 1). Alternatively, in addition to the at least one monomer M, the monomers to be polymerized comprise at least one other monomer M' that differs from monomer M, i.e. monomer M' is a conventional monomer without monomer unit A, said monomer M' being copolymerizable with monomer unit B (embodiment 2).
Abstract:
Procedimiento para separar mezclas de sustancias mediante una película de polímeros no porosa, el cualpresenta (a) al menos una fase inorgánica o metal-orgánica y (b) al menos una fase orgánica del polímero donde la película de polímeros puede obtenerse mediante la polimerización de al menos un monómero que presentaal menos un primer segmento polimerizable del monómero A1 que contiene al menos un metal o un semimetal M, yal menos un segundo segmento orgánico polimerizable del monómero A2 que se encuentra unido al segmentopolimerizable del monómero A1 mediante un enlace químico covalente, bajo condiciones de polimerización, bajo lascuales tanto el segmento polimerizable del monómero A1 como también el segmento orgánico polimerizable delmonómero A2 polimerizan al romperse el enlace químico covalente entre A1 y A2
Abstract:
The present invention relates to a process for producing a particulate nanocomposite material, in which the particles of the nanocomposite material comprise a) at least one inorganic or organo(semi)metallic phase which comprises at least one (semi)metal M; and b) at least one organic polymer phase. The invention also relates to the nanocomposite materials obtainable by this process. The process comprises the polymerization of at least one monomer MM which has at least one first cationically polymerizable monomer unit A which has a metal or semimetal M, and at least one second cationically polymerizable organic monomer unit B which is joined to the polymerizable unit A via at least one, e.g. 1, 2, 3 or 4, covalent chemical bond, under cationic polymerization conditions under which both the polymerizable monomer unit A and the polymerizable unit B polymerize with breakage of the bond or bonds between A and B, where the polymerization is carried out in an aprotic solvent in which the nanocomposite material is insoluble, in the presence of at least one polymerization initiator and of at least one further substance selected from a) at least one surface-active substance and ß) at least one particulate material.
Abstract:
The invention relates to spiro compounds of the formula (I) and to monolithic materials prepared therefrom by twin ring-opening polymerization which consist of a porous metal oxide or semimetal oxide framework and are suitable for use as catalyst supports or as supports for active compounds.