METHOD FOR SEPARATING SUBSTANCE MIXTURES BY MEANS OF MULTIPHASE POLYMER FILMS

    公开(公告)号:CA2774213A1

    公开(公告)日:2011-04-07

    申请号:CA2774213

    申请日:2010-09-27

    Applicant: BASF SE

    Abstract: The present invention relates to a method for separating substance mixtures by means of a non-porous polymer film, comprising (a) at least one inorganic or metal-organic phase, and (b) at least one organic polymer phase, wherein the polymer film can be obtained by polymerizing at least one monomer comprising at least one first polymerizable monomer segment A1, comprising at least one metal or semi-metal M, and at least one second polymerizable organic monomer segment A2, connected to the polymerizable monomer segment A1 by means of a covalent chemical bond, under polymerization conditions, under which both the polymerizable monomer segment A1 and the polymerizable organic monomer segment A2 polymerize while breaking the covalent chemical bond between A1 and A2. The present invention further relates to the use of the above polymer films for permeating, gas separating, or pervaporating.

    METHOD FOR THE PRODUCTION OF COMPOSITE MATERIALS

    公开(公告)号:CA2754718A1

    公开(公告)日:2010-10-07

    申请号:CA2754718

    申请日:2010-04-01

    Applicant: BASF SE

    Abstract: The invention relates to a method for producing a nanocomposite material composed of a) at least one inorganic or organometallic phase, and b) an organic polymer phase. Said method includes the polymerization of at least one monomer M which comprises at least one first polymerizable monomer unit A containing a metal or semimetal M, and at least one second polymerizable organic monomer unit B that is linked to polymerizable unit A via a covalent chemical bond, in polymerization conditions in which both polymerizable monomer unit A and polymerizable unit B polymerize while the bond between A and B is broken. The monomers M to be polymerized comprise a first monomer M1 and at least one second monomer M2 which differs from monomer M1 in at least one of monomer units A or B (embodiment 1). Alternatively, in addition to the at least one monomer M, the monomers to be polymerized comprise at least one other monomer M' that differs from monomer M, i.e. monomer M' is a conventional monomer without monomer unit A, said monomer M' being copolymerizable with monomer unit B (embodiment 2).

    PROCESS FOR PRODUCING A PARTICULATE NANOCOMPOSITE MATERIAL

    公开(公告)号:CA2759166A1

    公开(公告)日:2010-11-11

    申请号:CA2759166

    申请日:2010-05-07

    Applicant: BASF SE

    Abstract: The present invention relates to a process for producing a particulate nanocomposite material, in which the particles of the nanocomposite material comprise a) at least one inorganic or organo(semi)metallic phase which comprises at least one (semi)metal M; and b) at least one organic polymer phase. The invention also relates to the nanocomposite materials obtainable by this process. The process comprises the polymerization of at least one monomer MM which has at least one first cationically polymerizable monomer unit A which has a metal or semimetal M, and at least one second cationically polymerizable organic monomer unit B which is joined to the polymerizable unit A via at least one, e.g. 1, 2, 3 or 4, covalent chemical bond, under cationic polymerization conditions under which both the polymerizable monomer unit A and the polymerizable unit B polymerize with breakage of the bond or bonds between A and B, where the polymerization is carried out in an aprotic solvent in which the nanocomposite material is insoluble, in the presence of at least one polymerization initiator and of at least one further substance selected from a) at least one surface-active substance and ß) at least one particulate material.

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