Abstract:
PURPOSE: A manufacturing method of silicon polymer asymmetric composite film is provided to enhance fabrication efficiency, heat resistance and intensity by having inorganic film characteristic and to improve water transmission property. CONSTITUTION: A manufacturing method of silicon polymer asymmetric composite film comprises the following steps: coating a supporter with a macromolecular solution which includes silicon polymer and pore-forming agent; and forming an asymmetrical composite film by phase transfer the supporter by dipping the same into non-solvent. The silicon polymer is ladder type polysilsesquioxanes.
Abstract:
PURPOSE: A block copolymer electrolyte composite membrane is provided to be usefully used in various fields requiring moderate ion conductivity such as an operator/sensor, a fuel cell, a secondary battery, a capacitor, etc. CONSTITUTION: A block copolymer electrolyte composite membrane comprises a planar inorganic filler surface-treated by a sulfone group; and a block copolymer which comprises one or more selected from sulfone group, carbonate group, and phosphate group. A manufacturing method of the block copolymer electrolyte composite membrane comprises: a step of surface-modifying the planar inorganic filler by a sulfone group; a step of adding and dispersing the surface-modified planar iorganic filler to a block copolymer electrolyte solution selected from sulfone group, carbonate group and phosphate group, and a step of drying the electrolyte solution.
Abstract:
PURPOSE: A low dielectric layer is provided to have low moisture absorption ratio, high surface modulus and hardness, together with excellent physical properties, and to embodying excellent low-dielectric performance. CONSTITUTION: A low dielectric layer comprises is manufactured by using silsesquioxane polymer matrix as a precursor. The silsesquioxane polymer matrix is a silsesquioxane sol, manufactured by polymerizing multi-reactive cyclic siloxane, a fluorinated silane monomer, and alkoxysilane. A manufacturing method of the low dielectric layer comprises: a step of manufacturing silsesquioxane by a sol-gel method by using multifunctional cyclic siloxane, fluorine silane monomer and alkoxysilane as monomers; a step of manufacturing coating liquid comprising the silsesquioxane sol, and solvent; and a step of spreading and curing the coating liquid.
Abstract:
본 발명은 대부분 소각되는 폐 가교 고밀도 폴리에틸렌계(high density polyethylene, HDPE) 파이프의 가교결합을 초임계 메탄올을 이용하여 탈가교화(decrosslinking) 함으로써 재성형 가능한 고밀도 폴리에틸렌계 파이프로 재생시키는 방법에 관한 것으로, 폐 가교 고밀도 폴리에틸렌계 파이프를 370 내지 390℃의 반응온도 및 5 내지 30 ㎫의 반응압력 조건 하에서 5 내지 10분간 초임계 메탄올을 반응용매로 사용하는 탈가교화 반응에 의해 재성형 가능한 고밀도 폴리에틸렌계 수지로 재생시키는 것을 특징으로 한다. 폐 가교 고밀도 폴리에틸렌, 가교 파이프, 재활용, 초임계 반응, 탈가교화
Abstract:
PURPOSE: A method for removing catalyst residues from the hydrolysate of cyclosiloxane is provided to improve the efficiency of a removing operation by using a column adsorbing alkoxylate compounds. CONSTITUTION: Cyclosiloxane is hydrolyzed from a solution containing cyclosiloxane, a catalyst, and a solvent. The solution is filtered using a column adsorbing alkoxylate compounds. The cyclosiloxane contains one or more selected from tetramethyl-cyclotetrasiloxane, pentamethyl-cyclotetrasiloxane, and the mixture of the same. The catalyst contains a Pd-based catalyst. The solvent contains one or more selected from tetrahydrofuran, dioxane, and the mixture of the same. The column contains a column adsorbing magnesium oxides. The content of the catalyst in the solution is 1ppm.
Abstract:
PURPOSE: A method for regenerating wasted crosslinked high density polyethylene is provided to reduce cost required for de-crosslanking reaction using supercritical methanol as a reaction solvent. CONSTITUTION: Wasted crosslinked high density polyethylene-based pipe is converted into a remoldable high density polyethylene based resin by a decrosslinking reaction for 5 to 10 minutes using supercritical methanol as a reaction solvent under 370 to 390 degrees Celsius of reaction temperature and 5 and 30MPa of reaction pressure. The supercritical methanol is supercritical fluid with 32.04g/mol of molecular weight. The supercritical methanol has 512.6 degree Celsius of critical temperature and 8.09MPa of critical pressure, measured by a pressure gauge(A).
Abstract:
PURPOSE: A silsesquioxane polymer and a synthesis method thereof are provided to secure the low dielectric, the high modulus, and the compatibility with an organic solvent of the polymer. CONSTITUTION: A silsesquioxane polymer is obtained by condense-polymerizing a modified cyclic siloxane stereoisomer, and has the weight average molecular weight of 1,000~1,000,000. The modified cyclic siloxane stereoisomer is a cyclic siloxane substituted with a hydroxyl group. A synthesis method of the silsesquioxane polymer comprises the following steps: modifying the cyclic siloxane with a stereoisomer; separating the stereoisomer capable of forming a polymer; and condense-polymerzing the polymer using the stereoisomer as a monomer.
Abstract:
본 발명은 형태 안정성 및 내열성이 우수한 열가소성 탄성 복합체 조성물 및 이를 이용한 전자파 흡수 및 노이즈 차단용 복합 박막에 관한 것으로, 구체적으로 가공성과 유연성이 뛰어난 열가소성 탄성체 또는 그의 유도체 단독, 또는 이와 함께 내열성 향상을 위한 고결정성 저분자량의 폴리올레핀계 고분자를 포함하는 고분자 수지; 편상(flake)의 연자성 금속합금 분말; 및 가교제를 포함하는 형태 안정성 및 내열성이 우수한 열가소성 탄성 복합체 조성물 및 이를 이용한 전자파 흡수 및 노이즈 차단용 복합 박막에 관한 것이다. 본 발명에 따른 열가소성 탄성 복합체 조성물은 열가소성 탄성체 단독 또는 고결정성 저분자량의 폴리올레핀계 고분자와의 병용 사용과 금속합금 분말의 첨가로 인해 박막 단소화의 경우에도 형태 및 치수 안정성, 내열성, 유연성, 가공성 등의 물성이 우수하고 향상된 전자파 흡수 효율을 나타내기 때문에 전자기기에서 전자파 흡수 및 노이즈 차단용 복합 박막으로 유용하게 사용될 수 있다. 형태 안정성, 내열 박막 복합체, 열가소성 탄성체, 노이즈 차단
Abstract:
PURPOSE: A porous transition metal oxidation catalytic membrane, a manufacturing method thereof, and a method for processing wastewater containing non-degradable organic materials are provided to continuously process the wastewater with good oxidation efficiency. CONSTITUTION: A manufacturing method of a porous transition metal oxidation catalytic membrane includes the following steps: mixing a transition metal compound with a block copolymer, a surfactant, an organic polymer and a mixture in a solvent at a room temperature; forming nanostructure by removing the solvent after filling a frame with the compound; dipping the transition metals in the structure; and removing a nanostructure mold by sintering the compound in 150 ~ 1,000°C for 1 ~ 24 hours.
Abstract:
A method for preparing a polyolefin-based foamed particle is provided to prevent the deterioration of formability and physical properties due to the dispersant remaining on the surface of particles by using no dispersant. A method for preparing a polyolefin-based foamed particle comprises the steps of introducing a hydrophilic functional group to the surface of a polyolefin-based resin particle; putting the surface-treated polyolefin-based resin particle, a foaming agent and an aqueous dispersion medium into a pressure-resistant container, heating them with stirring, and discharging the resin particle with an aqueous dispersion medium and a foaming agent under the circumstance of lower pressure than that of the container, thereby foaming the resin particle.