公开(公告)号：DE59606624D1

公开(公告)日：2001-04-26

申请号：DE59606624

申请日：1996-11-20

Applicant: BASF AG

Inventor： HAEUSSLING LUKAS ,  BERNHARD LUDWIG ,  REICH WOLFGANG ,  SCHWALM REINHOLD ,  BECK ERICH ,  HARTMANN GABRIELE

IPC: C08F2/46 ,  C08F2/54 ,  C08F10/14 ,  C08F20/10 ,  C08F210/14 ,  C08F290/00 ,  C08F290/06 ,  C09D4/02

Abstract: A radiation-hardenable compsn. based on radiation-hardenable radically-polymerisable cpds. contains alpha -olefins with more than 8 C.

公开(公告)号：AU1024501A

公开(公告)日：2001-04-23

申请号：AU1024501

申请日：2000-10-12

Applicant: BASF AG

Inventor： MEIER ANTJE ,  KRANIG WOLFGANG ,  BECK ERICH ,  REICH WOLFGANG ,  PAULUS WOLFGANG ,  SCHROF WOLFGANG

IPC: C08F222/10 ,  C08F222/20 ,  C08F290/06 ,  C09D4/00 ,  C09D4/06

Abstract: The invention relates to a method for the production of adhesive-free, reduced-migration and reduced-yellowing coatings, in particular Foliendeckstrichen. Inventive coating materials containing less than 0.1 weight % of a photoinitiator and even in the absence of a photoinitiator can be hardened by exposure to UV-radiation, if the coating materials contain (meth)acrylate groups (A) and >CH-O-ether structure units (B) in certain minimum amounts, whereby (A) and (B) can also be accommodated in one molecule or in different molecules. The method exhibits many economic, technical and toxicological advantages due to said reduction of the amount of photoinitiators or the absence of photoinitiators.

公开(公告)号：DE19947054A1

公开(公告)日：2001-04-05

申请号：DE19947054

申请日：1999-09-30

Applicant: BASF AG

Inventor： SCHWALM REINHOLD ,  PAULUS WOLFGANG ,  MEISENBURG UWE ,  BECK ERICH ,  BRUCHMANN BERND ,  SCHROF WOLFGANG

IPC: C08G18/08 ,  C08G18/78 ,  C08G18/80 ,  C09D175/16 ,  C08G18/67 ,  C09D175/14

Abstract: UV- and heat-curable aqueous polyurethane dispersion based on aliphatic polyisocyanates and low-mol. wt. aliphatic compounds with at least 2 hydroxyl, mercapto or amino groups also contains compounds with NCO-reactive groups and UV-polymerizable double bonds, carboxylic or sulfonic acids with NCO-reactive groups and an isocyanate blocking agent. UV- and heat-curable aqueous polyurethane dispersions (PD), essentially comprising: (a) aliphatic polyisocyanates with an NCO functionality of 2-4.5, (b) compounds with isocyanate-reactive group(s) and C=C double bond(s) which can be polymerized with UV in presence of a photoinitiator, (c) aliphatic compounds with a mol. wt. of less than 500 and at least 2 isocyanate-reactive hydroxyl, mercapto or prim. and/or sec. amino groups, (d) compounds with isocyanate-reactive group(s) and carboxylic or sulfonic acid group(s), (e) a basic compound for at least partial neutralization of the acid groups in (d), (f) an isocyanate blocking agent (f1) with a deblocking temperature of 70-160 deg C or an added low-mol. wt. compound (f2) with blocked isocyanate groups, and (g) optionally compounds other than (b-f) with only one isocyanate-reactive group. Dispersions (PD) are obtained by reacting (a) with (b) and (c) using a stoichiometric excess of NCO groups over OH groups and with sufficient (d) and (e) for good dispersibility in aqueous media, and then introducing blocked isocyanate groups by reaction with (f1) or by addition of (f2) containing (b) as additive.

公开(公告)号：AT199243T

公开(公告)日：2001-03-15

申请号：AT96118091

申请日：1996-11-12

Applicant: BASF AG

Inventor： HAEUSSLING LUKAS ,  BERNHARD LUDWIG ,  REICH WOLFGANG ,  SCHWALM REINHOLD ,  BECK ERICH

IPC: C07C67/08 ,  C07C67/62 ,  C07C69/54 ,  C08G65/332 ,  C09D4/02

Abstract: A process for the production of (meth)acrylate esters (I) by esterification of (meth)acrylic acid (II) with mono- or poly- hydric alcohols (III) is claimed. The reaction mixture, still containing (II) in amounts equivalent to an acid number of at least 5 mg KOH/g, is treated with amino compound(s) (IV) containing at least one prim., sec. or tert. amino group. Also claimed are: (1) esters (I) obtained by this process; and (2) radiation-curable materials (RCM) containing (I).

公开(公告)号：DE19937759A1

公开(公告)日：2001-02-15

申请号：DE19937759

申请日：1999-08-10

Applicant: BASF AG

Inventor： BECK ERICH ,  JAECKH CHRISTOF ,  KRANIG WOLFGANG ,  DICKERHOF KARLHEINZ ,  WEISS WOLFRAM

IPC: B44C5/04 ,  C09D161/28 ,  D21H27/24 ,  B05D1/36 ,  B05D3/02 ,  B32B27/08

Abstract: The invention relates to plates having a decorative surface which are produced by: (i) impregnating a supporting material, e.g. a paper sheet; with a mixture (A) of an aqueous solution or an aqueous dispersion of a thermally hardenable melamine formaldehyde resin (A1) with a radiation-hardenable acrylate resin (A2), e.g. a urethane polyester and/or polyether acrylate, which can be diluted with water and/or which can be dispersed in water; (ii) coating the dried impregnated supporting material with a covering lacquer consisting of a mixture (B) that contains a radiation-hardenable acrylate resin (B1), e.g. a urethane acrylate as well as a thermally hardenable etherified melamine formaldehyde resin (B2), and; (iii) radiation-hardening and successively compacting the supporting material that is impregnated and provided with a covering lacquer. During processing, the employed coating system exhibits, in addition to good pot lives, a particularly good adhesiveness between the covering lacquer layers and the impregnated supporting materials.

公开(公告)号：DE19860049A1

公开(公告)日：2000-06-29

申请号：DE19860049

申请日：1998-12-23

Applicant: BASF AG

Inventor： SCHWALM REINHOLD ,  BRUCHMANN BERND ,  BECK ERICH

IPC: B05D7/24 ,  C08F290/06 ,  C08G18/67 ,  C08G18/75 ,  C08G18/79 ,  C08G18/81 ,  C08K5/103 ,  C09D4/00 ,  C09D5/00 ,  C09D175/04 ,  C09D175/14 ,  C09D175/16 ,  C08G18/10 ,  C08G18/78 ,  C08G18/32 ,  C08L75/16

Abstract: The invention relates to a hardenable preparation containing a prepolymer and the following incorporated by polymerisation: (a) an isocyanate which is at least bifunctional on average and is based on a compound of formula (I), wherein R and R , independently of each other, represent C1-12-alkylene; (b) an ethylenically unsaturated compound containing isocyanate reactive groups and (c) optionally, a saturated compound containing isocyanate reactive groups.

公开(公告)号：DE19851139A1

公开(公告)日：2000-05-11

申请号：DE19851139

申请日：1998-11-05

Applicant: BASF AG

Inventor： SCHROF WOLFGANG ,  SCHWALM REINHOLD ,  BECK ERICH ,  MEISENBURG UWE

IPC: B05B5/025 ,  B05C9/14 ,  B05D3/06 ,  B05D5/06 ,  B05D7/24 ,  C08F2/48 ,  B05D3/00

Abstract: A crosslinking reaction is initiated in a reactive paint formulation. This is coated-onto a surface at least locally, before reaction is completed. Independent claims are included for equipment carrying out the process, and for the coating so produced. The equipment employs a sprayer and/or electrostatic applicator with bell housing. Preferred features: Initiation of reaction preferably employs UV illumination (1), in conjunction with at least one photoinitiator in the formulation. Kinetics of the reaction are controlled by temperature variation, and/or by use of a sufficiently slowly-running reaction, especially a cationic polymerization, and/or by spatial separation of photoinitiator(s) from the formulation components and/or by minimizing reactivity of the photoinitiator(s). Spatial separation cited, is by nano-structuring of the paint formulation. Further stages include mixing a UV protection agent and/or pigment into the formulation before coating. A hand spray gun (6) applies the paint. In the equipment, optical fibers (3, 4) transmit UV light to the paint formulation.

公开(公告)号：AT190328T

公开(公告)日：2000-03-15

申请号：AT95114706

申请日：1995-09-19

Applicant: BASF AG

Inventor： HAEUSSLING LUKAS ,  JAEGER ULRICH ,  REICH WOLFGANG ,  BECK ERICH ,  LEBKUECHER WERNER ,  SCHWALM REINHOLD

IPC: C08G18/66 ,  C08G18/08 ,  C08G18/12 ,  C08G18/42 ,  C08G18/65 ,  C08G18/67 ,  C09D175/16

公开(公告)号：DE59603969D1

公开(公告)日：2000-01-27

申请号：DE59603969

申请日：1996-09-16

Applicant: BASF AG

Inventor： SCHWALM REINHOLD ,  REICH WOLFGANG ,  HAEUSSLING LUKAS ,  BECK ERICH

IPC: C08F2/48 ,  C08F2/44 ,  C08F2/46 ,  C08F2/50 ,  C08F8/30 ,  C08F8/32 ,  C08F20/10 ,  C08F290/06 ,  C08G73/00 ,  C09D4/00 ,  C09D4/02

Abstract: Radiation-curable compsns. (I), contg. (a) radiation-curable, radically-polymerisable cpds. and (b) capped amino cpds. which are surface-active in cpds. (a) and which release amino cpds. with free prim. and/or sec. amino gps. when irradiated with high-energy light, the total no. of H atoms contained in amino gps. being at least 2. Also claimed is (i) a process for the prodn. of (I) by adding cpds. (b) to cpds. (a); (ii) a process for the prodn. of coatings or mouldings by irradiating (I) with high-energy light; (iii) moulded prods. or coatings obtd. by this process.

公开(公告)号：AT187978T

公开(公告)日：2000-01-15

申请号：AT96114802

申请日：1996-09-16

Applicant: BASF AG

Inventor： SCHWALM REINHOLD ,  REICH WOLFGANG ,  HAEUSSLING LUKAS ,  BECK ERICH

IPC: C08F2/48 ,  C08F2/44 ,  C08F2/46 ,  C08F2/50 ,  C08F8/30 ,  C08F8/32 ,  C08F20/10 ,  C08F290/06 ,  C08G73/00 ,  C09D4/00 ,  C09D4/02

Abstract: Radiation-curable compsns. (I), contg. (a) radiation-curable, radically-polymerisable cpds. and (b) capped amino cpds. which are surface-active in cpds. (a) and which release amino cpds. with free prim. and/or sec. amino gps. when irradiated with high-energy light, the total no. of H atoms contained in amino gps. being at least 2. Also claimed is (i) a process for the prodn. of (I) by adding cpds. (b) to cpds. (a); (ii) a process for the prodn. of coatings or mouldings by irradiating (I) with high-energy light; (iii) moulded prods. or coatings obtd. by this process.