PROCESS FOR PREPARING SUBSTITUTED BIPHENYLS

    公开(公告)号:CA2636695A1

    公开(公告)日:2007-12-06

    申请号:CA2636695

    申请日:2007-05-31

    Applicant: BASF AG

    Abstract: A process for preparing substituted biphenyls of the formula I in which the substituents are defined as follows: X is fluorine or chlorine; R1 is nitro, amino or NHR3; R2 is cyano, nitro, halogen, C1-C6-alkyl, C1-C-6-alkenyl, C1-C6-alkynyl, C1-C6-alkoxy, C1-C6-haloalkyl, C1-C6-alkylcarbonyl or phenyl; R3 is C1-C4-alkyl, C1-C4-alkenyl or C1-C4-alkynyl; n is 1, 2 or 3, where in case that n is 2 or 3, the R.sup.2 radicals may also be different, which comprises reacting the compound of the formula II in which Hal is halogen and X and R1 are as defined above, in the presence of a base and of a palladium catalyst selected from the group of:3 a) palladium-triarylphosphine or -trialkylphosphine complex with palladium in the zero oxidation state, b) salt of palladium in the presence of triarylphospine or trialkylphosphine as a complex ligand or c) metallic palladium, optionally applied to support, in the presence of triarylphosphine or trialkylphosphine, in a solvent, with a diphenylborinic acid (III) in which R2 and n are as defined above, where the triarylphosphines or trialkylphosphines used may be substituted.

    New substituted imidazolo pyrimidine compounds useful as fungicidal agents to combat phytopathogenic fungus, animal parasites such as insects, as plant protectant, and to protect materials in hygiene sector

    公开(公告)号:DE102007008940A1

    公开(公告)日:2007-09-20

    申请号:DE102007008940

    申请日:2007-02-23

    Applicant: BASF AG

    Abstract: Substituted imidazolo pyrimidine compounds (I) and their salts, are new. Substituted imidazolo pyrimidine compounds of formula (I) and their salts, are new. R1>e.g. H, 1-12C (halo)alkyl or 2-12C (halo)alkenyl; R2>Z-Y1>-(CR7>R8>)p-(CR5>R6>)q-CR3>R4>-A; Z : e.g. H, carboxyl, formyl, 5-8C alkyl, 1-8C haloalkyl or 2-8C (halo)alkenyl; Y1>O or S; R3>-R8>e.g. H, 1-8C (halo)alkyl, 2-8C (halo)alkenyl or 2-8C (halo)alkynyl; A : a bond with the nitrogen atom; W1>, W2>e.g. H, halo, cyano, nitro, 1-4C alkyl, 2-6C alkenyl or 2-6C alkynyl; Het : substituted 5-6 membered saturated, partially unsaturated or aromatic heterocyclic containing 1-4 heteroatoms of O, N or S; X : e.g. halo or (halo)1-4C alkyl; p : 0-5; and q : 0 or 1. Full Definitions are given in the DEFINITIONS (Full Definitions) Field. Independent claims are included for: (1) a fungicidal agent comprising (I) and a solid- or liquid carrier material; (2) a seed containing (I) (1-1000 g/100 kg); (3) a combination comprising (I), fungicidal-, insecticidal- and/or herbicidal- active agent; (4) a method to combat phytopathogenic fungus comprising treating the fungus with (I) and/or treating the protecting materials, plants, soil and/or seeds with (I), before fungus attack; and (5) preparation of (I). [Image] ACTIVITY : Fungicide; Plant Protectant; Insecticide; Arachnicide; Antiparasitic; Nematocide; Cytostatic. MECHANISM OF ACTION : None given.

    DERIVADOS DE HETEROCICLILCARBOXANILIDA PARA CONTROLAR INFECCIONES DE ROYA EN PLANTAS LEGUMINOSAS

    公开(公告)号:PE20070538A1

    公开(公告)日:2007-07-12

    申请号:PE2006000936

    申请日:2006-08-03

    Applicant: BASF AG

    Abstract: DE FORMULA (I) DONDE: n ES 0, 1, 2, 3 o 4; Hal ES HALOGENO; X ES HALOALQUILO C1-C6 o HALOALQUENILO C2-C6; Het ES UN RADICAL PIRAZOL, TIAZOL O UN RADICAL PIRIDINA DE FORMULA (IIa), (IIb) o (IIc) DONDE: R1, R3 Y R4 SON ALQUILO C1-C4 o HALOALQUILO C1-C4; R2 ES H o HALOGENO; R5 ES HALOGENO, ALQUILO C1-C4, HALOALQUILO C1-C4, ALCOXI C1-C4, ALQUILTIO C1-C4, ALQUILSULFINILO C1-C4 o ALQUILSULFONILO C1-C4. LOS DERIVADOS SE USAN EN COMBINACION CON UN COMPUESTO ACTIVO II SELECCIONADO DE: AZOLES COMO BROMOCONAZOL, CIPROCONAZOL, EPOXICONAZOL, FLUQUINCONAZOL, FLUSILAZOL, FLUTRIAFOL, IMAZALILO, PROCLORAZ Y TRIADIMEFON; ACILALANINAS COMO BENALAXILO, METALAXILO, MEFENOXAM, OFURACE Y OXADIXILO; DERIVADOS DE AMINA COMO GUAZATINA; ANILINOPIRIMIDINAS COMO PIRIMETANILO, MEPANIPIRIM Y CIPRODINILO; DICARBOXIMIDAS COMO IPRODIONA, PROCIMIDONA Y VINCLOZOLINA; DITIOCARBAMATOS COMO MANCOZEB, METIRAM Y TIRAM; COMPUESTOS HETEROCICLICOS COMO BENOMILO, BOSCALIDA, CARBENDAZIM, CARBOXINA, FUBERIDAZOL, PENTIOPIRAD, TIABENDAZOL Y 5-CLORO-7-(4-METILPIPERIDIN-1-IL)-6-(2,4,6-TRIFLUOROFENIL)-[1,2,4]TRIAZOLO[1,5-a]PIRIMIDINA; FENILPIRROLES COMO FENPICLONILO Y FLUDIOXONILO; OTROS FUNGICIDAS COMO BENTIAVALICARB, FOSETILO, IPROVALICARB Y METRAFENONA; ESTROBILURINAS COMO AZOXISTROBINA, KRESOXIM-METILO Y PIRACLOSTROBINA; AMIDAS DE ACIDO CINAMICO COMO DIMETOMORF, FLUMETOVER Y FLUMORF; Y OTROS COMO IMAZETAPIR, IMAZAMOX, IMAZAPIR, DIMETENAMIDA-p, FIPRONILO, CARBOFURANO, BENFURACARB Y NEONICOTINOIDE INSECTICIDA; ENTRE OTROS

    DERIVADOS DE ARILANILIDA PARA TRATAMIENTO DE SEMILLAS

    公开(公告)号:PE20070595A1

    公开(公告)日:2007-06-27

    申请号:PE2006000946

    申请日:2006-08-04

    Applicant: BASF AG

    Abstract: DE FORMULA (I) DONDE: X ES HALOGENO; Y ES O o S; n ES 0, 1, 2, 3 o 4; R ES ALQUILO C1-C6, HALOALQUILO C1-C8, HALOALQUENILO C2-C8, CICLOALQUILO C3-C6 o CICLOALQUENILO C3-C6; Ar ES UN RADICAL ARILO DE FORMULA (IIa), (IIb) o (IIc) DONDE R1 ES H, HALOGENO, ALQUILO C1-C4 o HALOALQUILO C1-C4; R2 ES ALQUILO C1-C4; R3 ES H, HALOGENO O METILO; R4 ES H, HALOGENO, ALQUILO C1-C4 o HALOALQUILO C1-C4; R5 ES ALQUILO C1-C4 o HALOALQUILO C1-C4; Z ES CH o N; Y R6 ES HALOGENO, ALQUILO C1-C4, HALOALQUILO C1-C4, ALCOXI C1-C4, ALQUILTIO C1-C4, ALQUILSULFINILO C1-C4 o ALQUILSULFONILO C1-C4. LOS DERIVADOS SE PUEDEN EMPLEAR JUNTO CON UN INGREDIENTE FUNGICIDA ACTIVO SELECCIONADO DE: AZOLES COMO BROMOCONAZOL, CIPROCONAZOL, DIFENOCONAZOL, EPOXICONAZOL, FLUQUINCONAZOL, FLUSILAZOL, FLUTRIAFOL, HEXACONAZOL, IMAZALIL, METCONAZOL, MICLOBUTANIL, PENCONAZOL, PROPICONAZOL, PROCLORAZ, PROTIOCONAZOL, TEBUCONAZOL, TETRACONAZOL, TRIADIMENOL Y TRITICONAZOL; ACILALANINA COMO BENALAXIL, METALAXIL, MEFONOXAM, OFURACE Y OXADIXIL; DERIVADOS DE AMINA COMO GUAZATINA; ANILINOPIRIMIDINAS COMO PIRIMETANIL, MEPANIPIRIM Y CIPRODINIL; DICARBOXAMIDAS COMO MANCOZEB, METIRAM Y TIRAM; COMPUESTOS HETEROCICLICOS COMO BENOMIL, CARBENDAZIM, OXICARBOXIN, FUBERIDAZOL, PICOBENZAMIDA, PENTIOPIRAD, PROQUINAZIDA, TIABENDAZOL Y TIOFANATO-METILO; FENILPIRROLES COMO FENPICLONIL Y FLUODIOXONIL; OTROS FUNGICIDAS COMO BENTIAVALICARB, CIFLUFENAMIDA, FOSETIL, ENTRE OTROS; ESTROBILURINAS; AMIDAS DEL ACIDO CINAMICO COMO DIMETOMORF, FLUMETOVER Y FLUMORF

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